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FACTORS AFFECTING SEDIMENTATION Several factors affect the separation of settle able solids from water. Some of the more common types of factors to consider are: PARTICLE SIZE :-The size and type of particles to be removed have a significant effect on the operation of the sedimentation tank. The shape of the particle also affects its settling characteristics. A round particle, for example, will settle much more readily than a particle that has ragged or irregular edges
WATER TEMPERATURE Another factor to consider in the operation of a sedimentation basin is the temperature of the water being treated. When the temperature decreases, the rate of settling becomes slower. CURRENTS Several types of water currents may occur in the sedimentation basin: Density currents caused by the weight of the solids in the tank, the concentration of solids and temperature of the water in the tank. Eddy currents produced by the flow of the water coming into the tank and leaving the tank.
TYPES OF SEDIMENTATION
PLAIN SEDIMENTATION - when impurities are separated from fluid by action of natural forces alone CLARIFICATION WHEN CHEMICALS (sedimentation with coagulation) when chemicals are added to hasten aggregation of finely suspended matter CHEMICAL PRECIPITATION when chemicals are added to throw dissolved impurities out of solution than it is called chemical precipitation
TYPE 1 OR DISCRETE SETTLING also known as FREE SETTLING as particles have little tendency to flocculate. It is sedimentation when particles have low concentration particles settles as individual entities Example of Type I settling is the settling of silt, grit etc., from river water before applying to the slow sand filters. TYPE 2 OR FLOCCULANT SETTLING refers to dilute suspensions which flocculate during sedimentation. This results in increase in mass and hence settling rate increase with depth Example of TYPE 2 SETTLING are settling in primary settlers
TYPES OF SETTLING
TYPE 3 OR HINDERED SETTLING refers to settling of suspension of intermediate concentration. Intermediate forces hold particles together and they settle as a unit. In hindered settling, the velocity gradients around each particle are affected by the presence of nearby particles. So the normal drag correlations do not apply Example of HINDERED SETTLING IS settling in secondary clarifiers TYPE 4 OR COMPRESSION SETLING refers to settling of suspension of high concentration. On contact particles form a structure and settling takes place by compression of structure due to weight of particles Settling of SLUDGE is example of compression settling
As seen above, not only does the settling take more time as the slurry becomes more concentrated but, critical sedimentation point occurs at progressively higher interface heights
(Ref 4)
From Newtons second law mdV/dt = Fg Fb Fd where: m = mass V = velocity of particle Fg = weight of particle Fb = force of buoyancy Fd = drag force
DRIVING FORCE (FI) = Fg - Fb = (Ss- S)gV where S = density of fluid S s = particle density g = acceleration due to gravity Vp = volume of particle
FD depends upon :Dynamic viscosity Mass of fluid Shape and size of fluid DRAG FORCE is given by NEWTONs LAW for frictional drag as FD = CDASVS2/2 FD = DRAG FORCE CD = Drag coefficient A= Projected area of particle
Therefore equation 1 can be rewritten as mdV/dt = (Ss- S)gVp - CDASVS2/2 At steady state terminal velocity will be reached hence dV/dt = 0 Therefore (Ss- S)gVp = CDASVS2/2 Solving for VS we get VS = (4(Ss- S)gd/3CD S) where d = diameter of the spherical particle
CD depends upon Reynolds's Number For R between .5 to 104 CD= 24/R+3/(R)+.34 For high Re >103 to 104 CD = .4 For Re < .5 CD = 24/R
A suggested equation for the variation of floc density with particle size is Ss S = kd-0.7 Where Ss = floc density S = density of water d = diameter of particle K = coefficient dependent on characteristic of water and chemicals involved The rate of flocculation is proportional to mean velocity gradient in the system , concentration of particle and the particle size
To develop this we have to perform a settling column test in which suspension is kept in long column and allowed to settle under quiescent conditions Samples are withdrawn from this cylinder, at several depths at several time interval and % removal is determined Numerical value of % removal is located at the co ordinates identifying the time and depth of the sample and iso concentration lines connecting points of equal removal are drawn.
Continuous Flow Type velocity of particles is such a parameter which can be easily controlled In this, particles continue to flow with a small velocity and the settable solids settle a the bottom before they reach the outlet They are of two types (a)Horizontal Flow (b)Vertical Flow
The basin is divided into four zones INLET ZONE from where the water enters the tank SETTLING ZONE where the suspended particles get settled under gravity SLUDGE ZONE where the suspended particles get collected after settling OUTLET ZONE from where water and left over suspended particles assemble and get carried away outside the tank
Consider a particle entering the tank to have a vertical falling speed of vs Time of falling through a distance H will be H/v s For particles to reach the bottom before the water leaves the tank the falling speed should be equal to the time of horizontal flow H/vs = LBH/Q vs = Q/LB Hence it defines the surface overflow rate as flow divided by plan area of the basin Particles with speed greater than Q/A will get settled
to = LBH/Q to is known as detention period If a particle with a falling speed less than vs<Q/A enters the tank it will settle only a distane h during the detention time which is given as h/vs =to =LBH/Q h= LBHvs /Q But LBH/Q is vs Hence h=(vs/vs)H Ratio of removal of this size particle to that of settling value vs is given by
DETENTION PERIOD
xr = h/H = vs/vs For example a tank of 400m2 surface area and rate of inflow is 1.6m3/sec than Q/A = .4cm/sec Hence all particle having speed vs = .4cm/sec or greater will be completely removed Only 50% particles having speed vs = .2cm/sec will be removed And 25% of particles having speed vs =.1cm/sec will be removed
DESIGN ELEMENTS
Following are the important elements of design 1)Detention Period and Displacement Efficiency Detention period :- it is theoretical time taken by a particle in water to pass between entry and exit of a settling tank to = LBH/Q Flow through period :-it is average time required by a batch of water to pass through the settling tank and it is always less than the detention period due to short circuit effects
Displacement efficiency :- it is defined as the ratio of flow through period and the detention period = td/to 2)OVERFLOW RATE AND SURFACE LOADING : Quantity of water passing per hour per unit horizontal area is known as overflow rate or surface loading vs = Q/A
3)BASIN DIMENSIONS :- surface area of the basin is determined on the basis of surface loading rate or overflow rate surface area = (Volume of water in liters hours)/(surface loading rate) Length to width ratio should be from 3:1 to 5:1 Depth of the basin should be kept from 2.5 to 5m Slope should be 1% in case of rectangular tanks and 8% in case of circular tanks
4) INLET and OUTLET ARRANGEMENTS Ideal inlet structure should be such that Uniformly distribute water across width and depth of the tank Mix it with water already in the tank to prevent density currents Minimize large scale turbulence Initiate longitudinal and radial flow to so as to achieve high removal efficiency Outlet arrangements consists of weirs, notches or orifices Lauder Outlet pipe
SLUDGE REMOVAL The particle settled in the basin consist of sludge which should be removed either manually or mechanically Where the quantity of suspended matter is small than clearance is done once in 2 4 months And where it is large clearance is done quite often Also removal of sludge manually is very expensive
Claification is achieved in 3 stages 1) addition of measured amount of chemicals known as coagulants 2)formation of precipitate which coagulates and form a floc 3) sedimentation Characteristics of Coagulants The ability of a chemical additive to produce coagulation is in general dependent on the 1)ELECTRIC CHARGE of the ion or molecule used as coagulant , the larger the charge the more effective the coagulant will be 2) SIZE OF ION or molecule used as coagulant the larger the size of the molecule the more effective the coagulant will be.
WORKING OF COAGULANTS
COMMON COAGULANT
1)Alum One of the earliest, and still the most extensively used coagulant, is aluminum sulfate (Al/S04)3 18 H2O), also known as alum. It is readily soluble in water. When dissolved in water following hydrolysis reaction takes place Al2(SO4)318H2O +3Ca(HCO3)2Al(OH)3+ 3CaSO4+18H2O+6CO2 Aluminum hydroxide is insoluble in water and forms a floc
DOSAGE is 75 to 250 ppm in a pH range of 4.5 to 7 RELATIVE COAGULANT POWER against negative colloids is greater than 1000
(Ref 3)
DISADVANTAGES It is effective only at certain pH range, and good flocculation may not be possible with alum in some waters.
Ferrous Sulphate:-Ferrous sulphate, ordinarily known as copperas, is fed usually in solution form with strength of 4 to 8 %. The alkalinity and pH value of natural water are too low to react with copperas to form the desired ferric hydroxide floc, It is necessary, therefore, to add lime with copperas to secure coagulation. The following reaction takes place FeSO47H2O+Ca(OH)2Fe(OH)2+CaSO4 +7H2O Ferrous hydroxide thus formed gets oxidized by dissolved oxygen in water to form ferric hydroxide DOSAGE is in between 70 to 200 ppm in a pH range of 4 to 7
LIME Lime is a generic name used to identify several combinations of calcium and oxygen, such as or CaO (quicklime). Lime often contains magnesium In the presence of bicarbonate ion lime will react to form a calcium carbonate precipitate That can remove colloids through the sweeping floc mechanism. The reaction involved is Ca(OH)2+ Ca(HCO3)2 CaCO3 + 2H2O DOSAGE should be in between 150 to 500 ppm and pH range may vary from 9 to 11 (Ref 2)
COAGULANT AIDS
coagulant aids are additives that can be added to a destabilized colloidal suspension and hence they tend to promote the growth of large, rapid-settling floc which can then flocculate Typical coagulant aids are: Activated silica Polyelectrolytes
REFRENCES
1) WATER SUPPLY ENGNEERING By B.C.PUNMIA 2) http://cpe.njit.edu/dlnotes/che685/cls071.pdf 3) http://www.mrwa.com/OPSedimentation.pdf 4)http://www.filtrationandseparation.com/thick ener/sld006.htm 5)http://lorien.ncl.ac.uk/ming/particle/cpe124p 2.html
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