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− E / RT
k = k0e
Where
k0 = pre-exponential factor
E =Activation energy (i.e. sufficient energy to destroy the
molecular bonds)
R= Gas constant
T= Absolute temperature of the process
Combustion Reactions (Carbon)
Main reactions
2C + O2 = 2CO + 3950 BTU/lb (Deficit air)
C + O2 = CO2 +14093 BTU/lb
Secondary reactions
2CO + O2 = 2CO2 + 4347BTU/lb C
+ CO2 = 2CO -7.25MJ/kg
Combustion Reactions (Carbon)
Carbon reaction
2C + O2 =2CO [Eco =60kJ/mol]
C + O2 =CO2 [Eco2 =140kJ/mol]
reaction at 1200oC
4C + 3O2 =2CO + 2CO2 (Ratio 1:1)
Reaction at 1700oC
3C + 2O2 = 2CO +CO2 (Ratio 2:1)
Sulfur reaction
S + O2 = SO2 + 3980 BTU/lb
(undesirable)
Combustion Reaction (N2)
Nitrogen reaction
MW Elect
Q Furnace =
ηCycle
Efficiency of thermal power plants is 37%-45% for
different types of cycle
For typical conventional P.F. boilers, coal flow rate
is
290-350 T/hr For 500 MW units
120-145 T/hr For 200 MW units
Arrangement of fuel input in
furnace
Coal is pulverized in mills at a fineness of 70% thru
200 mesh. Dried powdered coal is conveyed to
furnace (at a temperature < 95-100oC)
Indian coals are suitable for dry bottom furnace design only,
because of
a. High fuel ash (35-50%)
b. High silica in ash (55-65% & vitrification temp. is 2000oK)
c. High flow temperature (1600oC approx)
Configuration of Dead
chamber Steam drum
HORIZONTAL PASS
w/w hanger Screen
tubes tubes
ARCH TUBES
Downcomer
FURNACE
BCW p/p
To APH
Reheater
S
Drum C
Platen SHTR
R
DPNL E
E
SHTR n
Gooseneck LTSH
Chimney
Downcomer
waterwall
Fireball Economiser
ID fan
ESP
APH
Bottom Ash
Steam generation principle
Steam power plants operate on
Rankine Cycle, DM water as
working fluid. SH RH
Sensible heat is added in w/w HPT
HPH+Eco IPT
economiser +furnace
Steam generation takes place BFP
LPT
in waterwall.
LPH
Typical furnace efficiency is
45% approx. CEP
condenser
Heat transfer in furnace and
enclosed superheater takes
place thru radiation.
Superheater & Reheater
Heat associated with the flue gas
is used in superheaters &
Reheater, LTSH, economiser.
Maximum steam temperature is SH RH
decided by the operating drum w/w HPT
pressure and metallurgical HPH+Eco IPT
constraints of the turbine blade BFP
material. LPT
Reheating is recommened at LPH
pressure above 100 ksc operating
pressure. Reheating is done at 20-
25% of the operating pressure. CEP
condenser
Carbon steel, alloy steel & SS
used for tubing of SH & RH.
Principle of circulation
Density water and steam
changes with pressure as
shown.
185 ksc
At higher pressure,
density difference Sp. gravity
reduces.
Flow establishment in
down comer, waterwall
and drum is due to 225
density difference and ksc
height of water column 165 ksc
(i.e. waterwall) at lower
pressure. Pressure (KSC)
Type of Circulation
Natural circulation (upto
165 ksc) Density difference &
height of water column
Assisted by external
Forced/ assisted
circulation (185-190 ksc) circulating pump (CC/
BCW pump)
Once thru boiler
1. Sub critical
2. Supercritical
Below 221.5 bar
240-360 bar
Circulation ratio
It may be defined as
ratio of feed water flow thru CR = 30-35 Industrial
down comers to the steam boilers
generated in water wall. CR = 6-8 Natrual cir.
Ratio of the weight of 2- Boilers
phase mixture to the weight CR = 2-3 Forced cri.
of dry steam in waterwall. Boilers
Ratio of the total fluid CR = 1 Once thru boilers
contained to the weight of
the dry steam in waterwall. (Sub critical)
CR = 1 Supercritical
boilers
Representation of steam/ water
parameters on T-S diagram
1. Sub critical parameter
3 2. Critical parameter,
Temperature
(225.65 ksc/ 374.16oC)
374.16oC 2 3. Supercritical parameter
1
Entropy
Design concepts of once thru steam
generators
Controlled point
in circuitry Mix locations
C/R flow
{0 from
External downcomers
External downcomers
60% to
Full
Sulzer design
Load}
C/R pump
Feed
Valved control of furnace ckt Combined C/R
Benson Design
design
Comparision of measures to improve
%
efficiency
46 0.03 bar
double
300bar 0.065bar
44 600/600
single
250bar
42 540/560 250bar
120 540/560
1.15 170bar
40
1.25 130 535/535
39 Excess exit gas steam conditions Reheat cond. Pressure
Air temp.
Effect of supercritical parameters
on efficiency (%)
Pressure/ Temp 175 bar 245 bar 295 bar
540oC/ 540oC Ref. 1.92 2.44
540oC/ 566oC 0.72 2.74 3.33
565oC/ 565oC 1.35 3.45 4.12
600oC/ 600oC 3.10 5.30 6.09
600oC/620oC 3.62 5.91 6.61
Advantage
1. Saving on coal consumption on higher efficiency
2. Reduction in fuel handling system & pollution control.