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DyD
Conservation of species requires that these two rates be equal to each other:
d dx dW
− (WxW ) = −W W − x W = DyD
dt dt dt
−WdxW − xW dW = y D Ddt QB
pressure constant
dew point y
T T1
V T5
T4 T2
Tb(B)
T3
T3
T2
T1
T4
Tb(A)
L T5
xa ya
xA=0 xA=1 x
xB=1 xB=0 9
Lecture 15: Batch Distillation
Distillation: Basic elements of the process
Va , y a
La, xa=xd
condenser
Ln-1 xn-1
Vn yn Overhead product D, xd
Ln xn
Vn+1 yn+1
F , zf
Lm-1 xm-1
Vm ym
Bottom product B, xb
Lm xm
Vm+1 ym+1
Vb , y b boiler
Lb, xN
Lecture 15: Batch Distillation 10
Distillation: Operating lines
Va , y a
Rectifying section
La, xa=xd=y1=ya
condenser
Ln-1 xn-1
Overhead product D, xd
Vn yn
R=La/D
Ln xn
Vn+1 yn+1
F , zf
Lm-1 xm-1
Vm ym
Bottom product B, xb
Lm xm
Vm+1 ym+1
Vb , y b boiler
Lb, xN
Lecture 15: Batch Distillation 11
Distillation: Operating lines
Ln D
Vn +1 yn +1 = Ln xn + Dx D ⇒ yn +1 = xn + xD
Vn +1 Vn +1
This equation is a straight line (V=const, L=const, L/V=const) if:
Va , y a
L D
yn +1 = xn + x D La, xa condenser
V V Overhead product D, xd
R=L/D
Ln xn Vn+1 yn+1
L L L L/D R
R= ; = = = Reflux ratio
D V L + D L / D + D / D R +1
R 1
yn +1 = xn + xD
R +1 R +1
R 1
yn +1 = xn + xD
R +1 R +1
y
slope=R/(R+1)
1
xD
R +1
xD
x
Lecture 15: Batch Distillation 14
Distillation: Operating lines
Va , y a
La, xa
condenser
Ln-1 xn-1
Overhead product D, xd
Vn yn
R=La/D
Ln xn
Vn+1 yn+1
F , zf
Lm-1 xm-1
Stripping section
Vm ym
Bottom product B, xb
Lm xm
Vm+1 ym+1
Vb , y b boiler
Lb, xN
Lecture 15: Batch Distillation 15
Distillation: Operating lines
L xm =V ym +1 + Bx B Lm xm
Vm+1 ym+1
Bottom product B, xb
boiler
L B
ym +1 = xm − xB y
V V
L
slope= V
yB
xN
Lecture 15: Batch Distillation
xB x 16
Distillation: Feed stage considerations
L V L V L V
F F F
L V L V L V
F F F
F F F
dew point
bubble point
q=1 vapour feed q=0
liquid feed
L V L V L V
F F F
Vy = Lx + Dx D rectifying section
D
y (V − V ) = ( L − L ) x + DxD + BxB F
B
FzF
q zF
y= x+
q −1 1− q
Feed line
Lecture 15: Batch Distillation 20
q>1
Distillation: Feed line behavior
q=1
x
y=
q zF
y= x+ 0<q<1
q −1 1− q
q=0
x=zf
x=zf
q zF
y= zF + = zF q<0
q −1 1− q
y=zf
R 1
yn +1 = xn + xD
R +1 R +1
y
q zF y1
y= x+
q −1 1− q
L B
yn +1 = xm − xB
V V zf
1 yB
xD
R +1
xB xN zf xD
x
R 1
yn +1 = xn + xD
R +1 R +1
y
L B
yn +1 = xm − xB y1
V V
q zF
y= x+
q −1 1− q zf
yB
xB xN zf xD
x
D=0
y
F=0 R=L/D=∞
y1
L/V=1
Ln + D = Vn +1
Ln = Vn +1
B=0
zf
Total reflux
R 1
yn +1 = xn + xD
R +1 R +1 yB
If R=L/D= ∞ then R/(R+1)=1; also L=V
xB xN zf xD
y n +1 = xn
x
D=0
y
F=0 R=L/D=∞
y1
L/V=1
Ln + D = Vn +1
Ln = Vn +1
B=0
zf
Total reflux
R 1
yn +1 = xn + xD
R +1 R +1 yB
If R=L/D= ∞ then R/(R+1)=1; also L=V
xB xN zf xD
y n +1 = xn
x
a) Graphical methods y
D, xD
F, z R=L/D
B, xB
xB xD
x
y n +1 = xn
y m +1 = xm
Consider relative volatility coefficient for a binary mixture of A and B:
yA / xA y y
α AB = ⇒ α AB B = A
y B / xB xB x A
For a binary mixture, yA+yB=1, and xA+xB=1, so skipping the A, B subscripts and rewriting everything
for the light component A:
1− y y
α AB =
1− x x
1− y y
α AB =
1− x x
For a particular stage n+1:
1 − yn +1 yn +1 yn +1 xn +1
α n +1, AB = ⇒ = α n +1, AB
1 − xn +1 xn +1 1 − yn +1 1 − xn +1
At the same time: y n +1 = xn
xn xn +1
So = α n +1, AB
1 − xn 1 − xn +1
xn xn +1
= α n +1, AB
1 − xn 1 − xn +1
xD x1
= α1, AB
1 − xD 1 − x1
x1 x2
= α 2, AB
1 − x1 1 − x2
xD xn +1
= α1, ABα 2, AB α n +1, AB
1 − xD 1 − xn +1
xD xB
= α1, ABα 2, AB α N +1, AB
1 − xD 1 − xB
xD N min +1 xB
= (α )
1 − xD 1 − xB
ln[ xD (1 − xB ) / xB (1 − xD )
N min = −1
ln α AB
Fenske equation
y
q zF
y= x+ y1
q −1 1− q
R 1
yn +1 = xn + xD
R +1 R +1 zf
L B
yn +1 = xm − xB
V V yB
xB xN zf xD
x
zf
xB xN zf xD
x
R 1
yn +1 = xn + xD
R +1 R +1 y
y1