been increased in recent years. • Even structures constructed high performance concrete, start to deteriorate long before reaching their designed service life • Expansive cement is a cement that when mixed with water produces a paste that after setting increases in volume to a greater degree than does portland-cement paste. Literature Title Authors Year Observations Expansive S. Nagataki & 1998, Properties of expansive cement. Kinds admixtures (mainly H. Gem Elsevier Ltd. of expansive cement. ettringite)
Expansive Cement SHU -T’IEN LI The Uses of self stressing cement.
Concrete Aberdeen Group Slight-expansive Bingliu Zhang, Uses of expansive cement as binder road base course Weiguo Shen, coarse. binder: Properties, Jing Wang hydration and performance
Application of the Reza Mechanical properties of polymer
polymer concrete Allahvirdizade concrete and applications in repair. in repair of h & R. concrete Rashetnia structures TYPES • Type K expansive cement : A mixture of Portland cement, Anhydrous Tetracalcium Trialuminate sulfate (C4A3S), Calcium sulfate (CaSO4), and Lime (CaO). • Type M expansive cement : Portland cement and calcium sulfate. • Type S expansive cement : a portland cement containing a high computed tricalcium aluminate (C3A) and calcium sulfate • The hydration chemistry of expansive cements is described with emphasis on the components for formation of ettringites. • Expansive cement concrete as ‘shrinkage- compensating concrete’ or ‘chemical prestressing concrete ’ is applied to many kinds of concrete construction. • Shrinkage-compensating concrete is an expansive cement concrete in which expansion if restrained induces compressive stresses which approximately offset tensile stresses in the concrete induced by drying. • Self-stressing concrete is an expansive cement concrete in which expansion, if restrained, induces compressive stresses of a high enough magnitude to result in significant compression in the concrete after drying shrinkage and creep has occurred. • Formation of pores in the hardened structure or formation of gel state hydrates with low density is required for the expansion to coexist with chemical shrinkage. Advantages • The use of expansive concrete in place of reinforced concrete slab of highway steel bridge may have effect on diminishing of crack due to the introduction of chemical pre-stress and shrinkage decreasing effect. • The concept originally advanced was that if the ends of the pavement could be restrained while the concrete was curing and tending to expand, a compressive stress would be built up within the concrete itself. • Compression was to be obtained not by squeezing the ends of the pavement, but rather by simply restraining the ends as the concrete expanded • The important factor in expansion is not merely the hydration of expansive ingredients, but the formation of surrounding hydrates which the compressive force produced from the expansive ingredients are transmitted to. • As for durability, the expansive concrete given long time water curing does not change the expansive rate after it has reached a settled value. Polymer concrete(PC) • PC is composite material in which binder is synthetic organic polymer. • Long chain of monomers. • Improvising mechanical properties of the concrete. • Durability of the concrete. Types of polymer concrete (a) Polymer-Portland Cement Concrete (PPCC) (b) Polymer impregnated Concrete (PIC) (c) Polymer Concrete (PC). • PPCC : Polymer is incorporated into a Portland cement mix and a polymer network formed in situ during curing of the concrete.
• PIC : Precast conventional concrete is cured
and monomer is diffused through open cell and polymerized using chemical method. • PC : Resin concrete Case Study Application of the polymer concrete in repair of concrete structures • High sensitive to temperature. • Exhibits brittle behaviour at room temperatures • As temperature of test cycles increases, flexural elasticity decreases and failure becomes more ductile, making values of fracture toughness higher. • Decrease in mechanical strength. A large copper mine and refinery in the western united states had a dilemma. Their cell houses had experienced severe corrosion and structural degradation of the support columns for the tanks, each holding gallons of electrolyte. The refinery’s standard repair procedures was to remove corrosion products from the concrete and steel and then to top them with a polymer- modified Portland cement mortar. This standard repair method requires two to three days per column, and although temporarily effective, did not meet the company’s desire for a long-term solution. They decided upon a new approach using a polymer concrete, which is bisphenol A based-epoxy. This material is designed for maximum flowability, mechanical properties and chemical resistance. The cost of maintenance for polymer concretes per year of service life is significantly less than that of concrete with applied barrier coating, which may require multiple re- applications over the same number of years of service
Dunkelberg Et Al. - 2018 - Structural Concrete - The 2015 ACI-DAfStb Database of Shear Tests On Slender Prestressed Concrete Beams Without Stirrups-Overview and Evaluation of Current Design Approaches