UNIVERSIDAD AUTÓNOMA DE SAN LUIS POTOSÍ

FACULTAD DE CIENCIAS QUÍMICAS

TRANSFERENCIA DE MASA I

DRA. ERIKA PADILLA ORTEGA

CORPUS TORRES CECILIA IMELDA

LEIJA MÉNDEZ ERIKA
RANGEL GARCÍA PEDRO LUIS
ELABORACION DIAGRAMA PRESION
CONTRA COMPOSICION
Sistema NO ideal
componente 1: Metano
componente 2: Metil -acetato
Diagrama P xy

 Paso 1:
Paso 2:Realizamos una tabla de x1 y x2 con
valores de 0 a 1 con intervalos de 0.1
Paso 3: Calculamos gamma1 y gamma 2
(𝐴∗𝑥22 )
con la ecuación gamma=𝑒 donde A
es el coeficiente de actividad
Paso 4: calculamos presiones de saturación
(1y 2) con la Ec. De Antoine, a su vez
calcular P total
Paso 5: completamos la tabla con el
calculo de y1 y y2
Paso 6: Graficar
ELABORACION DIAGRAMA PRESION
CONTRA COMPOSICION
Sistema Ideal
componente 1:Benceno
componente 2:EtilBenceno
 Paso 1:
Paso 2:Realizamos una tabla de x1 y x2 con
valores de 0 a 1 con intervalos de 0.1
Paso 3:Calculamos presiones a las
diferentes composiciones
Paso 4: Calculamos Presión total
Paso 6: Calculamos y1 y y2
Paso 7: Graficamos
SISTEMA IDEAL TEMPERATURA
COMPOSICION
Sistema ideal

Compuesto 1: n-pentano
Compuesto 2:n- heptano
PRESION : 90 kpa
 Paso 1
Con las Constantes de Antonie calcular Psat

CONSTANTES n-pentano n-heptano

a 13.7667 13.8622
b 2451.88 2910.26
c 232.014 216.432
Ecuaciones para realizar la tabla
𝑏
(𝐴− )
 𝑃𝑠𝑎𝑡 = 𝑒 𝑇+𝐶

𝑃𝑠𝑎𝑡 1
𝐴𝑙𝑓𝑎 =
𝑃 𝑠𝑎𝑡 2

𝑃𝑠𝑖𝑠𝑡
𝑃𝑐𝑜𝑟𝑟𝑒𝑔𝑖𝑑𝑎 =
𝑥2
𝑥1 + ( )
𝑎𝑙𝑓𝑎
𝐴
𝑇𝑐𝑜𝑟𝑟𝑒𝑔𝑖𝑑𝑎 =
𝐿𝑁 𝑃𝑐𝑜𝑟𝑟𝑒𝑔𝑖𝑑𝑎 −𝐵 −𝐶

𝑥1 (𝑃𝑐𝑜𝑟𝑟𝑒𝑔𝑖𝑑𝑎)
𝑦1 =
𝑃𝑠𝑖𝑠𝑡𝑒𝑚𝑎

𝑦2 = (1 − 𝑦1)
x1 x2 T p1sat p2sat alfa12 Pcorr Tcorr y1 y2
0 1 90 469.889185 78.6458043 5.97475211 537.72769 95.8060308 0 1
0.1 0.9 95.8060308 537.72769 93.8365547 5.73047137 350.119429 78.019893 0.38902159 0.61097841
0.2 0.8 78.019893 350.119429 53.4393913 6.55171065 279.411547 69.4214206 0.62091455 0.37908545
0.3 0.7 69.4214206 279.411547 39.6958973 7.03880163 225.310508 61.6517375 0.75103503 0.24896497
0.4 0.6 61.6517375 225.310508 29.8681047 7.54351541 187.680442 55.3619619 0.8341353 0.1658647
0.5 0.5 55.3619619 187.680442 23.4437463 8.00556528 160.01236 50.0885605 0.88895755 0.11104245
0.6 0.4 50.0885605 160.01236 18.9677894 8.43600464 139.014214 45.5953329 0.92676143 0.07323857
0.7 0.3 45.5953329 139.014214 15.7288421 8.83817216 122.625215 41.7076377 0.95375167 0.04624833
0.8 0.2 41.7076377 122.625215 13.3061231 9.21569821 109.528745 38.2992676 0.97358885 0.02641115
0.9 0.1 38.2992676 109.528745 11.4429704 9.57170569 98.8524919 35.277067 0.98852492 0.01147508
1 0 35.277067 98.8524919 9.97618671 9.9088454 90 32.5709808 1 0
Se grafican los datos obtenidos.

T vs xy a P=90kPa Pen-Hep
120

100

80
Temperatura

60
x1
y1
40

20

0
0 0.2 0.4 0.6 0.8 1 1.2
xy
Sistema no ideal temperatura
composición
Datos del sistema:

T(K) 100 100

A 2.248 2.248
pentano A B n- heptano
a 13.7667 13.86622
b 2451.88 2910.26
c 232.014 216.432
lnPisat 6.381830687 4.66910972
Pisat 591.0086699 106.6027939
P (kPa) 104.4 104.4
 Calculamos Tsat 1 y 2 para obtener
una T promedio
𝐴 = 2.771 − ( 0.00523 𝑇 )

T1 sat T2 sat Tprom

36.8775918 99.283237 68.0804144
 Se realiza la siguiente tabla:
x1 x2 T A gama1 gama2 p2sat p1sat alfa12 p1satcorr tcorr A gamma1 p1sat y1 Y2
0 1 100 2.248 1 1 106.602794 591.00867 5.54402608 578.796323 99.0639074 2.25289576 1 103.733117 0 1
0.1 0.9 99.06390739 2.25289576 1 1 103.733117 578.796323 5.5796677 399.540867 83.284218 2.33542354 1 63.8264835 0.38270198 0.61729802
0.2 0.8 83.28421799 2.33542354 1 1 63.8264835 399.540867 6.25979758 318.487213 74.3516065 2.3821411 1 47.3650269 0.61012876 0.38987124
0.3 0.7 74.35160651 2.3821411 1 1 47.3650269 318.487213 6.72410075 258.349886 66.5448162 2.42297061 1 35.9372098 0.74238473 0.25761527
0.4 0.6 66.54481623 2.42297061 1 1 35.9372098 258.349886 7.18892444 215.94264 60.1656232 2.45633379 1 28.3487299 0.82736644 0.17263356
0.5 0.5 60.16562323 2.45633379 1 1 28.3487299 215.94264 7.61736558 184.569857 54.8001398 2.48439527 1 23.0218642 0.88395525 0.11604475
0.6 0.4 54.80013978 2.48439527 1 1 23.0218642 184.569857 8.01715514 160.641826 50.2160508 2.50837005 1 19.14388 0.92322889 0.07677111
0.7 0.3 50.21605084 2.50837005 1 1 19.14388 160.641826 8.39128881 141.895762 46.2417054 2.52915588 1 16.2297641 0.95140837 0.04859163
0.8 0.2 46.24170537 2.52915588 1 1 16.2297641 141.895762 8.74293436 126.872152 42.7520086 2.547407 1 13.9806232 0.9722004 0.0277996
0.9 0.1 42.75200858 2.547407 1 1 13.9806232 126.872152 9.07485669 114.596894 39.6540468 2.56360934 1 12.2048898 0.98790426 0.01209574
1 0 39.65404684 2.56360934 1 1 12.2048898 114.596894 9.38942468 104.4 36.8775918 2.5781302 1 10.7754982 1 0
Se grafican los datos: