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Once the exergy is wasted, it can never
be recovered. when we use energy (to
heat our homes, for example), we are not
destroying any energy; we are merely
converting it to a less useful form, a form
of less exergy.
2
Dead State
When system is in thermodynamic equilibrium with the
environment
Same temperature and pressure as surroundings, no kinetic or
potential energy, chemically inert, no unbalanced electrical,
magnetic, etc effects…
Exergy Forms
3
Now let’s determine the exergy of various forms of energy.
Exergy
Property
Availability or available work
Work = f(initial state, process path, final state)
Useful work
Upper limit on the amount of work a device can deliver
without violating any thermodynamic law.
(always a difference between exergy and actual work
delivered by a device)
System operating between high temp and dead state
4
Exergy of kinetic energy
Kinetic energy is a form of mechanical energy and can be
converted directly into work. Kinetic energy itself is the
work potential or exergy of kinetic energy independent of
the temperature and pressure of the environment.
Exergy of kinetic
energy:
r2
V
xke ke (kJ/kg)
2
5
Exergy of potential
energy
Potential energy is a form of mechanical energy and can be
converted directly into work. Potential energy itself is the
work potential or exergy of potential energy independent of
the temperature and pressure of the environment.
xpe pe gz (kJ/kg)
6
Useful Work
The work done by work producing devices is not always entirely in
a useable form. Consider the piston-cylinder device shown in the
following figure.
W P dV ( P P0 ) dV P0 dV
Wb, useful P0 dV 7
The actual work done by the gas is
W Wb, useful P0 dV
Wb, useful P0 (V2 V1 )
Wsurr P0 dV P0 (V2 V1 )
Wu W Wsurr
8
Reversible Work
Reversible work Wrev is defined as the maximum amount
of useful work that can be produced (or the minimum
work that needs to be supplied) as a system undergoes a
process between the specified initial and final states. This
is the useful work output (or input) obtained when the
process between the initial and final states is executed in
a totally reversible manner.
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Irreversibility
The difference between the reversible work Wrev and the
useful work Wu is due to the irreversibilities present during
the process and is called the irreversibility I. It is equivalent
to the exergy destroyed and is expressed as
th Wu
For heat engines and other II
work-producing devices and th , rev Wrev
12
Taking the heat transfer to be from the system to its
surroundings, the conservation of energy is
Ein Eout dEsystem
0 Q W dU
The work is the boundary work and can be written as
W P dV ( P P0 ) dV P0 dV
Wb, useful P0 dV
T0 Q
WHE th Q (1 ) Q Q T0
T T
Qnet Q
dS
T T
WHE Q T0 dS 13
Q WHE T0 dS
WHE T0 dS Wb, useful P0 dV dU
X X 2 X 1 m(2 1 )
( E E0 ) P0 (V V0 ) T0 ( S S0 )
r2 r2
V V1
(U U 0 ) P0 (V V0 ) T0 ( S S0 ) m 2 mg ( z2 z1 )
2
(2 1 )
(e e0 ) P0 (v v0 ) T0 ( s s0 )
r r
V22 V12 15
(u u0 ) P0 (v v0 ) T0 ( s s0 ) g ( z2 z1 )
2
Exergy of flow
The energy needed to force mass to flow into or out of a
control volume is the flow work per unit mass given by.
wflow Pv
The exergy of flow work is the excess of flow work done against
atmospheric air at P0 to displace it by volume v. According to
the above figure, the useful work potential due to flow work is
wflow, energy Pv P0 v 16
Thus, the exergy of flow energy is
xflow energy Pv P0 v ( P P0 )v
Flow Exergy
Since flow energy is the sum of nonflow energy and the flow
energy, the exergy of flow is the sum of the exergies of
nonflow exergy and flow exergy.
x flowing fluid xnonflowing fluid xflow exergy
r2
V
(u u0 ) P0 (v v0 ) T0 ( s s0 ) gz ( P P0 )v
2
r2
V
(u Pv) (u0 P0 v0 ) T0 ( s s0 ) gz
2
r2
V
(h h0 ) T0 ( s s0 ) gz
2
The flow (or stream) exergy is given by
r2
V
(h h0 ) T0 ( s s0 ) gz 17
2
The exergy of flow can be negative if the pressure is lower than
atmospheric pressure.
Q
T
Note in the above figure that entropy generation is always
by exergy destruction and that heat transfer Q at a location
at temperature T is always accompanied by entropy transfer
in the amount of Q/T and exergy transfer in the amount of
(1-T0/T)Q.
Note that exergy transfer by work is zero for systems that have
no work.
Exergy transfer by mass
Mass flow is a mechanism to transport exergy, entropy, and
energy into or out of a system. As mass in the amount m enters
or leaves a system the exergy transfer is given by
Exergy transfer by mass:
X mass m 20
Note that exergy transfer by mass is zero for systems that
involve no flow.
The Decrease of Exergy Principle and Exergy
Destruction
The exergy of an isolated system during a process always
decreases or, in the limiting case of a reversible process, remains
constant. This is known as the decrease of exergy principle and
is expressed as
X isolated ( X 2 X 1 )isolated 0
Exergy Destruction
Irreversibilities such as friction, mixing, chemical reactions, heat
transfer through finite temperature difference, unrestrained
expansion, non-quasi-equilibrium compression, or expansion
always generate entropy, and anything that generates entropy
always destroys exergy. The exergy destroyed is proportional to
the entropy generated as expressed as
X destroyed T0 Sgen 21
The decrease of exergy principle does not imply that the
exergy of a system cannot increase. The exergy change of a
system can be positive or negative during a process, but
exergy destroyed cannot be negative. The decrease of
exergy principle can be summarized as follows:
0 Irreversible proces
X destroyed 0 Reversible process
0 Impossible process
Exergy Balances
Exergy balance for any system undergoing any process can be
expressed as
Total Total Total Change in the
exergy
exergy
exergy
total exergy
entering leaving destroyed of the system
General:
X in X out X X
14 2 43 14destroyed
2 43 14 2system
43
Net exergy transfer Exergy Change 22
by heat, work, and mass destruction in exergy
General, rate
form:
General, unit-mass
basis:
( xin xout ) xdestroyed xsystem
whe T
re X&heat 1 0 Q&
T
X&work W&useful
X& m&
mass
X&system dX system / dt
For a reversible process, the exergy destruction term,
Xdestroyed, is zero. 23
Considering the system to be a general control volume and
taking the positive direction of heat transfer to be to the
system and the positive direction of work transfer to be
from the system, the general exergy balance relations can
be expressed more explicitly as
T0
1 T Qk W P0 (V2 V1 ) mi i me e X destroyed X 2 X 1
k
T1 T2 (25 287)oC
Tav 156oC
2 2
(156 273)K 429K
T v
s2 s1 Cv, ave ln 2 R ln 2
T1 v1
m3
kJ (287 273) K kJ 0.1
kg
0.690 ln 0.2598 ln
kg K (25 273) K kg K m3
0.8 kg
kJ
0.105
kg K
26
Wrev,in X 2 X 1
Therefore, the change in exergy and the reversible work are
identical in this case. Substituting the closed system exergy
relation, the reversible work input during this process is
determined to be
wrev,in 2 1
(u2 u1 ) P0 (v2 v1 ) T0 ( s2 s1 )
Cv,ave (T2 T1 ) P0 (v2 v1 ) T0 ( s2 s1 )
kJ m 3 kJ
0.690 (287 25)K 100 kPa(0.1 0.8)
kg K kg m3kPa
kJ
(25 273)K(0.105 )
kg K
kJ
142.1
kg
kg
Example 8-2
Steam enters an adiabatic turbine at 6 MPa, 600C, and 80
m/s and leaves at 50 kPa, 100C, and 140 m/s. The
surroundings to the turbine are at 25C. If the power output
of the turbine is 5MW, determine
(a)the power potential of the steam at its inlet conditions, in
MW.
(b) the reversible power, in MW.
(c)the second law efficiency.
28
The mass flow rate of the steam is determined from the
steady-flow energy equation applied to the actual process,
0 (steady)
E&in E&out E&systems
14 2 43 14 2 43
Rate of net energy transfer Rate of change
by heat, work, and mass of energy
r2 r2
V V
m&1 (h1 1 ) m&2 ( h2 2 ) W&out 0
2 2
m&1 m&2 0
m&1 m&2 m&
r2 r2
The work done by the turbine V V2
&
Wout m&(h1 h2 ) 1
and the mass flow rate are 2 2
W&out
m& 29
(h1 h2 ) ke
r r
Where: V22 V12
ke
2 2
(140 m/s) 2 (80 m/s) 2 1kJ/kg
2 2
2 1000 m /s
kJ
6.6
kg
From the steam tables:
� kJ
h 3658.8
P1 6 MPa ���
1
kg
��
T1 600o C �� kJ � kJ
s1 7.1693 h @ h 104.83
P0 100 kPa �� 0 o
�
� kg �
K �
f@25 C
kg
��
� kJ T0 25o C �� kJ
h 2682.4 s0 @ sf@25o C 0.3672
P2 50 kPa ��
�
2
kg �
� kg �
K
��
T2 100o C �� kJ
s2 7.6953
�
� kg �
K
30
W&out
m&
(h1 h2 ) ke
5 MW 1000 kJ/s �
� kg
� � 5.16
kJ � MW � s
(3658.8 2682.4 6.6)
kg
� kJ kJ �
(3658.8
� 104.83) (298 K )(7.1693 0.3672)
kg kg K�
kg �
& 5.16 �
�
s � (80m/s) � kJ/kg � �
1 2
�
� � 2 2 � �
�
� 2 1000
� m /s � �
kg � � MW �
kJ �
5.16 1533.3
� �
� � 7.91MW 31
s � kg �
�1000 kJ/s �
The power output of the turbine if there are no irreversibilities
is the reversible power and is determined from the rate form
of the exergy balance applied on the turbine and setting the
exergy destruction term equal to zero. 0 (steady)
X&in X&out X&destroyed X&system
0
14 2 43 14 2 43 14 2 43
Rate of net exergy transfer Rate of exergy Rate of change
by heat, work, and mass destruction of exergy
X&in X&out
m& W&
1 rev, out m& 2
W&rev, out m&( 2 1 )
m& (h1 h2 ) T0 ( s1 s2 ) ke pe
0
� kJ kJ �
(3658.8
� 2682.4) (298 K )(7.1693 7.6953)
kg � kg K�
kg �
W&rev, out 5.16 �
s � kJ �
�6.6 �
� kg �
kg � � MW �
kJ � ©
5.16 1126.5
� �
� � 5.81MW M A Boles, 2010
32
s � kg �
�1000 kJ/s �
The second-law efficiency is determined from
W& 5 MW
II 86.1%
&
Wrev 5.81MW
33