Professional Documents
Culture Documents
1
May 2009
SPECIAL SOLUTIONS
Fire PerformanceTechnologies
2
May 2009
Nexans Oil&Gas expertise towards
3
Total presentation
May 2009
Onshore Hypron®
Cables
HYPRON®
Aliphatic and aromatic hydrocarbons resistant
Current practices
Petrochemical & Refinery soils environments : Risk of insulation damages &
penetration of chemical products (acids, bases, aliphatic and aromatic
hydrocarbons) towards the conductors.
== Cables are protected against external chemical products by a
conventional lead sheath.
4
Total presentation
May 2009
Onshore Hypron®
Cables
HYPRON®
Aliphatic and aromatic hydrocarbons resistant
HYPRON®
5
Total presentation
May 2009
Onshore Hypron®
Cables
Design
AluPE tape
Lead sheathing HDPE sheath
PA sheath
6
Total presentation
May 2009
Onshore Hypron®
Cables
Design
AluPE tape
Lead sheathing HDPE sheath
PA sheath
7
Total presentation
May 2009
Onshore Hypron®
Cables
Polyamides are known for their resistance to a wide range of chemicals, different
Properties
types of oil and greases.
Standard HFFR
Physical properties Standard
polyamide Polyamide
Density (g/cm3) ISO 1183 1,13 1,17
Moisture absorption
- Humidity absorption (23°C / 50% RH) ISO 62 2,5% 2,5%
- Water absorption (23°C) 9,5% 9,0%
Mechanical properties
- Tensile modulus (@ 1 mm/min)
3150 MPa 3800 MPa
- Yield stress (@ 50 mm/min) ISO 527-1
85 MPa 80 MPa
- Nominal strain at break (@ 50
45% 50%
mm/min)
Flammability
- at thickness @ 1,6 mm UL94 - Pass (V-0)
- at thickness @ 0,38 mm - Pass (V-0) 8
Total presentation
May 2009
Hypron®
Electrical properties of insulation
Insula tion resista nce
(IRM 903 oil)
32000 160°C
EI 2046 (Lead)
EI 2048 (Hypron)
28000 140°C
24000 120°C
Temperature
20000 100°C
12000 60°C
8000 40°C
4000 20°C
0
0 100 200 300 400 500 600 700
Time (hours)
9
Total presentation
May 2009
Onshore Hypron®
Cables
Objectives: Ageing tests
Remain mechanical properties of insulation materials above 50% vs. initial values
Mechanical properties evolution:
Tensile strength (MPa)
Elongation at break (%)
Standard references:
EN 60811-1-1: mechanical properties measurement
No sign of gases or liquid inside the cable after tests ….
Construction:
Core / insulation 4 x 2,5mm² XLPE with or without mica tape
Bedding
Hypron technology: Alu/PE tape + HDPE+ PA6
Outer sheath: PVC
10
Total presentation
May 2009
Onshore Hypron®
Cables
Comparison:
Ageing test in Oil IRM 903 @ 90°C Ageing tests
Evolution of Tensile strength (MPa) and Elongation at break (%) on insulation
materials
Compositions:
4 x 2,5mm² XLPE – Bedding – AluPE – HDPE - PA6 - PVC
4 x 2,5mm² mica/XLPE
Elongation at break -(%)
Bedding - AluPE - HDPE - PA6 - Tensile
PVC strength (MPa)
500 20.0
450 18.0
400 16.0
350 14.0
300 12.0
150 6.0
0 0.0
0 10 20 30 40 50 60 70 80 0 20 40 60 8011
Weeks Weeks
May 2009
Onshore Hypron®
Cables
Technical data sheet
HYPRON®
Aliphatic and aromatic hydrocarbons resistant
12
Total presentation
May 2009
Onshore Hypron® Cables
LV cable according to IEC 60502-1
Low Voltage cable
Lead sheath Hypron® Variation (%)
(3 x 150 mm²)
Diameter (mm) 55 50 -9.1%
Weight (kg) 11306 8761 -22.5%
Price (€) - - -13.0%
Instrumentation cable
Lead sheath Hypron® Variation (%)
(20 pairs 1mm²)
Diameter (mm) 45,6 44,7 -2,0%
Weight (kg) 5349 3026 -43,4%
Price (€) - - -25,0%
Advantages
Fire resistant (IEC 60331) Halogen free (IEC 60754-1)
Easier installation
Longer length per drum Fire retardant (IEC 60332-3-22(A)) Low toxicity
MV splicing :
long length available should permit single length laying
15
May 2009
Qualification
Directive 2002/95/EC of the European Parliament and of the Council of 27 January 2003 on the restriction of the use of
certain hazardous substances in electrical and electronic equipment
The purpose of this Directive is to approximate the laws of the Member States on the restrictions of the use of hazardous
substances in electrical and electronic equipment and to contribute to the protection of human health and the
environmentally sound recovery and disposal of waste electrical and electronic equipment.
Article 3
Definitions
For the purposes of this Directive, the following definitions shall apply:
(a) "electrical and electronic equipment" or "EEE" means equipment which is dependent on electric currents or electromagnetic
fields in order to work properly and equipment for the generation, transfer and measurement of such currents and
fields falling under the categories set out in Annex IA to Directive 2002/96/EC (WEEE) and designed for use with a
voltage rating not exceeding 1000 volts for alternating current and 1500 volts for direct current;
Article 4
Prevention
Member States shall ensure that, from 1 July 2006, new electrical and electronic equipment put on the market does not contain
lead, mercury, cadmium, hexavalent……
On the basis of a proposal from the Commission, the European Parliament and the Council shall decide, as soon as scientific
evidence is available, and in accordance with the principles on chemicals policy as laid down in the Sixth Community
Environment Action Programme, on the prohibition of other hazardous substances and the substitution thereof by
more environment-friendly alternatives which ensure at least the same level of protection for consumers.
16
May 2009
Qualification
MANUAL
DEP 32.37.20.10-Gen.
July 1999
(DEP Circulars 02/01 and 83/03 have been incorporated)
An extruded bedding of high density polyethylene compound meeting the requirement of ASTM D1248, type 3, class C, category 5, grade J5 shall be applied
over the collective screen.
The bedding shall be bounded to the plastic coated aluminium foil. A single layer of round galvanized steel wire armored shall be applied spirally over the
polyamide protective sheath. A high density polyethylene compound meeting the requirements of ASTM D 1248, Type 3, Class C, Category 5, Grade J5 shall be
applied over the galvanized steel wire armor (see clause 13.3.3) to the dimensions specified in Table 2.
18
May 2009
Nexans Oil&Gas expertise towards
Fire
Performances
Technologies
19
May 2009
Why Fire Safety?
20
May 2009
Introduction
Fire safety & cables
What is fire ?
Polymer degradation
Radical formation
FUEL
21
May 2009
Introduction
Fire safety & cables
Fire extinction
and escape
possible
Flash over
Start of fire &
Ignition propagation
Time
Role of the Role of the
fire reaction fire resistance
(no propagation) ( circuit intregrity )
22
May 2009
Introduction
Fire safety & cables
23
May 2009
Nexans expertise in
Fire safety
Product development
Materials & Designs
25
May 2009
Fire reaction
26
May 2009
Fire reaction
Oxygen
Heat
Polymer particles
in vapor phase
(fuel)
Thermal degradation
of the polymer
27
May 2009
Fire reaction
Dilution of the
gaz vapor phase
from sheath
combustion
28
May 2009
Fire reaction
Particle trap
Particle stabilization
29
May 2009
Fire reaction
Particle trap
Vapor phase
absorption
30
May 2009
Fire reaction
Barrier effect
31
May 2009
Fire reaction
Thermal insulation
32
May 2009
Fire reaction
33
May 2009
Fire reaction
34
May 2009
Fire reaction
35
May 2009
Fire reaction
36
May 2009
Fire reaction
37
May 2009
International standards
International European Spain France Germany Italy UK China USA BELGIUM
IEC/ISO EN UNE UTE VDE CEI BS/LUL GB/T UL/IEEE/ASTM NBN EN
Flame IEC 60332-1-1
NF C 32 070 Cat. BS EN 50265
Retardant IEC 60332-1-2 EN 50265 UNE EN 50265
C2
VDE 472- 804B CEI 20-35
(BS 4066/1)
GB/T 18380-1 UL 44 NBN EN 50265
(cable) IEC 60332-1-3
EN 50266-2-1
IEC 60332-3-22 (A)
Fire Retardant EN 50266-2-2
IEC 60332-3-23(B) BS EN 50266
(bunched IEC 60332-3-24(C)
EN 50266-2-3 UNE EN 50266 NF C 32 072 VDE 472-804C CEI 20-22/3
(BS 4066/3)
GB/T 18380-3 IEEE 383 NBN C30-004 F2
cables) EN 50266-2-4
IEC 60332-3-25(D)
EN 50266-2-5
Fire Resistant FR 2
DIN 4102-12
(cable system) NBN 713 020
IEC 60331-11 UNE EN 50200 FR 1
Fire Resistant (750°C) EN 50200 UNE EN 50362 NF C 32 070 Cat. BS 6387 C1 NBN EN 50200
VDE 472- 814 CEI 20-36 GB/T 19216
(cable) IEC 60331-12 EN 50362 UNE 20-431 CR1 BS 8434-1 & 2 C2 NBN EN 50362
( 830°C) (IEC 60331) C3
ASTM E 662
Smoke density
IEC 60695-6-30 NF C 20902-1 NFPA 258
chamber ISO 5659-2 NF C 20902-2
BS 6401
ASTM D 2843
(static method) (XP2 chamber)
Smoke opacity NF X 10702
BS EN 50268
(material- IEC 61034 EN 50268 UNE EN 50268 NF C 20452 VDE 472- 816 CEI 20-38
(BS 7622-1&2)
GB/T 17651 ASTM D 2843 NBN EN 50268
cables) NF C 32073
Gases and
NF X 70100
smoke Toxicity
IEC 60754-1 EN 50267 UNE EN 50267 NF X 70101 CEI 20-37 GB/T 17650 NBN EN 50267
(material - NF C 20454
cables)
Gases and
smoke
BS EN 50267
Corrosivity IEC 60754-2 EN 50267 UNE EN 50267 NF C 20454 VDE 472-813 CEI 20-37
(BS 6425 - 1)
GB/T 17650 NES 713 NBN EN 50267
(material -
cables)
Oxygen Index ISO 4589 NF T 51071 BS 2782
Temperature
IEC 60216 VDE 304-21
Index 38
May 2009
Reaction to fire
Standard: IEC 60332-1, NF C 32070 test n°1 (Cat. C2), BS 4066-1, VDE 472/804 B,
EN 50265-1
Test: Resistance to vertical flame propagation
Objective:
Limited flame propagation on wire or cable
No flaming droplets
Products concerned: Insulated wires or cables
Test conditions:
Insulated wire or cable sample: 600 mm
Test sample fixed vertically in a metallic screen
Source of heat: 1 kW propane burner inclined at 45°
Time for the flame application: 1 to 8 min
Depending on sample diameter
Recommended values:
The minimum length of uncharred surface: 50 mm under top support
Fire test on video
39
May 2009
Reaction to fire
TEST METHOD
≠ SIMULATION
OF REAL FIRE
Air 5000l/min
41
May 2009
Mastering
Fire Resistance
42
May 2009
Mastering the
standards
Flame tests
43
May 2009
Mastering the
standards
Oven tests
44
May 2009
Fire resistant test
46
May 2009
Fire resistant test
Standard: EN 50200
Test: Resistance to fire with mechanical shocks
Objective: Maintain circuit integrity
Products concerned: Electrical power, control, data or communication
cables and optical fibre cables (Ø 20 mm)
Test conditions:
Cable mounted in a U form on a non combustible wall
Flame temperature: 830°C
Mechanical shocks: 1 shock / 5 min
Rated voltage: Up to 0.6 / 1 kV (electrical cables)
47
May 2009
Fire resistant test
48
May 2009
Mastering the
standards
Summary of the qualitative description of each fire resistant test
Temperature Duration Cable
Standard Fire type Shock Water
(°C) (min) length
50
May 2009
Fire safety
Smoke & Toxicity
Ambient air
modification
98% of victims are died by asphyxia
51
May 2009
Phenomenon
understanding
Smoke
Smoke due to partially burned particles :
52
May 2009
Smoke emission
54
May 2009
Toxicity
Ammonia 5,33
has a lower toxicity
Hydrogen sulphide 5,33
index Carbon monoxide 1,00
Toxicity index
May 2009
+ NOx, Dioxins, aldehydes, …. 56
Corrosivity
(Reminder : 1 kG of PVC burnt produces about 2 liter of Hydrochloric Acid of “Xi” concentration)
57
May 2009
Bringing
Solutions
for
the end user
58
May 2009
Fire safety
Smoke & toxicity
60
May 2009
References
61
May 2009
Africa
• Algeria
Sonatrach : Arzew LNG Equatorial Guinea
Sonatrach : Skikda Refinery
Bechtel - LNG
Sonatrach Hassi Messaoud OilField
Tunisia
• Ivory Coast
SIR refinery- Abidjan Hasdrubal LNG-Petrofac
El Borma Field - SITEP
Nigeria
• Libya Daewoo/Mobil - Refinery
Great man made river –Marubeni
SOC-Tripoli-Mehlita Gas Pipeline. Exxon/Mobil - Refinery
NLNG Projects-Shell /KBR
• Angola
Total Dalia Gas treatment OML 58 - Saipem
62
May 2009
Americas
• Peru • USA
Camisea gas development I & II Calpine
Talara Refinery – PlusPetrol/Tecnicas.
Shell Martinas (California)
• Venezuela Shell (Gulf of Mexico)
Contrina-PDVSA
Sincor Petrochem- Total
• Brasil
Petrobras P 36,38,42,52,54,58,61,62
• Colombia Comperj Petrochem
Cerro Matoso Mining Refinery- Bechtel Pernambuco Refinery
Cartagena Refinery-CB&I
Pacific Rubiales Energy – Quifa field •Mexico
Ecopetrol-Chichimene •Pemex - Danjos Refinery
• Ecuador •Bajio Gas treatment - Bechtel
Repsol YPF Pipeline upgrade
63
May 2009
CIS
• Georgia
• Azerbaijan Tbilissi metering: AES
ACG Terminal: KBR/ AIOC
BTC pipelines : Botas
SCP pipelines: Petrofac
• Russia
• Kazakhstan Kharyga 1 field: Petrofac
Sakhaline 1 & 2 gas treatment
Kashagan O&G treatment - Agip KCO
TCO :Parson-FluorDaniel Prirazlomnoe Platform
Caspian pipeline - Tefken Gazprom : Aztrakan – Linegaz
Tuapse Refinery - Rosneft
• Uzbekistan
• Turkmenistan
Fergana refinery - Tefken Turkmenbashi refinery :
FosterWheeler
South Yoloten refinery - Petrofac
64
May 2009
Central Asia
Iran Turkey
Petrofac/Elf : Dorood Tupras: refinery
Technip/Olefin 9th, LNG: Botas
Amir Kabir, NPCC-Soroosh BTC (Botas) – Tefken
Pidec:Abadan Refinery
Hyundai /Elf Balal
South Pars 4&5: ENI
NIGC/OIEC : 6 Compressor Stations
65
May 2009
Middle East
• Bahrein • U.A.E.
Alstom/Bapco Dolphin: McDermott
• Iraq
ADCO/Technip : NEB
Suleimaniyah: ABB
South Gaz Co :repairs GASCO- ABICS : Cegelec
Basra Export Terminal : Foster Wheeler
ADMAOPCO – Umm Shaif Gas Injection plant
• Qatar
QatarChemical:LG Benzene
• Yemen
Technip/KBR: Q.Chem 1 Atuf field facilities upgrade: Total
Shell Pearl GTL- KBR/Saipem
YemGas –LNG Terminal – Technip
• Saudi Arabia
Aramco-Maintenance & Repairs Asharq Masood:Nexen Petroleum
Operations
• Kuwait
NPC : MAA refinery & OLK2
66
May 2009
Asia / Pacific
• Vietnam
Dong Quat refinery – technip
• Thailand.
• Indonesia PTTAR – EXXON Refineries upgrades
West Natuna refinery – Conoco
Texaco Refinery. PPTEP – ARTHIT blocks development
Balikpapan Expensions - TOTAL
• Australia
DARWIN LNG - Bechtel
67
May 2009
Europe
• Holland • France.
Shell Refinery ( Pernis ) TOTAL Refinery & Petrochem ( Gonfreville)
TOTAL Refinery ( Lyon )
• Spain
CEPSA – Cartagena refinery TOTAL Refinery ( Nantes )
ARKEMA INEOS ( Fos / Mer )
• Germany
TOTAL Refinery ( Leuna )
• Norway
Statoil Refinery ( Oslo)
• UK
Milford Haven Terminal
• Belgium
FINA Refinery & Petrochem ( Antwerp )
BASF Petrochem ( Antwerp )
68
May 2009
69
May 2009
Thank you for your attention
www.nexans.com
70
May 2009