CE6002

CONCRETE TECHNOLOGY
 UNIT I CONSTITUENT MATERIALS

Cement
Different types
Chemical composition and Properties
Tests on cement-IS Specifications
Aggregates
Classification
Mechanical properties and tests as per BIS
Grading requirements
Water
Quality of water for use in concrete.
UNIT II CHEMICAL AND MINERAL ADMIXTURES
Accelerators
Retarders
Plasticisers
Super plasticizers
Water proofers
Mineral Admixtures like
Fly Ash
Silica Fume
Ground Granulated Blast Furnace Slag and
Metakaoline
Their effects on concrete properties
 UNIT III PROPORTIONING OF CONCRETE
MIX
Principles of Mix Proportioning
Properties of concrete related to Mix Design
Physical properties of materials required for Mix
Design
Design Mix and Nominal Mix
BIS Method of Mix Design
Mix Design Examples
 UNIT IV FRESH AND HARDENED
PROPERTIES OF CONCRETE
Workability
Tests for workability of concrete
Slump Test and Compacting factor Test
Segregation and Bleeding
Determination of Compressive and Flexural strength as per
BIS
Properties of Hardened concrete
Determination of Compressive and Flexural strength
Stress-strain curve for concrete
Determination of Youngs Modulus.
 UNIT V SPECIAL CONCRETES
Light weight concretes
High strength concrete
Fibre reinforced concrete
Ferrocement
Ready mix concrete
SIFCON
Shotcrete
Polymer concrete
High performance concrete
Geopolymer Concrete
 TEXTBOOKS:
1.Gupta.B.L., Amit Gupta, "Concrete
Technology", Jain Book Agency, 2010.
2.Shetty,M.S, "Concrete Technology", S.Chand
and Company Ltd, New Delhi, 2003
 REFERENCES:

1.Santhakumar,A.R; "Concrete Technology" ,

Oxford University Press, New Delhi, 2007
2.Neville, A.M; "Properties of Concrete", Pitman
Publishing Limited, London,1995
3.Gambir, M.L; "Concrete Technology", 3rd Edition,
Tata McGraw Hill Publishing Co Ltd, New Delhi,
2007
4.IS10262-1982 Recommended Guidelines for
Concrete Mix Design, Bureau of Indian
Standards, New Delhi, 1998
 UNIT I
CONSTITUENT MATERIALS
CEMENT

Cement is a well-known building material and

has occupied an indispensable place in
construction works.
A cement is a binder, a substance that sets and
hardens and can bind other materials together.
There are variety of cements available in the
market and each type is used under certain
conditions due to its special properties.
 A mixture of cement and sand when mixed with
water to form a paste is known as cement
mortar whereas the composite product obtained
by mixing cement, water and an inert matrix of
sand and gravel or crushed stone is called
cement concrete.
 The cement commonly used is Portland
cement and the fine and coarse aggregates
used are those that are usually obtainable,
from nearby sand, gravel or rock deposits.

In order to obtain a strong, durable and

economical concrete mix, it is necessary to
understand the characteristics and
behaviour of the ingredients.
 Portland cement is defined as hydraulic
cement, i.e. a cement that not only hardens
by reacting with water but also forms a water-
resistant product.

The ingredients of concrete can be classified

into two groups, namely active and inactive.
 The active group consists of cement and
water, whereas the inactive group comprises
fine and coarse aggregates.
The inactive group is also sometimes called
the inert matrix.
Although all materials that go into a concrete
mixture is essential, cement is by far the most
important constituent because it is usually the
delicate link in the chain.
 The function of cement is, first to bind the sand
and coarse aggregates together and second to
fill the voids in between sand and coarse
aggregate particles to form a compact mass.

Although cement constitutes only about 10

percent of the volume of the concrete mix, it is
the active portion of the binding medium and the
only scientifically controlled ingredient of
concrete.
 Joseph Aspdin patented a similar material,
which he called Portland cement, because
the render made from it was in color similar
to the prestigious Portland stone.
CHEMICAL COMPOSITION

The raw materials used for the manufacture of

cement consist mainly of lime, silica, alumina
and iron oxide.
These oxides interact with one another in the
kiln at high temperature to form more complex
compounds.
The relative proportions of these oxide
compositions are responsible for influencing
the various properties of cement, in addition to
rate of cooling and fineness of grinding.
 The table below shows the approximate
oxide composition limits of ordinary Portland
Cement.
Oxide Percent content
CaO 60-67
SiO2 17-25
Al2O3 3.0-8.0
Fe2O3 0.5-6.0
MgO 0.1-4.0
Alkalies (k2O, Na2O) 0.4-1.3
SO3 1.3-3.0
Functions of cement ingredients
Lime:
Controls strength and soundness. Its deficiency
reduces
strength and setting time.
Silica:
Gives strength due to the formation of dicalcium and
tricalcium silicates. Excess of it causes slow setting.
Alumina:
Responsible for quick setting. It acts as a flux and
lowers the clinkering temperature. If in excess it
lowers the strength.
 Calcium Sulphate: Present in the form of gypsum
and its function is to increase the initial setting time
of cement.
Iron Oxide: Imparts color and help in fusion of
different ingredients of cement.

Magnesia: Imparts color and hardness. If in excess

causes cracks and makes cement unsound.
 Sulphur: A small amount is used in making sound
cement. If in excess causes cement to become
unsound.

Alkalies: If excess in cement, causes alkali- aggregate

reaction (aggregates having silica react with the alkali
hydroxides in concrete, causing expansion and
cracking ) , efflorescence and discoloration when used
in concrete.
 The oxides present in the raw materials
when subjected to high clinkering
temperature combine with each other to form
complex compounds.
The identification of the major compounds is
largely based on R.H. Bogues work and
hence it is called Bogues Compounds.
The table below lists the major compounds.
Name of the Compound Formula Abbreviated Formula

Tricalcium silicate 3 CaO.SiO2 C 3S

Dicalcium silicate 2CaO.SiO2 C 2S

Tricalcium Aluminate 3CaO.Al2O3 C 3A

Tetracalcium 4CaO.Al2O3.Fe2O3 C4AF

aluminoferrite

It is to be noted that for simplicty sake abbreviated notations are

used.
C stands for CaO, S for SiO2, A for Al2O3, F for Fe2O3 and H for H2O
 In addition to the four major compounds, there
are many minor compounds formed in the
kiln.
The influence of these minor compounds on
the properties of cement or hydrated
compounds is not significant.
Two of the minor oxides namely K2O and
Na2O referred to as alkalis in cement are of
some importance.
 Tricalcium silicate and dicalcium silicate
are the most important compounds
responsible for strength.

Together they constitute 70 to 80 percent of

cement.
HYDRATION OF CEMENT

Anhydrous cement does not bind fine and

coarse aggregate.
It acquires adhesive property only when mixed
with water.
The chemical reactions that take place
between cement and water is referred as
hydration of cement.
The chemistry of concrete is essentially the
chemistry of the reaction between cement and
water.
 On account of hydration certain products are
formed.
These products are important because they
have cementing or adhesive value.
The quality, quantity, continuity, stability and
the rate of formation of the hydration
products are important.
Anhydrous cement compounds when mixed
with water, react with each other to form
hydrated compounds of very low solubility.
 The hydration of cement can be visualised in two
ways.
The first is through solution mechanism.
In this the cement compounds dissolve to
produce a supersaturated solution from which
different hydrated products get precipitated.
The second possibility is that water attacks
cement compounds in the solid state converting
the compounds into hydrated products starting
from the surface and proceeding to the interior of
the compounds with time.
 It is probable that both through solution and
solid state types of mechanism may occur
during the course of reactions between
cement and water.
The former mechanism may predominate in
the early stages of hydration in view of large
quantities of water being available, and the
latter mechanism may operate during the later
stages of hydration.
HEAT OF HYDRATION

The reaction of cement with water is

exothermic.
The reaction liberates a considerable quantity
of heat.
This liberation of heat is called heat of
hydration.
 On mixing cement with water, a rapid heat
evolution, lasting a few minutes, occurs.
The heat evolution is probably due to the reaction
of solution of aluminates and sulphates
(ascending peak A).
This initial heat evolution ceases quickly when the
solubility of aluminate is depressed by
gypsum(descending peak A).
Next heat evolution is on account of formation of
ettringite and also may be due to the reaction of
C3S (ascending peak B)
HYDRATION OF C3S
The chemical reaction of C3S with water can be
expressed as
C3S + water C-S-H + C-H +Heat
Where C-S-H is calcium silicate hydrate and C-H is
calcium hydrate.
C-S-H calcium silicate hydrate constitutes 50-60% of
the solids in the paste.
It forms a continuous binding matrix.
It is amorphous and fibrous and hence has a large
surface area.
It is an important factor for the strength development
of cement paste.
 C-H calcium hydrate makes up about 20% of
the solids in the paste.
It exists in the form of thick, crystalline
hexagonal plates and is embedded in the
C-S-H matrix.
Its growth fills the pore spaces.
It does not significantly contribute to strength.
Its leaching causes white patches and
efflorescence.
HYDRATION OF C2S

The hydration of C2S is similar to the hydration

of C3S.
The same products are generated.
However, C2S reacts slowly and hence
generates less heat.
It contributes to strength development at latter
stages.
HYDRATION OF C3A

This hydration reaction produces a substance

called ettringite as follows:
C3A + gypsum + water ettringite +heat
C3A+ettringite+water monosulphoaluminate
If the amount of gypsum is too little, C3A will
react fast and can cause a flash set.
On the other hand, too much gypsum will delay
setting and cause undue expansion.
As shown in the figure, ettringite is a crystalline and
needle like substance.
 It constitutes about 1020% of the solid
content.
It is a long, slender and prismatic crystal and is
stable only in the presence of gypsum.
It plays a minor role in strength development
but contributes considerably to durability.
Monosulphoaluminate is a stable hydration
product.
It is fairly crystalline.
 The figure shows thin irregular plates clustered
like a flower.
Hence it fills the pores and can reform ettringite
in the presence of sulphate ions.
HYDRATION OF C4AF

The hydration of C4AF is similar to that of C3A,

the same products are formed.

However, C4AF reacts slowly and hence

generates less heat and combines well with
gypsum.
 In summary, the hydration of cement occurs at
the surface of the grain.
All the compounds react simultaneously;
a compound reaction takes place.
The smaller grains hydrate first and the larger
grains become smaller while they hydrate.
Some very large grains never hydrate
completely.
 The hydration rate has the following hierarchy:
C3A, C3S, C4AF and C2S
Ettringite is formed first, followed by C-H and
C-S-H.
There is no change in the total volume of the
cement paste as a result of hydration.
After hydration, the paste composition consists of
both the solid and water phases.
Thus hydration is a chemical reaction.
The Bogue compounds react to form C-S-H, C-H,
ettringite, monosulphoaluminate and heat.
CEMENT TYPES
Ordinary Portland Cement
Ordinary Portland Cement 33 Grade
IS 269:1989
Ordinary Portland Cement 43 Grade
IS 8112: 1989
Ordinary Portland Cement 53 Grade
IS 12269:1987
Rapid hardening cement IS 8041: 1990
Extra Rapid Hardening Cement
Sulphate Resisting Cement IS 12330:1998
Portland Slag Cement IS 455: 1989
 Quick Setting Cement
Super Sulphated Cement - IS 6909 :1990
Low Heat Cement IS 12600: 1989
Portland Pozzolana Cement
IS 1489(Part I) 1991 (Flyash based)
IS 1489(PartII) 1991 (Calcined based)
Air Entraining Cement
Coloured Cement : White Cement
IS 8042:1989
 Hydrophobic Cement IS 8043 : 1991
Masonry Cement IS 3466: 1988
Expansive Cement
Oil Well Cement IS 8229:1986
Rediset Cement
Concrete Sleeper grade Cement
IRS-T 40: 1985
High Alumina Cement IS 6452:1989
Very High Strength Cement
ORDINARY PORTLAND CEMENT

Prior to 1987, there was only one grade of

OPC which was governed by IS 269-1976.
After 1987 higher grade cements were
introduced in India.
The OPC was classified into three grades,
namely 33 grade, 43 grade and 53 grade
depending upon the strength of the cement at
28 days when tested as per IS 4031-1988.
 It has been possible to upgrade the qualities
of cement by using
high quality limestone
Modern equipments
Closer on line control of constituents
Maintaining better particle size
distribution
Finer grading
Better packing
RAPID HARDENING CEMENT

This is similar to OPC.

As the name indicates it develops strength
rapidly and as such it may be more appropriate
to call it as high early strength cement.
Rapid hardening cement develops strength at
the age of three days, the same strength as
that is expected of ordinary portland cement at
seven days.
 The rapid rate of development of strength is
attributed to
the higher fineness of grinding (specific

surface not less than 3250 sq.cm per

gram)
higher C3S

lower C2S content

A higher fineness of cement particles expose

greater surface area for action of water and also
higher proportion of C3S results in quicker
hydration.
 Consequently, rapid hardening cement gives
out much greater heat of hydration during the
early period.

Therefore, rapid hardening cement should not

be used in mass concrete construction.
 The use of rapid hardening cement is
recommended in the following situations:
In pre-fabricated concrete construction

where formwork is required to be removed

early for re-use elsewhere.
Road repair works

In cold weather concrete where the rapid

rate of development of strength reduces the

vulnerability of concrete to the frost
damage.
EXTRA RAPID HARDENING CEMENT

It is obtained by inter grinding calcium

chloride with rapid hardening Portland
Cement.

The normal addition of calcium chloride

should not exceed 2 percent by weight
of the rapid hardening cement.
 It is necessary that the concrete made by
using extra rapid hardening cement should
be transported, placed and compacted and
finished within about 20 minutes.

It is also necessary that this cement should

not be stored for more than a month.

This cement accelerates the setting and

hardening process.
 A large quantity of heat is evolved in a very
short time after placing.
The acceleration of setting, hardening and
evolution of this large quantity of heat in the
early period of hydration makes the cement
very suitable for concreting in cold weather.
The strength is about 25 percent higher than
that of rapid hardening cement at one or two
days and 1020 percent higher at 7 days.
 The gain of strength will disappear with age and
at 90 days the strength of extra rapid hardening
cement or the OPC may be nearly the same.
There is some evidence that there is small
amount of initial corrosion of reinforcement
when extra rapid hardening cement is used, but
in general, this effect does not appear to be
progressive and as such no harm in using this
cement in reinforced work.
However, its use in prestress concrete
construction is prohibited.
SULPHATE RESISTING CEMENT
Ordinary Portland cement is susceptible to the
attack of sulphates, in particular to the action of
magnesium sulphate.
Sulphates react both with the free calcium
hydroxide in set-cement to form calcium
sulphate and with hydrate of calcium aluminate
to form calcium sulphoaluminate, the volume of
which is approximately 227% of the volume of
the original aluminates.
Their expansion within the frame work of
hardened cement paste results in cracks and
subsequent disruption.
 Solid sulphate do not attack the cement
compound.
Sulphates in solution permeate into
hardened concrete and attack calcium
hydroxide, hydrated calcium aluminate and
even hydrated silicates.
This is known as sulphate attack.
 Sulphate attack is greatly accelerated if
accompanied by alternate wetting and drying
which normally takes place in marine
structures in the zone of tidal variations.

To remedy the sulphate attack, the use of

cement with low C3A content is found to be
effective.
 Such cement with low C3A and
comparatively low C4AF content is known
as Sulphate Resisting Cement.
In other words, this cement has a high
silicate content.
The specification generally limits the C3A
content to 5 percent.
In many of its physical properties, sulphate
resisting cement is similar to OPC.
 The use of sulphate resisting cement is recommended
under the following conditions:
Concrete to be used in marine condition
Concrete to be used in foundation and
basement, where soil is infested with sulphates
Concrete used for fabrication of pipes which
are likely to be buried in marshy region or
sulphate bearing soils.
Concrete to be used in the construction of
sewage treatment works.
PORTLAND SLAG CEMENT

Portland slag cement is obtained by mixing

portland cement clinker, gypsum and
granulated blast furnace slag (a waste product
from blast furnaces) in suitable proportions and
grinding the mixture to get a thorough and
intimate mixture between the constituents.

Portland blast furnace cement is similar to OPC

with respect to fineness, setting time, soundness
and strength.
 It is generally recognized that the rate of
hardening of Portland blast furnace slag
cement in mortar or concrete is somewhat
slower than that of OPC during the first 28
days, but thereafter increases, so that at 12
months the strength becomes close to or
even exceeds those of Portland cement.
The heat of hydration of Portland blast
furnace cement is lower than that of OPC.
 So this cement can be used in mass
concrete structures with advantage.

However, in cold weather the low heat of

hydration of Portland blast furnace cement
coupled with moderately low rate of strength
development, can lead to frost damage.
 Extensive research shows that the presence of
GGBS leads to the enhancement of the
intrinsic properties of the concrete both in fresh
and hardened states.
The major advantages currently recognised
are:
Reduced rate of hydration
Refinement of pore structure
Reduced permeability
Increased resistance to chemical attack.
QUICK SETTING CEMENT

This cement as the name indicates sets very

early.
The early setting property is brought out by
reducing the gypsum content at the time of
clinker grinding.
This cement is to be mixed, placed and
compacted very early.
 It is used mostly in under water
construction where pumping is involved.

Use of quick setting cement in such

conditions reduces the pumping time and
makes it more economical.

It is also used in grouting operations.

SUPER SULPHATED CEMENT

It is manufactured by grinding together a

mixture of 8085 percent granulated slag,
1015 percent hard burnt gypsum and
about 5 percent Portland cement clinker.

The product is ground finer than that of OPC.

Specific surface must not be less than 4000

cm2per gm.
 It has a low heat of hydration of about 40
45 calories/gm at 7 days and 4550 at 28
days.
It has high sulphate resistance.
Because of this property, it is used in
foundation and marine constructions.
It is used in fabrication of reinforced
concrete pipes which are likely to be buried
in sulphate bearing soils.
LOW HEAT CEMENT

A low heat evolution is achieved by

reducing the contents of C3S and C3A
which are the compounds evolving the
maximum heat of hydration and
increasing C2S.

A reduction of temperature will retard the

chemical action of hardening and so further
restrict the rate of evolution of heat.
 The rate of evolution of heat will,
therefore, be less and evolution of heat
will extend over a longer period.
Therefore, the feature of low heat
cement is a slow rate of gain of
strength.
But the ultimate strength is same as
that of OPC.
PORTLAND POZZOLANA CEMENT
It is manufactured by the intergrinding of OPC
clinker with 10 to 25 % of pozzolanic material.

A pozzolanic material is essentially a siliceous

or aluminous material which while in itself
possessing no cementitious properties, which
will, in finely divided form and in the presence
of water, react with calcium hydroxide,
liberated in the hydration process, at ordinary
temperature, to form compounds possessing
cementitious properties.
 The pozzolanic materials generally used for
manufacture of PPC are calcined clay or
Flyash.

Calcium silicates produce considerable

quantities of calcium hydroxide, which is by
and large a useless material from the point of
view of strength or durability.
 If such useless mass could be converted into
a useful cementitious product, it considerably
improves quality of concrete.

The use of fly ash performs such a role.

The pozzolanic action is shown below.

Calcium hydroxide
+Pozzolana+ water C-S-H (gel)
 PPC can be used in all situations where
OPC is used except where high early
strength is of special requirement.

As PPC needs enough moisture for

sustained pozzolanic activity, a little longer
curing is desirable.
 Use of PPC would be particularly suitable for
the following situations:
For hydraulic structures
For mass concrete structures like dam,
bridge piers and thick foundation
For marine structures
For sewers and sewage disposal works
etc.
AIR-ENTRAINING CEMENT

This cement is made by mixing a small

amount of an air-entraining agent with
OPC clinker at the time of grinding.

The following types of air-entraining

agents could be used:
Alkali salts of wood resins
 Syntheticdetergents of the alkyl-aryl
sulphonate type

Calcium lignosulphate derived from the

sulphite process in paper making

Calcium salts of glues and other

proteins obtained in the treatment of
animal hides.
COLOURED CEMENT
For manufacturing various coloured cements
either white cement or grey Portland cement is
used as a base.

The use of white cement as a base is costly.

With the use of grey cement only red or brown

cement can be produced.

It consists of Portland cement with 510

percent of pigment.
 The raw materials used for manufacture of
white cement are high purity limestone
(96% CaCO3 and less than 0.07% iron
oxide).
The other raw materials are china clay with
iron content of about 0.72 to 0.8%, silica
sand, flourspar as flux and selenite as
retarder.
Sea shells and coral can also be used as
raw materials for production of white cement.
HYDROPHOBIC CEMENT
It is obtained by grinding OPC clinker with
water repellant film-forming substance such
as oleic acid and stearic acid.
The waterrepellant film formed around each
grain of cement, reduces the rate of deterioration
of the cement during long storage, transport, or
under unfavourable conditions.
The film is broken out when the cement and
aggregate are mixed together at the mixer
exposing the cement particles for normal
hydration.
 The film forming water-repellant material
will entrain certain amount of air in the body
of the concrete which incidentally will
improve the workability of concrete.

The properties are same as the OPC

except that it entrains a small quantity of air
bubbles.
MASONRY CEMENT
Ordinary cement mortar, though good when
compared to lime mortar with respect to strength
and setting properties, is inferior to lime mortar
with respect to workability, water-retentivity,
shrinkage property and extensibility.
Masonry cement is a type of cement which is
particularly made with such combination of
materials, which when used for making mortar,
incorporates all the good properties of lime
mortar and discards all the not so ideal
properties of cement mortar.
 This kind of cement is mostly used, as the
name indicates, for masonry construction.

It contains certain amount of air-entraining

agent and mineral admixtures to improve
the plasticity and water retentivity.
EXPANSIVE CEMENT
Concrete made with OPC shrinks while
setting due to loss of free water.

This is known as drying shrinkage.

Cement used for grouting anchor bolts or

grouting machine foundations or the cement
used in grouting the prestress concrete ducts,
if shrinks, the purpose for which the grout is
used will be to some extent defeated.
 The type of cement which suffers no overall
change in volume on drying is known as
expansive cement.
Cement of this type has been developed by
using an expanding agent and a stabilizer
very carefully.
About 820 parts of the sulphoaluminate
clinker are mixed with 100 parts of the
Portland cement and 15 parts of the
stabilizer.
IRS-T SPECIAL GRADE CEMENT

It is manufactured as per specification laid

down by ministry of railways under IRS T40:
1985.
It is a very finely ground cement with high
C3S content designed to develop high early
strength required for manufacture of concrete
sleeper for Indian Railways.
This cement can be used for prestressed
concrete elements, high rise buildings and
high strength concrete.
OIL WELL CEMENT

The desired properties of oil-well cement can

be obtained in two ways:
By adjusting the compound
composition of cement or
By adding retarders to OPC

The retarders are starches or cellulose

products or acids.
 These retarding agents prevent quick setting
and retains the slurry in mobile condition to
facilitate penetration to all fissures and
cavities.

Sometimes workability agents are also added

to this cement to increase the mobility.
REDISET CEMENT

A new product was needed for use in the

precast concrete industry, for rapid repairs of
concrete roads and pavements and slip-
forming.

Associated Cement Company of India have

developed this cement.
Properties of Rediset Cement
The cement allows a handling time of just

about 8 to 10 minutes.
The strength pattern is similar to that of OPC.

It releases a lot of heat which is advantageous

in winter concreting but excess heat liberation

is detrimental to mass concrete.
The rate of shrinkage is fast but the total

shrinkage is similar to OPC.

The sulphate resistance is poor.
Rediset can be used for
Very high early (3 to 4 hours)strength
concrete and mortar.
Patch repairs and emergency repairs
Quick release of forms in the precast
concrete products industry.
Slip-formed concrete construction
Construction between tides.
HIGH ALUMINA CEMENT

High alumina cement is obtained by fusing

or sintering a mixture, in suitable
proportions, of alumina and calcareous
materials and grinding the resultant product
to a fine powder.

The raw materials used for the manufacture

of high alumina cement are limestone and
bauxite.
 An important use of high alumina cement is
for making refractory concrete to withstand
high temperatures in conjunction with
aggregate having heat resisting properties.
RC is used for foundations of furnaces,
boiler settings.
It is also used in fire pits, construction of
electric furnaces, kilns etc.
VERY HIGH STRENGTH CEMENT
Macro-defect-free cements(MDF)
MDF refers to the absence of relatively large voids

or defects which are usually present in conventional

mixed cement pastes because of entrapped air and
inadequate dispersion.
In this process, 47% of one or several water soluble

polymers (such as hydroxypropylmethyle

cellulose, polyacrylamide of hydrolysed
polyvinylacetate) is added as rheological aid to
permit cement to be mixed with very small amount of
water.
Densely packed system (DSP)
Normal Portland cement and ultra-fine
silica fume are mixed.
The size of cement particles may vary from
0.5 to 100m and that of silica fume varies from
0.005 to 0.5m.
Silica fume is generally added from 5 to 25%.
A compressive strength of 270MPa have been
achieved with silica fume substituted paste.
Pressure densification and warm pressing
A new approach has been developed for
achieving very high strength by a method
called warm pressing (applying heat and
pressure simultaneously) to cement paste.
Compressive strength as much as 650MPa
and tensile strength upto 68MPa have been
obtained by warm pressing Portland and
calcium aluminate cements.
High early strength cement
Lithium salts have been effectively used as
accelerators in high alumina cement.
This has resulted in very high early strength in
cement and a marginal reduction in later
strength.
Strength as high as 4MPa has been obtained
within 1 hour and 27MPa has been obtained
within 3 hours time and 49MPa in one day.
Pyrament cement
Some cement industries in USA have developed a
super high early strength and durable cement
called by trade name pyrament cement.
This product is a blended hydraulic cement.
In this cement no chlorides are added during the
manufacturing process.
It produces a high and very early strength of
concrete and mortar which can be used for repair
of Air Field Run-ways.
Magnesium Phosphate Cement (MPC)
It has been developed by Central Road
Research Institute, New Delhi.

This is an important development for

emergency repair of airfields, launching pads,
road pavements suffering damage due to
enemy bombing and missile attack.
 MPC has been found to possess unique
hydraulic properties, controlled rapid set and
early strength development.

MPC is prepacked mixture of dead burnt

magnesite with fine aggregate mixed with
phosphate.

It sets rapidly yields durable high strength

cement mortar.
TESTS ON CEMENT

Testing of cement can be brought under

two categories:
Field testing
Laboratory Testing
FIELD TESTING

It is sufficient to subject the cement to field

tests when it is used for minor works.

The following are the Field tests:

Open the bag and take a good look at the
cement. There should not be any visible
lumps. The colour of the cement should
normally be greenish grey.
 Thrust your hand into the cement bag. It
must give you a cool feeling. There should
not be any lump inside.
Take a pinch of cement and feel between

the fingers. It should give a smooth and not

a gritty feeling.
Take a handful of cement and throw it on a

bucket full of water, the particles should

float for some time before they sink.
 Take about 100 grams of cement and a
small quantity of water and make a stiff
paste.
From the stiff paste, pat a cake with sharp
edges.
Put it on a glass plate and slowly take it
under water in a bucket.
 See that the shape of the cake is not
disturbed while taking it down to the
bottom of the bucket.

After 24 hours the cake should retain its

original shape and at the same time it
should also set and attain some strength.
LABORATORY TESTING

The following tests are conducted in the

laboratory:
Fineness test

Soundness test

Setting time test

Strength test

Heat of hydration test

Chemical composition test

FINENESS TEST

The fineness of cement has an important

bearing on
the rate of hydration
Rate of gain of strength
Rate of evolution of heat

Finer cement offers a greater surface area

for hydration and hence faster the
development of strength.
 Maximum number of particles in a sample of
cement should have a size less than about
100 microns.

The smallest particle may have a size of

about 1.5 microns.
Fineness of cement is tested in two ways:
By sieving IS 4031(Part I) : 1996
By determination of specific surface
(total surface area of all the particles in one
gram of cement) by air-permeability
apparatus. Expressed as cm2/gm or
m2/gm. Generally Blaine Air Permeability
apparatus is used - IS 4031(Part 2) : 1999
DETERMINATION OF FINENESS
BY DRY SIEVING
To determine fineness of cement and particle
size of cement.
Sample size 100gms; sieving period 15
minutes.
The standard sieve size used is 90 m.
The % residual (retained) of cement on 90 m
sieve shall not exceed 10%.
Sieve used for determining Fineness of Cement
DETERMINATION OF FINENESS BY BLAINE AIR
PERMEABILITY METHOD
Specific surface test(Blaine Test)(Air Permeability Test)
To determine fineness of cement (particle size of
cement) (5 to 30 m).
The fineness of cement is expressed in specific
surface of cement i.e. cm2/gm or mm2/gm.
It is determined by Air Permeability test or Lea-nurse
test.
The specific surface of cement shall not be less than
2250 cm2/gm or 225000 mm2/gm, for OPC.
For rapid hardening cement (RHC), it shall not be less
than 3250 cm2/gm.
DETERMINATION OF CONSISTENCY OF STANDARD
CEMENT PASTE
Consistency Test (Vicat Apparatus Test)
IS : 4 0 3 1 ( Part 4 ) - 1 9 8 8
To determine standard quantity of water to
produce standard cement paste.
The Vicat apparatus is used where the
penetration of plunger in standard cement paste
kept in Vicat mould shall be in a range of 33 to
35 mm from the top of the mould (5 to 7 mm
from the bottom).
 DETERMINATION OF INITIAL AND FINAL
SETTING TIMES

Initial setting time test (Vicat Apparatus)

IS : 4031 (Part 5) 1988 (Reaffirmed 2000)

To determine the time required by cement

paste to loss its plasticity.
 The Vicat apparatus is used to determine
initial setting time of cement where the
penetration of the needle in the cement
paste kept in Vicat mould (40 mm height)
shall be in a range of 33 to 35 mm from the
top.
It shall not be less than 30minutes(30min)
for normal cement, 60 minutes for low heat
cement and 5 minutes for rapid hardening
cement.
Final setting time of cement (Vicat Apparatus)
The time required by cement paste to gain the proper
shape and becoming hard considering from the instant
of adding water is called final setting time.
i.e., the time elapsing from the instant of adding water
to the cement and the instant when paste becomes
hard(solid) is known as final setting time which is
determined by Vicat apparatus where the enlarge
needle should not penetrate the specimen of cement.
Final setting time shall not exceed 10hrs for normal
cement, 30 minutes for rapid hardening cement.
SOUNDNESS TEST

DETERMINATION OF SOUNDNESS
Lechatelier Test IS 4031 (Part 3 ) 1988

To determine the soundness or unsoundness

of cement due to presence of free lime only.

The expansion of cement paste specimen in

Lechatelier mould shall not exceed 10mm.
Autoclave test
To determine soundness or unsoundness of
cement due to presence of magnesia.

Due to presence of steam around the

specimen expands caused by magnesia.

It shall not exceed 0.8% for soundness of

cement.
Autoclave for determining soundness
Compressive Strength Test
IS : 4031(Part 6):1988

To determine compressive strength of cement

where the specimen is made up of 1:3
(cement : sand) proportion i.e. 185 gm
cement and 555gm sand or 200gm cement
and 600gm sand.
 The specimen is tested under compression
machine at an age of 1 day, 3, 7 and 28
days.

The compressive strength of rapid hardening

cement at 1 day curing shall not be less than
16 MPa and at an age of 3 days it shall not
be less than 27.5 MPa.
Briquette Test
To determine strength of cement or concrete

where the specimen is made in dumbbell

shape (Zig Zag).

The tensile force is applied in the lab on the

specimen till the specimen fails in tension.

The tensile strength shall be of 10% of

compressive strength.
DETERMINATION OF HEAT OF HYDRATION
Test for Heat of Hydration IS : 4031 ( Part 9 )
1988.
To determine the heat of hydration, especially
for low heat cement.
A calorimeter is used in the lab.
The heat of hydration of low heat cement shall
not exceed 75 cal/gm at 28 days.
Hydration Test Apparatus
Chemical Composition Test
Ratio of percentage of lime to percentage of
silica, alumina and iron oxide, when calculated
by the formulae
CaO 0.7SO3
2.8 SiO 2 1.2 Al2O3 0.65 Fe2 O3
Not greater than 1.02 and not less than 0.66.
The above is called lime saturation factor per
cent.
AGGREGATES

The aggregate is a relatively inert material

and it imparts volume stability.
The aggregate provide about 75% of the
body of the concrete and hence its influence
is extremely important.
An aggregate should be of proper shape and
size, clean, hard and well graded.
It must possess chemical stability and it must
exhibit abrasion resistance.
Functions of Aggregate

It provides bulk to the concrete

It increases the density of the concrete mix.
It imparts volume stability.
It imparts durability to the concrete.
It is an inert material and is cheaper than
cement.
 The functions of Fine aggregate are
To assist in producing workability and
uniformity in the mix.
To assist the cement paste to hold the
coarse aggregate particles in suspension.
To promote plasticity in the mixture and
prevent possible segregation of paste and
coarse aggregate.
 The natural source of aggregate is obtained
from Igneous rocks (Granite, Basalt).
They are normally hard, tough and dense.
But the metamorphic rock (marble) is not
suitable for aggregates.
The most widely used artificial aggregates are
(i) clean broken bricks (ii) blast furnace slag.
The crushing strength of brick shall not be less
than 30 to 35 MPa.
Classification of Aggregate Based on Size
Fine Aggregate
It is the aggregate, most of which passes through

a 4.75mm IS sieve.
The lowest size of sand is about 0.07 mm.

The fine aggregate may be natural sand, crushed

stone sand or crushed gravel sand.

According to IS 383-1970, there are 4 grading

zones of the fine sand, grade 1, grade 2, grade3

and grade 4.
Coarse Aggregate
The aggregates, most of which are retained
on 4.75mm IS sieve are termed as coarse
aggregates.
The coarse aggregates may be
Crushed stone
Uncrushed gravel
Partially crushed stone or gravel.
 Sometimes combined aggregates are
available in nature consisting of different
fractions of fine and coarse aggregates,
which are known as all in aggregate.

The all in aggregates are not generally used

for making high quality concrete.
Classification of Aggregates according to
Shape
Rounded Aggregate
The aggregate with rounded particles (river or
sea shore gravel) has minimum voids ranging
from 32 to 33%.
It gives minimum ratio of surface area to the
volume, thus requiring minimum cement paste
to make good concrete.
 The only disadvantage is that the
interlocking between its particles is less, and
hence the development of the bond is poor,
making it unsuitable for high strength
concrete and pavement.
Irregular aggregates
The aggregate having partly round particles

(pit sand and gravel) has higher percentage of

voids ranging from 35 to 38 %.
It requires more paste for a given workability.

The interlocking between particles, though

better than that obtained with the rounded

aggregate, is inadequate for high strength
concrete.
Angular aggregates
The aggregate with sharp angular and rough
particles (crushed rock) has a maximum
percentage of voids ranging from 38 to 40%.
The interlocking between particles is good,
providing a good bond.
The aggregate requires more paste to make
workable concrete of high strength.
The angular aggregate is suitable for high
strength concrete and pavements subjected to
tension.
Flaky and elongated aggregates
An aggregate is termed flaky when its least
dimension (thickness) is less than three-fifth of
its mean dimension.
The particle is said to be elongated when its
greatest dimension (length) is more than nine-
fifth (1.8 times) of its mean dimension.
Classification based on Unit Weight
Normal Weight Aggregate
The commonly used aggregates i.e. sand,

gravel, crushed rocks such as granite, basalt,

sandstone (sedimentary) and limestone which
have specific gravities between 2.5 and 2.7
produce concrete with unit weight ranging from
23 to 26 kN/m3 and crushing strength at 28
days between 15 to 40 MPa are termed
Normal weight aggregate.
Heavy Weight Aggregate (High Density
aggregate)
Heavy weight aggregates are
Baryte(Gs = 4 to 4.6)
Ferrophosphorus (Gs = 5.8 to 6.8)
Haematite (Gs = 4.9 to 5.3)
Magnetite (Gs= 4.2 to 5.2)
Scrap Iron and Iron Shots (Gs = 6.2 to 7.8)

Heavy weight cocnrete is produced from

heavy weight aggregate, which is more
effective as a radiation shield.
The unit weight of concrete varies from 30 to
57 kN /m3.
Light weight Aggregate
The light weight aggregates have unit weight

upto 12 kN/m3.
These aggregates are obtained from pumice,

volcanic cinder, Diatomite, blast furnace slag,

fly ash etc,.
The weight of concrete (structure) is reduced

to a great extent and it provides better

thermal insulation and improved fire
resistance.
Fineness Modulus
The fineness modulus is a numerical index of
fineness, giving some idea of the mean size
of the particles present in the entire body of
the aggregate.
The fineness modulus is the sum of the
cumulative percentages retained on the
sieves divided by 100.
 According to IS 2386-1963, the sieves that
are to be used for the sieve analysis of the
aggregate for concrete are 80mm, 40mm,
20mm, 10mm, 4.75mm, 2.36mm, 1.18mm,
600m, 300m and 150m.
The fineness modulus can be regarded as a
weighted average size of a sieve on which
material is retained.
 For example, a fineness modulus of 6 can be
interpreted to mean that the sixth sieve, i.e.
4.75 mm is the average size.
The value of fineness modulus is higher for
coarser aggregate.
The fineness modulus for fine sand varies
between 2 and 3.5, for coarse aggregate it
varies between 5.5 and 8, for all in aggregate
it varies from 3.5 to 6.5.
 Any sand having FM more than 3.2 will not be
suitable for making satisfactory concrete.
The object (purpose) of finding FM is to grade
the given aggregates for the most economical
mix for the required strength and workability
with minimum quantity of cement.
If the test aggregates gives higher FM, the
mix will be harsh and if on the other hand
gives a lower FM, it produces an
uneconomical mix.
 Gradation
Gradation refers to the particle size distribution
of aggregates.
The gradation of coarse aggregate plays an
important role in workability and paste
requirements.
The gradation of fine aggregate affects the
workability and finishability of concrete.
 Types of gradation
Uniform grading

All particles are of same size.

It produces a large volume of voids irrespective

of particle size.
Hence the paste requirement for this concrete
is high.
 Continuous grading
Incorporates a combination of particles of
many sizes.
Hence, it minimises the volume of voids but
increases the particle surface area.
This is the preferred gradation.
 Gap gradation
This involves grading in which one or more
sizes are omitted. This type of concrete is
generally for architectural or aesthetic
purposes.
 Water