PRESENTASI ATK 2

PROBLEM 13.51

DWI CAHYA AYU NINGTYAS (08)

ID/D3 TEKNIK KIMIA
 PROBLEMS
A gaseous mixture consisting of 50 mol% hydrogen and 50 mol% acetaldehyde (C2H4O ) is initially
contained in a riggid vessel at a total pressure of 760 mmHg abs.
The formation of ethanol (C2H6O) occurs according to :
C2H4O + H2 C2H6O
After a time it was noted that the total pressure in the rigid vessel had dropped to 700 mmHg abs.
Calculate the degree of completion of the reaction at that time using the following assumption:
1. All reactants and products are in the gaseous state, and
2. The vessel and its contents were at the same temperature when the two pressure were
measured.
 PENYELESAIAN

P1 = 760 mmHg abs P2 = 700 mmHg abs

50 mol% C2H4O
VESSEL C2H6O
50 mol% H2
T1 = T2
DIKETAHUI : DITANYA :
Basis (n1) : 1lbmol of 50% H2 dan 50% C2H4O Hitunglah derajat kesempurnaan reaksinya
P1 : 760 mmHg dengan menggunakan asumsi :
P2 : 700 mmHg 1. Semua reaktan dan produk berada
T1 = T2 ( asumsi dari soal) dalam keadaan gas
2. Vessel dan isinya berada dalam
50 mol% H2 = = ,
temperatur yang sama saat kedua

50 mol% C2H4O = = , tekanan diukur (T1 = T2)
Rx : C 2H4O + H2 C 2H6O
 JAWAB :
1. Mencari n2 : 2. Mencari jumlah mol zat yang bereaksi :
P1V1=n1 R T1 P2V2=n2 R T2 n2 = 0,92105 lbmol
P1V1 P2V2
= Rx C2H4O + H2 C2H6O Mol yang
n1 R T1 n2 R T2
bereaksi di
m 0,5 0,5 - misalkan x
760 700
= r x x x
1 n2
s 0,5-x 0,5-x x = 0,92105 lbmol
n2 = 0,92105 lbmol (P pada 700mmHg) Maka, (0,5-x) + (0,5-x) + x = 0,92105 lbmol

1 - 2x + x = 0,92105 lbmol
3. Menentukan derajat kesempurnaan : 1 - 2x + x = 0,92105 lbmol

Degree of completion =

100 1 x = 0,92105 lbmol

0,07895 lbmol x = 1 - 0,92105 lbmol

= 100
0,5
x = 0,07895 lbmol
= 15,79 %
THANK YOU
Rumus untuk mencari derajat kesempurnaan suatu reaksi dapat dilihat pada buku
karangan David M.Himmelblau,James B.Riggs berjudul Basic Principles and
Calculations in Chemical Engineering Prentice Hall (7th edition). Halaman 240
,Chapter 9.