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Apatite Ca5(PO4)3(F,Cl,OH)
Fluorite CaF2
Calcite CaCO3
Cerussite PbCO3
Malachite CuCO3Cu(OH)2
Western Russia
Europe 11,000
Tunisia 7,800
Morocco China
US 41,500 20,000
24,000 Middle East
10,100
Brazil 4,500
South Africa 3,000 Australia
Isaac Asimov
Fertilizers
80%
Classification
Pebble(+16 mesh) Slimes(-150 mesh)
(final product) Coarse Fine (to tailings pond)
(16x35 mesh) (35x150 mesh)
High Solid(>70%) High Solid(>70%)
Conditioning Conditioning
Coarse Fine
Fatty Acid Flotation Fatty Acid Flotation
Coarse Fine
Amine Flotation Amine Flotation
R (Hydrocarbon Chain)
O O
Ca Ca
Bridging
60
40
20
0
20 30 40 50 60 70 80 90
Quartz
Apatite
80
60
40
20
0
0 100 200 300 400
Equilibration Time (Sec)
Apatite Quartz
Water
Solid Surface
Department of Metallurgical Engineering
University of Utah
Florida Phosphate Mining Start from
1900s
dragline
Mining by hand
Flotation
Mining
Wash Plant
100
80
60
40
0
0 1 2 3 4 5
Cell Number
30
Grade % P 2O5
25
20 New Collector
FA/FO
15
10
75 80 85 90 95 100
Phosphate Recovery %
100
90
Grade (% P 2O5) and Phosphate Recovery (%)
80
70
Recovery (with p3815)
60 Recovery (with PEO-1)
Grade (with p3815)
50
Grade (with PEO-1)
20
10
0
150 300 450 600 750 900 1050 1200 1350
Total Reagent Addition (g/t)
a b
90
Grade(%P2O5) and Phosphate Recovery(%)
80
70
60 Grade
Recovery
50
40
30
20
10
0
0 5 10 15 20 25 30 35
PEO-1, Weight Percent of Total Reagent Addition