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F R E E E N E R G Y A N D E Q U I L I B R I U M
C H E M I C A L E Q U I L I B R I A
S O L U T I O N S O F N O N E L E C T R O L Y T E S
S O L U T I O N S O F E L E C T R O L Y T E S
E L E C T R O C H E M I C A L C E L L S
CHEMICAL EQUILIBRIA
2 groups:
Homogeneous equilibrium is one established in a
system in which only one phase occurs.
Heterogeneous equilibrium is one established in a
system in which more than a single phase appears.
Law of Mass Action
= =
Kp and Kc Relationship
=
Gibbs-Helmholtz Equation
=
2
Relation of Kp and G
= ()
Temperature Dependence of Kp
=
2
Le Chatelier-Braun Principle
2 + 32 2 3 H = 45 kJ/mol
2 + 32 2 3 H = 45 kJ/mol
2 + 32 2 3 H = 45 kJ/mol
Reactants Products
At start: 1 0
At anytime 1- v
=
( )
F R E E E N E R G Y A N D E Q U I L I B R I U M
C H E M I C A L E Q U I L I B R I A
S O L U T I O N S O F
N O N E L E C T R OL Y T E S
S O L U T I O N S O F E L E C T R O L Y T E S
E L E C T R O C H E M I C A L C E L L S
SOLUTIONS OF NONELECTROLYTES
Nonelectrolytes
persists in uncharged form and exhibits no tendency
to dissociate into electrically charged ions.
They are solutions that do not conduct
electricity.
These are the solutions which yield for the dissolved
substances normal molecular weights, i.e. the
molecular weights expected from their chemical
formulas.
SOLUTIONS OF NONELECTROLYTES
Important Terms
Solute
Solvent
Solubility
Unsaturated solution
Saturated solution
Supersaturated solution
Ideal Solutions
= +
=
=
Colligative Properties
of Nonelectrolytic Solutions
Colligative Property Nonelectrolytes
=
1. Vapor-pressure
lowering Where P=vapor pressure of the pure solvent, xsolute=mole fraction of the
solute in the solution and P=extent of vapor pressure lowering
=
2. Boiling point
elevation Where = , ,
Kb=ebullioscopic constant and m=molality
=
3. Freezing point
depression Where = , , and Kf=cryoscopic constant
4. Osmotic
pressure =
Minimum pressure
required to prevent Where M = molarity, R = gas constant and T = absolute temperature
osmosis
Physical Chemistry 2
F R E E E N E R G Y A N D E Q U I L I B R I U M
C H E M I C A L E Q U I L I B R I A
S O L U T I O N S O F N O N E L E C T R O L Y T E S
S O L U T I O N S O F E L E C T R O L Y T E S
E L E C T R O C H E M I C A L C E L L S
SOLUTIONS OF ELECTROLYTES
Strong Electrolytes
The colligative properties of solutions of strong electrolytes
depend primarily on the number of ions that make up the
electrolyte and the extent of dissociation of the electrolyte.
Weak Electrolytes
Solutions that exhibit only poor conductance and a low
degree of dissociation are called weak electrolytes
Colligative Properties of Electrolytes
, = , +
2. Boiling point elevation
, = ,
3. Freezing point depression
4.Osmotic pressure
Minimum pressure required to = ln
, +
prevent osmosis
The Arrhenius Theory
of Electrolytic Dissociation
= [ . + ]
Exercises