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Quiz 2 (Extraction):
29/12/2016 (Thursday)
CHAPTER 7
LIQUID-LIQUID
EXTRACTION
EXTRACTION
SOLID-LIQUID EXTRACTION/LEACHING
Separation of solutes from solid using liquid solvent
Eg. Soya milk (solute) from soya bean (inert solid) using water (liquid
solvent)
LIQUID-LIQUID EXTRACTION
solute dissolves more readily in the solvent in which it has a higher solubility
component A = solute
component B = inert/carrier liquid
component C = liquid solvent
Example 12.5-1
30 kg isopropyl ether (C), 10 kg acetic acid (A) + 60 kg water (B)
Mix & come to equilibrium. Determine the raffinate and extract
compositions.
Original composition: xC = 0.3, xA = 0.1, xB = 0.6
1. Locate the original composition on the
right-angled triangle. Lets that point be M
2. By trial-&-error, draw a tie line that 0.3 M
passes throught M to intersect the raffinate
and the extract layer
3. From the raffinate layer, the composition 0.1
is xA =0.12 , xC = 0.02
4. From the extract layer, the composition is
yA = 0.04 , yC = 0.94
SINGLE-STAGE EXTRACTION
yA1 yA2
xA0 xA1
Total material balance: L0 + V2 = L1 + V1 = M
Balance on A: L0xA0 + V2yA2 = L1xA1 + V1yA1 =MxAM
Balance on C: L0xC0 + V2yC2 = L1xC1 + V1yC1 =MxCM
Problem 12.5-2
V1 V2 = 400 kg
1 atm
yA1 yA2=0
L0 = 400 kg 293K L1
xA0 = 0.35 xA1
xAM = 0.075
Example 12.7-2
L0(0.3,0), VN+1(0,1), xN = 0.1, xAM = 0.075
1. Locate point L0(0.3,0.0),VN+1(0.0,1.0) and VN+1
V
LN(on the raffinate layer at xNA = 0.1) V2 3
V1
2. Draw a straight line connecting L0 & VN+1. N 2.3 stages
Locate point M M
VN+1min - stages
Case 1: min
LN
xMAmin L0
VN+1
MINIMUM SOLVENT RATE,VN+1min
VN+1min - stages
Case 2:
V1min
1. Draw a straight line from LN through VN+1.
2. Get as many tie lines between L0 and LN.
Extend the tie lines to intersect the line L0VN+1 Mmin