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Properties of Solutions
Section 11.1
Solution Composition
Solution Composition
moles of solute
Molarity (M ) =
liters of solution
mass of solute
Mass (weight) percent = 100%
mass of solution
moles A
Mole fraction ( A ) =
total moles of solution
moles of solute
Molality ( m ) =
kilogram of solvent
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Section 11.1
Solution Composition
Molarity
moles of solute
Molarity (M ) =
liters of solution
EXERCISE!
You have 1.00 mol of sugar in 125.0 mL of
solution. Calculate the concentration in units of
molarity.
8.00 M
EXERCISE!
You have a 10.0 M sugar solution. What volume
of this solution do you need to have 2.00 mol of
sugar?
0.200 L
EXERCISE!
10.0 M NaOH
5.37 M KCl
Mass Percent
mass of solute
Mass (weight) percent = 100%
mass of solution
EXERCISE!
6.6%
Mole Fraction
molesA
Mole fraction ( A ) =
total moles of solution
EXERCISE!
0.0145
Molality
moles of solute
Molality (m) =
kilogram of solvent
EXERCISE!
0.816 m
CONCEPT CHECK!
Polar solute, polar solvent Large Large Large, negative Small Solution forms
Nonpolar solute, polar solvent Small Large Small Large, positive No solution
forms
Polar solute, nonpolar solvent Large Small Small Large, positive No solution
forms
In General
One factor that favors a process is an increase in
probability of the state when the solute and solvent are
mixed.
Processes that require large amounts of energy tend not
to occur.
Overall, remember that like dissolves like.
Structure Effects:
Polarity
Pressure Effects:
Henrys law
Temperature Effects:
Affecting aqueous solutions
Structure Effects
Hydrophobic (water fearing)
Non-polar substances
Hydrophilic (water loving)
Polar substances
Pressure Effects
Little effect on solubility of solids or liquids
Henrys law: C = kP
C = concentration of dissolved gas
k = constant
P = partial pressure of gas solute
above the solution
Amount of gas dissolved in a solution is directly proportional to
the pressure of the gas above the solution.
A Gaseous Solute
The Solubilities
of Several Solids
as a Function of
Temperature
The Solubilities of
Several Gases in Water
Liquid/Vapor Equilibrium
Nonideal Solutions
Liquid-liquid solutions where both components are
volatile.
Modified Raoults Law:
Negative Acetone-
A A, B B < A B Positive Negative
(exothermic) water
Positive Ethanol-
A A, B B > A B Negative Positive
(endothermic) hexane
CONCEPT CHECK!
100.35 C
Osmosis
EXERCISE!
111 g/mol
Ion Pairing
At a given instant a small percentage of the sodium and
chloride ions are paired and thus count as a single
particle.
Examples
The expected value for i can be determined for a salt by
noting the number of ions per formula unit (assuming
complete dissociation and that ion pairing does not
occur).
NaCl i=2
KNO3 i=2
Na3PO4 i=4
Ion Pairing
Ion pairing is most important in concentrated solutions.
As the solution becomes more dilute, the ions are
farther apart and less ion pairing occurs.
Ion pairing occurs to some extent in all electrolyte
solutions.
Ion pairing is most important for highly charged ions.
Modified Equations
T = imK
= iMRT
Types of Colloids
Coagulation
Destruction of a colloid.
Usually accomplished either by heating or by adding an
electrolyte.