Calorimeter

CAMPOS IBARRA CARLA OLIVIA

GMEZ SOLS LUIS ARMANDO
PRADO LPEZ JORGE ANTONIO
RUIZ CHVEZ MICHEL
SOTO JUAN CARLOS
CALORIMETRY
Calorimetry, derived from the Latin calor meaning
heat, and the Greek metry meaning to measure.
Therefore, calorimetry is the science of measuring the
amount of heat.

Any process that results in heat being generated and
exchanged with the environment is a candidate for a
calorimetric study.

This is whay that calorimetry has a very broad range of

applicability, with examples ranging from drug design in
the pharmaceutical industry, to quality control of
process streams in the chemical industry, and the study
of metabolic rates in biological systems (people
included) .
CALORIMETER
Acalorimeteris an object used forcalorimetry, or the
process of measuring the heat ofchemical reactions
orphysical changes as well asheat capacity.
Antoine Lavoisier
Lived 1743 1794.
Antoine Lavoisier revolutionized chemistry. He
named the elements carbon, hydrogen and
oxygen;
- Discovered oxygens role in combustion and
respiration; established that water is a compound of
hydrogen and oxygen;
History.
The name calorimeter was made up byAntoine
Lavoisier.
In 1780, he used aguinea pigin his experiments
with this device to measure heat production. The
heat from the guinea pig's respiration melted snow
surrounding the calorimeter, showing that
respiratory gas exchange is combustion, similar to a
candle burning.
TYPES OF
CALORIMETERS
ADIABATIC
CALORIMETER

This calorimeter is used for the

measurement of specific heats of solids
and liquids which has the peculiarity of
reducing to a negligible value the heat
that can leave its interior or penetrate it.

Isolated system that allows to make the

relation between the generated heat and
the difference of temperature.

There are 3 methods that prevent heat

exchange between the system and
surroundings:

1. Rapid heat generation

2. The use of a thermal resistance
3. Control of the surrounding temperature
ISOPERIBOLIC
CALORIMETER
The temperature of the
surroundings remains
constant, while the
temperature of the system
varies with time.

A thermal resistance of
defined magnitude is used
between the cell and the
surroundings. The heat
exchange depends on the
temperature difference of
the surroundings (TA) and
the cell (TC).

TC(TA)
BOMB CALORIMETER
For combustion reactions, we
often enclose all reactants in
an explosive-proof steel
container, called the bomb
whose volume does not
change during a reaction.

The bomb is then submerged

in water or other liquid that
absorbs the heat of reaction.
The heat capacitor of the
bomb plus other things is
then measured using the
same technique as other
calorimeters.
DRY LOAD
CALORIMETER
It consists of a thermally
insulated charge where the
power is dissipated, a heat-
conductive transmission line
that connects the input to
the load and a thermometer.

It uses the principle of dual

charge, in which one absorbs
while the second acts as
reference temperature. It is
necessary that the
surroundings have a
constant temperature
gradient.
ISOTHERMAL HEATING
CALORIMETER
Is used for the direct
measurement of heat that is
released or absorbed during a
biomolecular bonding event.

All binding parameters can be

determined simultaneously in a
single experiment. Without the
need to modify the components of
the bond, either with fluorescent
markers or by means of
immobilization, ITC measures the
affinity of the binding components
in their native states.

The measurement of the heat

transfer during the bond allows
the exact determination of:
The bond constants (KD)
The stoichiometry of the
reaction (n)
Bibliography
https://www.google.com.mx/search?q=calorim
etro+de+lavoisier&source=lnms&tbm=isch&sa=
X&ved=0ahUKEwj21oy2sbHTAhUUVmMKHQljDjUQ_AU
IBigB&biw=1242&bih=602#tbm=isch&q=lavoisie
r+calorimeter&imgrc=DsSBCfDkvJnCsM
:

https://www.famousscientists.org/antoine-lavoisier
/

https://en.wikipedia.org/wiki/Calorimeter