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Devlin, P., Public-Private R&D Partnerships Examples, DOE Hydrogen Program, July 14, 2005.
Hydrogen Energy System
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Will a hydrogen-based energy economy, with its promise of clean,
sustainable energy, become a reality? This is clearly a complex issue
involving
economic and societal drivers (such as energy independence, energy
costs, global warming, pollution)
politico-economic decisions (such as infrastructure investment, R&D
investment)
exogenous developments(such as advancement in the performance of
other energy systems, military conflicts)
The use of hydrogen as an energy carrier may ultimately hinge upon
the performance achieved in hydrogen production distribution,
storage, and propulsion systems and components. The performance
of those, in turn, is highly dependent on technological advancements,
particularly on the properties of the materials used in their
manufacture. In other words, materials are key enabling technology to
a viable hydrogen economy.
It is clear, though, that alternative energy sources will eventually be
needed to satisfy the worlds ever-increasing energy requirement.
Since such a transition would be revolutionary, rather than
evolutionary, it will require a significant investment in research,
development, and infrastructure over a relatively long period. In other
words, it is not too soon to pursue the development of alternative
fuels.
In the transportation sector, in fact, hydrogen could have the greatest
impact. For more than 100 years, gasoline- and diesel-fueled internal
combustion engines have been used to supply motive power for a
wide range of vehicle sizes, shapes, and applications. These vehicles
are supplied with fuel by an efficient and pervasive petroleum-based
infrastructure that products a fuel with high energy density and
consistent performance. The challenge, then, for alternative fuels is to
supply equivalent, or nearly equivalent, vehicle performance, vehicle
cost, and operating costs.
Furthermore these requirements must be met on a scale sustainable at the levels expected for global
automotive use.
The major advantage of hydrogen as a transportation fuel, particularly with hydrogen fuel cell vehicles, is
that it simultaneously addresses many issues associated with current petroleum-base vehicle
technologies, including
(1) reduced greenhouse gas emissions
(2) reduced pollutant emissions
(3) diversification of fuel feedstocks
(4) energy independence
(5) on-board fuel efficiency
Each of the stages in the hydrogen fuel chainproduction , distribution, storage, utilization (e.g., fuel cell,
internal combustion engines) employs components and systems that require unique and sometimes
extraordinary material properties.
1. Hydrogen Production
Hydrogen is used primarily for petroleum refining and ammonia production with about 3.2 X 10 12 scf
produced in 2003. Most of this H2 was produced by steam methane reforming.
There are a number of processes that can produce H2 by the dissociation of water or steam. These
include low- and high-temperature electrolysis, solar and photoelectrochemical processes, and
themochemical processes such as the sulfur-iodine processes.
The source of the energy to dissociate water is a key to whether these processes will reduce
greenhouse gases and dependence on foreign fossil fuels. Nuclear energy as a source of electrical
and thermal energy offers a significant opportunity to achieve both goals.
Steam methane reforming is performed in a high-temperature, high-pressure reaction chamber
typically operating between 1,250 to 1,575 oC at pressures of 20 to 100 atmospheres. Materials issues
are the same as those of high-temperature, high-pressure vessels where creep of corrosion-resistant
materials is important for the containment vessel and durability of alumina, chromia, or SiC refractory
lining materials is critical to the performance of the system.
Electrolytes are a critical material in the performance of electrolyzers.
Low-temperature electrolysis of water relies on proton exchange
membrane (PEM) cells using sulfonated polymers for the electrolytes.
Key issues for all electrolyzers are the kinetics of the system that is
controlled by reaction and diffusion rates. Catalysts such as platinum,
IrO2 and RuO2 are used to improve the reaction kinetics, but they also
contributed to the cost of the system, which is also an issue. Steam
electrolysis is also a possibility at a temperature of about 1,000 oC using
ceramic membranes.
Materials issues surround the kinetics of the electrode processes and
durability of the interconnect materials in the high-temperature, oxygen-
rich environments. Thermochemical water-splitting processes such as
the S-I process offer high efficiency when coupled with an efficient source
of heat, but have significant issues associated with corrosion of system
materials. Materials being considered include Hastelloy B-2, C-276,
Incoloy 800H, SiC, and Si3N4 with and without noble metal coatings.
Use of solar energy to produce H2 is another route for reducing greenhouse
gas emissions form fossil fuels while also reducing our dependence on foreign
fossil fuels.
Photoelectrochemical and photobiological processes are two examples that
are solar energy driven. Photobiological hydrogen production is a process
where microorganisms (algae or cyanobacteria) function as photocatalysts.
Algae or cyanobacteria use photosynthesis to split water into O 2, protons, and
electrons. Materials issues associated with this process are sketchy since this
process has not developed beyond the exploratory stage.
The low energy density of sunlight will dictate a system that covers a large
area, so material costs will be a critical issue in the economics of this process.
A concentrating reactor system will require light-transmitting elements from the
dish-concentrating collector into the reactor. An overall list of material
properties that will be critical to the operation of this type of H2 production
system includes transmittance, outdoor lifetime (i.e., durability to sunlight),
biocompatibility, H2 and O2 permeation rates, and physical and mechanical
properties.
2. Hydrogen Distribution
http://hcc.hanwha.co.kr/english/pro/ren_hsto_idx.jsp
http://www.ifw-dresden.de/institutes/imw/sections/21/funct-
magn-mat/hydrogen-storage/
Devlin, P., Public-Private R&D Partnerships Examples, DOE
Hydrogen Program, July 14, 2005.
Materials for the Hydrogen Economy, Jones, R. H. and
Thomas, G. J., ed., CRC Press, Boca Raton, 2008.