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Energy
At the anode
SO4- - - 2e SO4
When H2 SO4 reacts with anode (which
is Cu)
Cu++ + 2e Cu
Faradays laws of
Electrolysis
1st Law:
Weight of a substance libreted from an electrotype
in a given time is propotional to the total quantity
of electricty passed in that time.
W Q
Then W I.t
or W = Z.I.t
I = Current in Ampere
t = Time in seconds
Z = Constant called the electro-chemical
equivalent of substance.
Electro-chemical Equivalent
If I = 1 Amp
T = 1 sec
Then W = Z
Therefore
It is the amount of that substance by
weight liberated in a unit time by the
passage of unit current
-do-
Current = 90-98 %
Energy Efficiency:
Due to secondary reactions the actual voltage required for
deposited or liberated of metal is higher than the theorotical
value which isncreases the actual energy required.
-do-
Voltage:
Voltage equired for the passage of the current
through an electrolyte depends upon the
potential drops at the electrodes and the
electrolyte. It is desireable that drops should be
reduced to minimum and for this purpose same
agent is added to make electrolyte a good
conductor thus reducing the voltage drops.
Example:
In copper plating sulphuric acid is added to
CuSO4 bath. The normal voltage to pass current
through most electrolyte is about 1 to 2 volts.
Example No. 1
Find thickness of copper deposited on a plate of
2.25 cm2 duringelectrolysis if a current of 1amp is
passed for 100 min.
(Density of copper id 8.89 gm/cc and ECE of Cu is
0.0003295 gms/Columb.)
Solution: ECE odf Cu = 0.0003295gm/col
Current strength = 1 amp
Time = 100 min = 100x60 =6000sec
Wt of Cu deposited W= ZIT = 0.0003295x1x6000
=1.977gm
Density of Cu = 8.9 gm/cc
-do-
Prepared by
Engr. Muzamil faiz