Professional Documents
Culture Documents
Air Pollution
Overview
Air Pollution in the Lower Atmosphere
Controlling Common Pollutants of the
Lower Atmosphere
High Altitude Ozone Depletion
Indoor Air Pollution
Controlling Indoor Air Pollution
Air Pollution in Lower
Atmosphere
A brief history
The atmosphere has long been a sink
for waste disposal
Long history of recognition of the
existence of atmospheric pollutants
Natural photochemical smog recognized
in 1550
Acid rain first described in 17th century
Point source
Fugitive source
Air Pollution in Lower
Atmosphere
2. Mobile source - move from place to
place while emitting pollutants
Automobiles, trucks, buses, aircraft,
ships, and trains.
General Effects of Air
Pollution
Affects many aspects of our
environment
Visual qualities
Vegetation
Animals
Soil
Water quality
Natural and artificial structures
Human health
General Effects of Air
Pollution
Significant factor in human death
rate for many large cities
Athens, Greece
Number of deaths higher on bad air quality
days
Hungary
1 in 17 deaths contributed to air pollution
US
300,000 deaths/year, health cost $50 billion
China
Large cities have major air pollution issues;
health cost $50$100 billion
General Effects of Air
Pollution
Affect human health in several ways
Toxic poisoning, cancer, birth defects,
eye irritation, and irritation of
respiratory system
Increased susceptibility to viral
infections, causing pneumonia and
bronchitis
Increased susceptibility to heart disease
Aggravation of chronic diseases, such as
asthma and emphysema
General Effects of Air
Pollution
Many air pollutants have synergistic
effects
Do greater damage to the lungs than a
combination of the two pollutants would
be expected to do based on their
separate effects
Air Pollutants
200 air pollutants recognized and
assessed by US EP and listed in Clean
Water Act
Primary pollutants
Emitted directly into the air
Carbon monoxide (58%), volatile organic
Occurs when
cloud cover
associated
with
stagnant air
Urban Air Pollution
Cities situated in a valley or
topographic bowl are more
susceptible to smog problems
Surrounding mountains and inversions
prevent pollutants from being
transported by wind or weather systems
Ex: Los Angeles
Potential for Urban Air
Pollution
Determined by the following
factors:
1. Rate of emission of pollutants per unit
area
2. Downwind distance that a mass of air
moves through an urban area
3. Average speed of the wind
4. Elevation to which potential pollutants
can be thoroughly mixed by naturally
moving air in the lower atmosphere
Urban Air Pollution
Concentration of pollutants in the air
is directly proportional to the first
two factors
As either emission rate or down wind
travel distance increase, so will the
concentration of pollutants
City air pollution decreases with
increases in third and forth factors
The stronger the wind and the higher
the mixing layer, the lower the pollution
Future Trends for Urban
Areas
The optimistic view
Air quality will continue to improve
We will developed effective ways to
reduce pollutants
The pessimistic view
Population pressures and economics will
dictate what happens in many parts of
the world
The result will be poorer air quality in
many locations
Future Trends for Urban Areas;
The United States
LA is a good area to look at for
strategies for pollution abatement.
Air quality plan involving the entire
urban region includes the following
features:
Strategies to discourage automobile use
and reduce the number of cars.
Stricter emission controls for
automobiles
Future Trends for Urban
Areas; Developing Countries
Dont have the financial base
necessary to fight air pollution
Ex: Mexico City
25 million people
50,000 buses, millions of cars
Topographically located in a natural
basin
Perfect situation for severe air pollution
problem
Controlling Common
Pollutants
The most reasonable strategies:
Reduce
Collect
Capture
Retain
Reduction of emissions through
energy efficiency and conservation
measures is preferred
Pollution Control:
Particulates
Particulates emitted from fugitive,
point or area stationary sources
are much easier to control
Point/area sources can be controlled
by
Settling chambers or collectors which
cause particulates to settle out
Fugitive sources controlled by
Protecting open areas
Controlling dust
Tied to
emission
standards
that attempt
to control air
pollution
Tougher
standards
set for ozone
and PM 2.5
Air Quality Index
Used to describe air pollution on a
given day
Determined from measurements of
the concentration of five major
pollutants:
Particulate matter, sulfur dioxide,
carbon monoxide, ozone, and nitrogen
dioxide.
Air Quality Index
AQI = 100
Air is unhealthy
AQI greater than 200
Air pollution alert is issued
AQI exceeds 300
Air pollution warning is issued - hazardous to
all people.
AQI exceeds 400
Air pollution emergency is declared, and
people are requested to remain indoors and
minimize physical exertion
Cost of Outdoor Air Pollution
Control
Fossil fuel-burning pollution control
A few hundred dollars per additional ton
of particulates removed
Aluminum plant
May be several thousand per ton
Cost benefit must be considered
Cost of Outdoor Air Pollution
Control
Economic analysis of air pollution includes
many variables, some of which are hard to
quantify
We do know the following:
With increasing air pollution controls, the capital
cost for technology to control air pollution
increases
As the controls for air pollution increase, the loss
from pollution damages decreases
The total cost of air pollution is the cost of
pollution control plus the environmental damages
of the pollution
Ozone Depletion
Ozone (O3)
Triatomic form of oxygen in which three
atoms of oxygen are bonded
Strong oxidant and chemically reacts
with many materials in the atmosphere
In the lower atmosphere, ozone is a
pollutant
Highest concentration of ozone in the
stratosphere
Ultraviolet Radiation and
Ozone
Ozone layer in the stratosphere called the
ozone shield
Absorbs most of the potentially hazardous
ultraviolet radiation from the sun
Ultraviolet radiation consists of
wavelengths between 0.1 and 0.4 m
Ultraviolet A (UVA)
Ultraviolet B (UVB)
Ultraviolet C (UVC).
Ultraviolet Radiation and
Ozone
Ultraviolet C (UVC)
Shortest wavelength and most energetic of the
types of ultraviolet radiation
Sufficient energy to break apart diatomic
oxygen (O2)
Each of these oxygen atoms may combine with
an O2 molecule to create ozone
UVC strongly absorbed in the
stratosphere, and negligible amounts
reach the Earths surface
Ultraviolet Radiation and
Ozone
Ultraviolet A (UVA)
Longest wavelength
Least energy of the three types of
ultraviolet radiation
UVA can cause some damage to living
cells
Not affected by stratospheric ozone,
and is transmitted to the Earths surface
Ultraviolet Radiation and
Ozone
Ultraviolet B (UVB)
Energetic and strongly absorbed by
stratospheric ozone
Ozone is the only known gas that
absorbs UVB
Depletion of ozone in the stratosphere
results in an increase in the UVB that
reaches the surface of the Earth
Ultraviolet Radiation and
Ozone
Approximately 99% of all ultraviolet
solar radiation (all UVC and most
UVB) is absorbed by the ozone layer
Natural service function
Protects us from the potentially harmful
effects of ultraviolet radiation
Measurement of
Stratospheric Ozone
First measured in 1920s using Dobson
ultraviolet spectrometer.
Dobson unit (DU) - 1DU = 1 ppb O3
Now have measurements from all over the
world for 30 years
Ground based measurements first
identified ozone depletion over the
Antarctic
Concentrations have been decreasing since
the mid-1970s
Ozone hole
Ozone Depletion and CFCs
Hypothesis that ozone in the
stratosphere is being depleted by
CFCs
Based on physical and chemical
properties of CFCs and knowledge
about atmospheric conditions
Vigorously debated by scientists,
companies producing CFCs, and other
interested parties
Ozone Depletion and CFCs
The major features of the hypothesis:
CFCs emitted in the lower atmosphere
are extremely stable and therefore have
a very long residence time (about 100
years)
CFCs eventually wander upward and
enter the stratosphere
Once above the stratospheric ozone,
they may be destroyed by UV radiation,
releasing chlorine, a highly reactive
atom
Ozone Depletion and CFCs
The chlorine released then depletes the
ozone
Depletion increases the amount of UVB
radiation that reaches Earths surface
UVB is a cause of human skin cancers
and is also thought to be harmful to the
human immune system
Emissions and Uses of
Ozone Depleting Chemicals
CFCs have been used
As aerosol propellants in spray cans
Working gas in refrigeration and AC
Production of Styrofoam
No longer used in spray cans but use
has increased in refrigerants
Simplified Stratospheric
Chlorine Chemistry
CFCs are
transparent to sunlight,
essentially insoluble
Non-reactive in the oxygen-rich lower
atmosphere
When CFCs reach the stratosphere,
reactions do occur
UVC splits up the CFC releasing chlorine,
the following two reactions can take place:
Cl + O3 ClO + O2
ClO + O Cl + O2
Simplified Stratospheric
Chlorine Chemistry
This series of reactions is what is
known as a catalytic chain reaction
Chlorine is not removed
Reappears in the second reaction
Repeated over and over
Process considerably more complex
Chain can be interrupted and Cl
stored in other reactions
The Antarctic Ozone Hole
Since 1958 ozone depletion has been
observed in the Antarctic every
October.
Thickness decreasing and geographic area
increasing
Polar Stratospheric Clouds
Form during the polar winter (polar night)
Air circulates about the pole in Antarctic
polar vortex.
Forms as the isolated air mass cools,
condenses, and descends.
Polar Stratospheric Clouds
Type I polar stratospheric clouds
When air mass reach a temp between
195 K and 190 K, small sulfuric acid
particles are frozen and serve as seed
particles for nitric acid (HNO3).
Type II polar stratospheric clouds
If temperatures drop below 190 K water
vapor condenses around Type I cloud
particles
Polar Stratospheric Clouds
During the formation nearly all
nitrogen oxides held in clouds
Facilitates ozone depleting reactions
When spring comes and sun returns it
breaks apart Cl2
Chlorine can not be sequestered to form
chlorine nitrate, one of its carbon sinks.
An Arctic Ozone Hole?
Polar vortex also forms over the
North Pole
Weaker and does not last as long as
Antarctic
Ozone depletion does occur at the NP
Major concern is ozone-deficient air
moving southward over population
centers.
Environmental Effects
Several serious potential
environmental effects
Damage to food chain on land and in
oceans (loss of primary production )
Damage to human health (skin
cancers, cataracts, and suppression
of immune system)
UV Index measure of UV radiation on a
given day
Environmental Effects
Reduce the risk of skin cancer and other
skin damage from UV exposure by:
Limit exposure to the sun between the hours of
10 A.M.and 4 P.M.
Use a sunscreen with an SPF of at least 30
Wear a wide-brimmed hat and, where possible,
tightly woven full-length clothing
Wear UV-protective sunglasses
Avoid tanning salons and sunlamps
Consult the UV Index before going out
Future of Ozone Depletion
The Montreal Protocol
Outlined a plan for the eventual
reduction of global emissions of CFCs to
50% of 1986 emissions
Elimination of the production of CFCs by
1999
Assessment of the protocol suggest that
CFCs will return to pre-1980 levels by
2050
Future of Ozone Depletion
Substitutes for CFCs
Hydrofluorocarbons (HFCs)
Do not contain chlorine
Fluorine atoms participate in reactions
atmosphere
Still causes ozone depletion if they do reach
illnesses (BRI)
Buildings with sick building syndrome
(SBS)
Symptoms people report cannot be traced
to any one known cause
Sick Buildings
When the cause is not detected. A number
of things may be happening:
The complaints result from the combined
effects of a number of contaminants present in
the building
Environmental stress from another source is
responsible
Employment-related stress may be leading to
the symptoms reported
Pollutants or toxins may be present but not
identified
Control of Indoor Air
Pollution
Strong financial incentives to provide
workers with a clean air environment
Meet minimum indoor air quality
standards
Including increase in the inflow of fresh
air through ventilation
Control of Indoor Air
Pollution
One of the principal means for controlling
quality is by dilution
Fresh outdoor air mixed
Ventilating air-conditioning system
Windows that can be opened
Various types of air-cleaning systems
reduce potential pollutants
Particles, vapors, and gases
Can be installed as part of the heating,
ventilation, and AC system or as stand-alone
appliances
Control of Indoor Air
Pollution
Education also plays an important role
May involve deciding not to install unvented or
poorly vented appliances.
Educated people are more aware of their legal
rights with respect to product liability and
safety.
Education provides people with the information
necessary to make decisions concerning
exposure, and strategies to avoid potentially
hazardous conditions in the home and
workplace.