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CHM-657
INORGANIC CHEMISTRY
Submitted By:
HIRA MEHMOOD.
HUMAM AHMED.
Submitted To:
Maam Naushaba,
Maam Humera
Maam Tuba
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Volumetric analysis involves oxidation-reduction
reaction or (redox reaction).
Iodometry is one of the most important redox titration
method.
Iodometry also known as iodometric titration is a
measured of volumetric chemical analysis, a redox
reaction where the appearance or disappearance of
elementary iodine indicates the end point.
Iodometry is of two types:
3. KI H2O K+ + I-
Oxidation of I- :
4. 3(2I- I2+2e-
Balancing of No. of Electrons (in Equation 4)
6. Cr2O7-2+6I-+14H+ 2Cr+3+7H2O+3I2
April 17, 2012
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Ionization of Na2S2O3.5H2O in aqueous Solution:
7. Na2S2O3.5H2O H2O 2Na+ + S2O3-2 + 5H2O
Oxidation of S2O3-2 :
8. 2S2O3-2 S4O6-2+2e-
Reduction of I2 :
9. I2+2e- 2I-
Net Equation (adding 8 and 9)
10. I2+ 2S2O3-2 2I-+S4O6-2
Analysis of sample solution:
Ionization of H2O2 in aqueous solution:
11.H2O2 H2O 2H + + O2-2
Reduction of O2-2 into H2O:
12.4H + + O2-2 + 2e- 2H2O
Oxidation of I- into I2 :
13. 2I- I2+ 2e-
Net Equation (adding 12 and 13)
14. 4H + + O2-2 + 2I- I2+ 2H2O
Reaction of NaHCO3 with HCl:
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Analysis of sample solution:
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Result:
The no.of mol of H2O2 present in the given sample solution
is found to be W mol/250.0 ml.
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