Professional Documents
Culture Documents
Session
Surface Chemistry - 1
Session Objectives
Adsorption
Desorption
Adsorption isobar
Catalysis
Adsorption
The phenomenon of higher concentration of any
molecular species at the surface than in the bulk
Adsorbent
The substance on the surface of which adsorption takes
place is called adsorbent
Adsorbate
The substance which is being adsorbed on the
surface of another substance.
Desorption
The process of removal of an adsorbed substance from
the surface on which it is absorbed
Adsorbent Materials
Activated Carbon
Activated Alumina
Silica Gel
Activated carbon
Adsorption vs absorption
Types of Adsorption
Positive adsorption occurs when the
concentration of adsorbate is higher on the
surface of adsorbent than in the bulk.
Negative adsorption occurs when the
concentration of adsorbate is less on the
surface of adsorbent than in the bulk.
Types of adsorption
1.
Physical adsorption
2.
Chemical adsorption
Freundlich Isotherm
A graph between the amount (x/m) adsorbed by an
adsorbent and the equilibrium pressure of the adsorbate
at constant temperature is called adsorption isotherm
At low pressure the graph is nearly straight line
x
p1
m
At high pressure x/m becomes
independent of p
x
p0
m
Over a narrow range of p
x
K p1/ n
m
log
X
1
logK logp
M
n
Freundlich Isotherm
Langmuir isotherm
f: fraction of surface area covered
p: partial pressure of the adsorbate
1-f
k ap
.........(i)
k ap+k d
x
=k 'af .........(2)
m
x/m
ap
1 bp
a = ka x ka/kd
b = ka/kd
The values of constants a and b depend
upon the nature of adsorbate, nature of solid
adsorbent and temperature.
Isotherm
equation
Application
Note
Useful in analysis of
reaction mechanism
Langmuir
x
ap
=
m 1+bp
Chemisorption and
physisorption
Freundlich
x
=Kp1/n
m
Adsorption isobar
Graph between the amount adsorbed(x/m) and temperature
at a constant equilibrium pressure of adsorbate gas is known
as adsorption isobar
Application of Adsorption
In clarification of sugar
In gas masks
In catalysis
In adsorption indicators
In chromatographic analysis
In preserving vacuum
In paint industry
Pressure
Disadvantage--Cause Explosions
Catalysts!!!!
Disadvantage--Costly
Role of a Catalyst
Catalysts speed up a chemical reaction
without being used up...
Catalyst-Reactants
Catalyst + Reactants
Catalyst + Products
Hydrogenation of alkene
Catalysis
Positive catalysis
2KClO3
MnO2
270 C
2KCl 3O2
Negative catalysis
2CHCl3 O2
Alcohol
2COCl2
2HCl
Auto catalysis
CH3 COOC2H5 H2O
CH3 COOH
C2H5OH
Catalysis
Types of catalysis
Homogeneous catalysis
Process
1. Hydrolysis of an ester.
2. Oxidation of SO2 to SO3
in lead chamber process
Products
Acid and Alcohol H+
SO3
Heterogeneous catalysis
Process
Products
Catalyst
1. Ammonia synthesis
NH3
Fe with Al2O3
2. Methanol synthesis
MeOH
ZnO/Cr2O3
Catalyst
NO
Catalysis
Enzyme catalysis
Reaction
Catalyst
Glucos e
Invertase
Fructose
Zymase
Ethanol
Thank you