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11-1
11-2
11-3
11-4
11-5
11-6
11-7
11-8
11-9
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Lewis Symbols
A chemical symbol represents the nucleus
and the core e-.
Dots around the symbol represent valence e-.
Si
Al
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As
Se
Bi
Sb
Ar
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2+
Ba
Ba
BaO
Cl
Mg
2 Cl
Cl
2+
Mg
MgCl2
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Cl
H N H
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Cl
H N
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O C O
O C O
O C O
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N N
N N
N N
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Skeletal Structure
Identify central and terminal atoms.
H
H C
H
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H
C O H
H
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Skeletal Structure
Hydrogen atoms are always terminal atoms.
Central atoms are generally those with the lowest
electronegativity.
Carbon atoms are always central atoms.
Generally structures are compact and symmetrical.
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Strategy for
Writing Lewis
Structures
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Formal Charge
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1
2
#bond pair e-
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Example 11-6
Writing a lewis Structure for a Polyatomic Ion.
Write the Lewis structure for the nitronium ion, NO2+.
Step 1:
Total valence e- = 5 + 6 + 6 1 = 16 e-
Step 2:
Plausible structure:
Step 3:
Step 4:
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ONO
ONO
16 4 12 = 0
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Example 11-6
Step 5:
O=N=O
Step 6:
ONO
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1
(8) = +1
2
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O N O
ONO
1
FC(O) = 6 - 2
(6) = +1
2
FC(N) = 5 - 0
1
(8) = +1
2
FC(O) = 6 - 6
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1
(2) = -1
2
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ONO
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Example 11-7
Using the Formal Charge Concept in Writing Lewis Structures.
Write the most plausible Lewis structure of nitrosyl chloride,
NOCl, one of the oxidizing agents present in aqua regia.
2+
2-
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2+
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11-5 Resonance
+ -
O
O O
O
O O
+ -
O
O O
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N=O
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OH
HCH
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F
F
Cl
Cl
Cl
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Cl
Cl
Cl
P
Cl
Cl
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VBT
Bond is cosequence of overlapping of two atomic
orbitals
Orbital with unpaired e can only overlape
Combination of two atomic orbital will form one
moecular orbital
M.O. can be of two type i and ii
i = e density is max. along inter nuclear axis
i = e density is max. above and below
inter nuclear axis
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Steric No -2 linear
AX2
AX3
3= 3+0
AX2E1
3= 2+1
Bent
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AX3E1
AX2E2
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See saw
T shaped
Linear
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AX6
AX5L
AX4L2
Square planer
Square pyramid
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AX7
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Terminology
Bond length distance between nuclei.
Bond angle angle between adjacent bonds.
VSEPR Theory
Electron pairs repel each other whether they are in
chemical bonds (bond pairs) or unshared (lone pairs).
Electron pairs assume orientations about an atom to
minimize repulsions.
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Polar Molecules
Molecules with ends
50
Polar Molecules
5.5 Properties of
covalent bonds
Dipole moments depend on bond polarities
Dipole moments
Polar bonds
Polar bonds can result in polar
molecules, depending on
the molecules geometry
A polar molecule will align
itself in an electric field
The extent to which the
molecules align in a field is
referred to as the dipole
moment and has the Greek
symbol mu,
9.5 Properties of Covalent Bonds
Hydrogen Halides
Cl
Electronegativity
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Dipole moment of HF
Dipole Moments
Dipole Moments
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Dipole Moments
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Properties of bond
2.
3.
4.
Bond Energy
1.
2.
3.
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Bond Length
Distance between two nuclei
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Bond Length
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Bond Energies
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Bond Energies
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Chapter 11 Questions
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