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NEUTRALIZATION
Neutralization Reaction
Adding lime to neutralize acidic
soil
Treating excess acid in the
stomach with anti-acids
Definition
Neutralization is the reaction of
hydrogen ions (H+) from an acid with
hydroxide ions (OH-) from a base or
alkali to form water molecules.
Heat of neutralization is the heat
change when one mole of water is
formed from the reaction between an
acid and an alkali.
Heats of neutralization
between strong acids and
strong alkalis
Chemical
equation
HCl + NaOH
Ionic equation
H (kJ mol-1)
H+ + OH-
H 2O
- 57.3
H+ + OH-
H 2O
- 57.3
NaCl + H2O
HNO3 + NaOH
NaNO3 + H2O
H2SO4 + 2KOH
K2SO4 + 2H2O
2H+ + 2OH-
2H2O
- 114.6
Explanation.
The H for monoprotic acid is the same
because the reaction between one mole H +
and one mole of OH- will produced one mole
of water.
In diprotic acid reaction, the value of H is
double because diprotic acid produced two
mole of H+.
It undergoes complete dissociation.
Chemical equation
CH3COOH + NaOH
Ionic equation
H (kJ mol1
)
H+ + OH-
H 2O
< 57.3
H+ + OH-
H 2O
< 57.3
H+ + OH-
H 2O
< 57.3
CH3COONa + H2O
H3PO4 + KOH
K3PO4 + H2O
CH3COOH + NH3
CH3COONH4 + H2O
Explanation.
The value for H involving weak
acid is always less than 57.3
kJ/mol.
Because some of the heat given
out during the neutralization is
used to dissociate the acid
molecules completely.
Steps to be taken
Step 1: Calculate how many moles of
sodium hydroxide and hydrochloric
acid
Number of mole for NaOH (n) = Molarity (M) x
Volume (V)
= 1.0 x 50/ 1000
= 0.05 mole
Number of mole for HCl (n)
= 1.0 x 50/ 1000
= 0.05 mole
= Molarity (M) x
Volume (V)
1mole H+
OH-
react with
+
1 mole