Fundamentals of

Chem. II
Test Review
SI Session 9/18/2013

Practice Test

Question 1
Which of the following molecules should have

the most stabilizing interactions with the

molecule depicted here?

Most Stabilizing- C, A, B -Least Stabilizing

Question 2
Rank the following two sets separately by

band gap.
Largest- Si, Ge, Sn Smallest
Largest- Ge, GaAs, ZnSe -Smallest

Question 3
Rank the following in order of solubility of

gases in water at STP.

Most- O2, CO, N2, Ne -Least

Question 4
Rank the following in order of freezing point

decrease in pure water when _______ is added.

Largest- 1 mole K3PO4, 1 mole NaBr, 2

moles glucose -Smallest

Question 5
Define the following.
Colloid

Suspensions of particles larger than individual ions or molecules

but too small to be separated by gravity

Alloy

A homogeneous mixture or solid solution of two or more metals,

the atoms of one replacing or occupying interstitial positions
between the atoms of the other

Polymorphism

the property of crystallizing in two or more forms with distinct

structure

Vulcanization

The process of crosslinking polymer chains, such as those in

rubber, with short chains of sulfur atoms

Question 6
Use the following figure of potassium iodide to

answer the following questions.

Which sphere represents potassium?
Pink
Which sphere represents iodide?
Green
What type of cubic lattice is this?

Face-centered cubic

What is the empirical formula of this

compound?

KI

Question
7
A B
C
Use the diagram to answer the following.
Which represents a p-type semiconductor?
B
Which represents an n-type semiconductor?

Which would represent Ge?

A
Which would represent GeAs?
C
Which would represent GaGe?

What does VB stand for?

Valence band

CB

VB

Question 8
Circle the H that is always negative in

solution.
H (solute)

H(solvent)

H (solute-solvent)

Question 9
Pick your favorite two addition and two condensation

polymers and draw their monomer. Include their

designated recyclable number
Addition

Polyethylene (2-HDPE, 4-LDPE)

Polypropylene (5-PP)
Polystyrene (6-PS)
Polyvinyl chloride (3-V)

Condensation

Polyurethane (7-OTHER)
Polyethylene terephthalate (1-PETE)
Nylon 6,6 (7-OTHER)
Polycarbonate (7-OTHER)

Question 10
Break the following polymers repeating unit

into its corresponding monomers

What category of polymer is this?

Condensation
What is the strongest intermolecular force

between strands of this polymer?

Dipole-dipole

[N2]
1.87M
1.87M
6.37M

[H2]
2.16M
4.41M
2.16M

Initial reaction rate

2.00x105 M/s
8.34x105 M/s
2.32x106 M/s

Question 11
Some measurements of initial reaction rates are

shown below.
What is the order in respect to N 2?

What is the order in respect to H 2?

What is the overall order of this reaction?

4
What is the rate law?
Rate=k*[N2]2[H2]2
What is the value of the rate constant?
12,259

Question 12
Camphor (C10H16O) melts at 179.8oC, and it

has a particularly large freezing point

depression constant, Kf=40.0oC/m. when
0.201g of an organic substance of unknown
molar mass is dissolved in 22.01g of liquid
camphor, the freezing point of the mixture is
found to be 176.7oC. What is the molar mass
of the solute?
117.84 g/mol

Questions?