Professional Documents
Culture Documents
OBJECTIVES
In the end of this chapter the students should be able to:
i.
WATER
common chemical substance that is essential for the survival of all known
forms of life. In typical usage, water refers only to its liquid form or state, but
the substance also has a solid state (ice), and a gaseous state (water vapor or
steam).
plays an important role in the world economy, as it functions as a solvent for a
wide variety of chemical substances and facilitates industrial cooling and
transportation.
To function properly, human needs at least 8 glasses of water daily.
Approximately 70% of freshwater is consumed by agriculture.
Different bodies of water provide livelihood and economic security to different
countries.
Declining water quality has become a global issue of concern as human
populations grow, industrial and agricultural activities expand, and climate
STANDARDS
In the setting of standards, agencies make political and
technical/scientific decisions about how the water will be used.
In the case of natural water bodies, they also make some reasonable
estimate of pristine conditions.
Different uses raise different concerns and therefore different
standards are considered.
Natural water bodies will vary in response to environmental conditions.
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UNIT
Ammoniacal Nitrogen
Biochemical Oxygen
Demand
Chemical Oxygen Demand
Dissolved Oxygen
pH
Colour
Electrical Conductivity*
Floatables
Odour
Salinity
Taste
Total Dissolved Solid
Total Suspended Solid
Temperature
Turbidity
Faecal Coliform**
Total Coliform
mg/l
mg/l
I
0.1
1
IIA
0.3
3
IIB
0.3
3
mg/l
mg/l
TCU
S/cm
%
mg/l
mg/l
10
7
6.5 - 8.5
15
1000
N
N
0.5
N
500
25
25
5-7
6-9
150
1000
N
N
1
N
1000
50
25
5-7
6-9
150
N
N
N
50
NTU
count/100
ml
count/100
ml
5
10
Normal +
2 C
50
100
50
400
100
5000
5000
Notes
* = At hardness 50 mg/l CaCO3
# = Maximum (unbracketed) and 24-hour average (bracketed) concentrations
N = Free from visible film sheen, discolouration and deposits
CLASS
III
0.9
6
50
3-5
5-9
150
IV
2.7
12
V
> 2.7
> 12
100
<3
5-9
6000
2
4000
300
> 100
<1
300
Normal +
2 C
5000
5000
(20000)a (20000)a
50000
50000
> 50000
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CHEMICAL PARAMETER
Substance that dissolved in water
Total dissolved solid, alkalinity, hardness, metals, organic compounds,
and nutrients
BIOLOGICAL
Living organism that can be found in the water.
It may lead to bad taste, odor, corrosion and slime production
Pathogen
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PHYSICAL PROPERTIES
CHEMICAL PROPERTIES
TOTAL SOLID
ALKALINITY
TURBIDITY
HARDNESS
COLOR
TEMPERATURE
BIOLOGICAL PROPERTIES
BACTERIOLOGICAL PARAMETERS: COLIFORMS,
FECAL COLIFORMS,
SPECIFIC PATHOGENS, AND VIRUSES
PARAMETERS
WHAT IT INDICATES
pH
Biochemical Oxygen
Demand (BOD)
UNIT MEASUREMENT
Parameter
Value
Dissolved oxygen
mg/L or ppm
Water temperature
Degrees C or F
pH
mg/L or ppm
Nitrite
mg/L or ppm
Alkalinity/Hardness
Salinity
ppm: Most dissolved substances found in water are measured in parts per million
(ppm) or even smaller amounts. This means that for every one million parts (units)
of water there is a certain number of parts of the substance.
Concentration: Concentrations of certain substances are also measured in
parts per billion, parts per trillion and so on. These are very small amounts
but certain substances can be harmful even at these very low concentrations.
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2.2.1 PHYSICAL
PARAMETERS
FORMULA
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3. COLOR
May be due to the presence of organic matter, metals
(iron, manganese) or highly colored industrial waste
Desirable that drinking water be colorless
APHA Color (Hazen scale)
- sometimes referred to as a yellowness index that is
used to
assess the quality of liquids that are clear to
yellowish in
color.
- Desirable limit, 5 hazen unit
- Permissible limit 25 hazen unit
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4. TURBIDITY
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4. TEMPERATURE
Water temperatureis one of the most important characteristics of
an aquatic system, affecting:
Dissolved oxygen levels. The solubility of oxygen decreases as water
temperature increases.
Chemical processes.Temperature affects the solubility and reaction rates of
chemicals. In general, the rate of chemical reactions increases with increasing water
temperature.
Biological processes.Temperature affects metabolism, growth, and reproduction.
Species composition of the aquatic ecosystem. Many aquatic species can
survive only within a limited temperature range.
Water density and stratification. Water is most dense at 4C. Differences in
water temperature and density between layers of water in a lake leads to
stratification and seasonal turnover.
Environmental cues for life-history stages. Changes in water temperature may
act as a signal for aquatic insects to emerge or for fish to spawn.
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2.2.2 CHEMICAL
PARAMETERS
1. HARDNESS
Capacity of water for reducing and destroying the lather of soap
It is total concentration of calcium and magnesium ions
Temporary hardness Bicarbonates of Calcium and Magnesium
Permanent hardness Sulphates, chlorides and nitrates of calcium
and magnesium
0 50 mg/l CaCO3
- soft
50 150 mg/l CaCO3
- moderately hard
150 300 mg/l CaCO3 - hard
300 above CaCO3
- very hard
Surface water is softer than ground water
Causes encrustations in water supply structures
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Types of hardness
There are two basic types of water hardness:
1. Temporary hardness
2. Permanent hardness
Temporary Hardness
Temporary Hardness is due to the
bicarbonate ion, HCO3-, being present in the
water. This type of hardness can be removed
by boiling the water to expel the CO2.
Ca(HCO3)2CaCO3+ H2O + CO2
Heating
Mg(HCO3)2 Ma (OH)2+ 2CO2
Heating
Main Mechanism
Permanent hardness
Permanent hardness is due to the presence of the
ions Ca2+, Mg+2, Fe3+and SO4-. This type of
hardness cannot be eliminated by boiling. The
water with this type of hardness is said to
bepermanently hard.
2. ALKALINITY
pH is the measure of hydrogen ion concentration
Neutral water pH : 7
Acidic water has pH below 7
Basic water has pH above 7
Desirable limit 6.5-8.5. Beyond this limit the water will affect the mucous
membrane and water supply system
Capacity to neutralize acid
Presence of carbonates, bi-carbonates and hydroxide compounds of Ca, Mg,
Na and K
Alkalinity = hardness, Ca and Mg salts
Alkalinity > hardness - presence of basic salts, Na, K along with Ca and Mg
Alkalinity < hardness neutral salts of Ca & Mg present
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3. DISSOLVED OXYGEN
is the amount of oxygen that is present in the water. It is measured in
DO Meter
Benchtop DO Meter
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10
29
27
summer
25
0
6 a.m.
noon
6 p.m.
midnight
6 a.m.
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Epilimnion
High temperature
High dissolved oxygen
Thermocline
Hypolimnion
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BOD bottle
Note: 1 mg/L of BOD may correspond to more or less than 1 mg/L of the offensive
substance.
BOD is determined in the laboratory by measuring the depletion of dissolved oxygen
in the contaminated water placed in a closed container, over the course of several
days (usually 5 days)
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CALCULATING BOD
The ratio of undiluted sample is called the sample size, usually expressed as a
percentage, while the inverse relationship is called the dilution factor.
Sample size (%) = volume of undiluted sample x 100
volume of diluted sample
CALCULATING BOD
BODt
DOb ,t DOs ,t
P
DOb,t dissolve oxygen concentration in blank after t day of incubation, mg / L
DOs ,t dissolve oxygen concentration in sample after t day of incubation, mg / L
P dilution factor
( DOs ,i DOs ,t ) ( DOb ,i DOb,t ) f
BODt
P
DOs ,i initial dissolve oxygen of sample
DOb,i initial dissolve oxygen of blank
f ratio of seed in diluted sample to blank
(volume of seed in diluted sample) /(volume of blank )
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EXAMPLE 1
BOD
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BODt
DOb ,t DOs ,t
P
EXAMPLE 2
BOD
Suppose the estimated BOD of an influent sample is 400 mg/L and assume the DO of saturated
dilution water is 8.0 mg/L. Since the criteria for most valid results states that the DO depletion at
the end of five days incubation should be at least 2.0 mg/L and the residual DO at least 1.0
mg/L, the formulas to calculate the minimum and maximum estimated dilution.
TUTORIAL 1
A BOD measurement is to be carried out for wastewater
sample. The waste water sample inserted to BOD bottle is 10
ml. The 300 ml BOD bottle will be filled up with dilution water.
Calculate the BOD5 for the waste water using the given data.
Concentration
DO (mg/L)
Day 1
7.5
Day 5
5.0
SOLUTION
Where,
= DO of diluted sample immediately after preparation, mg/L
= DO of diluted sample after 5 days incubation at 20 C, mg/L
P = Dilution factor
TUTORIAL 2
200 mL of river water sample was collected. 2 mL of river
water diluted to 1 L, aerated and seeded. The dissolved
oxygen content was 7.8 mg/L initially. After 5 days, the
dissolved oxygen content had dropped to 5.9 mg/L. Estimate
the BOD5 of this river water sample.
SOLUTION
BOD5 = 7.8 mg/L 5.9 mg/L = 950 mg/L
2 mL/1000 mL
DIFFERENCE
B.O.D
BOD is only a measurement of
C.O.D
COD refers the requirement
microorganisms to decompose
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6. NUTRIENT
Excess nutrients cause algal blooms. As algae die and decay, the high bacterial
load rapidly consumes dissolved oxygen.
Nitrate
Increasing level of nitrate is due to Agricultural fertilizers, manure, animal dung,
nitrogenous material ,sewage pollution (blue baby diseases to infants)
Under normal conditions, the nitrogen cycle keeps the amount of available nitrogen in
balance with the demands. However, excessive use of fertilizers and nutrient rich sewage
release have created a surplus of nitrate. The result is eutrophication from excess algae
and bacteria with reduced dissolved oxygen.
Phosphate
Phosphates concentrations in clean water is generally low; however, phosphorus is used
extensively in fertilizer and other chemicals.
The primary sources of phosphates to surface water are detergents, fertilizers, and natural
mineral deposits.
High levels of phosphate can over stimulate the growth of aquatic plants and algae.
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7. METAL
IRON
One of the earths most plentiful resource
High iron causes brown or yellow staining of laundry, household fixtures
Metallic taste, offensive odour, poor tasting coffee
Cause iron bacteria
Acceptable limit 0.3 mg/l
FLUORIDE
Occurs naturally
Long term consumption above permissible level can cause
dental flurosis (molting of teeth)
Skeletal flurosis
Acceptable limit 1 mg/l
Maximum permissible limit 1.5 mg/l
Remedy 1) Deflouridation
2) Mixing Fluoride free water
3) Intake of vitamin C,D, calcium, antioxidants
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METAL
Arsenic
Occur in ground water
Industrial waste, agricultural insecticide
High arsenic causes 1) various type of dermatological lesions, muscular weakness,
paralysis of lower limbs, can also cause skin and lung cancer
Acceptable limit 0.05 mg / l
Heavy Metal
Present as mineral in soil and rocks of earth
Human activities
Battery Lead & Nickel
Textile - Copper
Photography Silver
Steel production Iron
Spektrofotometer DR6000
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COLORED WATER
Green or blue water: Usually caused by corrosion of copper
plumbing.
Black or dark brown water: Often caused by manganese in
the water or pipe sediment.
Brown, red, orange or yellow water: Usually caused by
iron rust.
Milky white or cloudy water: Usually caused by tiny air
bubbles. If your water is white, fill a clear glass with water and
set it on the counter. If the water starts to clear at the bottom
of the glass first, the cloudy or white appearance is trapped
air.
BIOLOGICAL PARAMETER
PATHOGENS
Capable of infecting and transmitting diseases to human
Bacteria: Bacteria constitute a large domain of prokaryotic
microorganisms. Typically a few micrometers in length, bacteria have a
number of shapes, ranging from spheres to rods and spirals.
Fungi: can produce musty taste and odour as well as colour and turbidity.
Algae: Increase the level of DO in water. But too much of algae, will affect
taste and smell and can reduce the intensity of light penetration.
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