Professional Documents
Culture Documents
Matter
States of Matter
Meltin
g
Liquid
Freezing
Condensati
on
Sublimatio
n
Depositi
on
Gas
Vaporizati
on
Ionizatio
n
Plasm
a
Deionizatio
n
Gases
Properties of Gases
Gas Pressure
Properties of Gases
12
Gas Pressure
Gas pressure:
Is described as a force acting on a specific area
Pressure (P) = Force
Area
Has units of atm, mm Hg, torr, and pascals
1 atmosphere (1 atm) is 760 mm Hg
1 mm Hg = 1 torr
1.00 atm = 760 mm Hg = 760 torr
13
Origin of Pressure
Units of Pressure
Gas pressure,
Is described as a force acting on a specific area
15
Learning Check
A. What is 475 mm Hg expressed in atm?
1) 475 atm
2) 0.625 atm
3) 3.61 x 105 atm
B. The pressure in a tire is 2.00 atm. What is this
pressure in mm Hg?
1) 2.00 mm Hg
2) 1520 mm Hg
3) 22 300 mm Hg
16
Solution
A. What is 475 mm Hg expressed in atm?
2) 0.625 atm
475 mm Hg x 1 atm
= 0.625 atm
760 mm Hg
B. The pressure of a tire is measured as 2.00 atm. What is
this pressure in mm Hg?
2) 1520 mm Hg
2.00 atm x 760 mm Hg = 1520 mm Hg
1 atm
17
Atmospheric Pressure
The atmospheric pressure:
Is the pressure exerted
by a column of air from
the top of the
atmosphere to the
surface of Earth
Is about 1 atmosphere
or a little less at sea
level
18
19
Barometer
A barometer:
Measures the pressure
exerted by the gases
in the atmosphere
Indicates atmospheric
pressure as the height
in mm of the mercury
column
20
Learning Check
A. The downward pressure of the Hg in a barometer is
_____ than (as) the pressure of the atmosphere.
1) greater
2) less
3) the same
B. A water barometer is 13.6 times taller than a Hg
barometer (DHg = 13.6 g/mL) because:
1) H2O is less dense
2) H2O is heavier
3) air is more dense than H2O
21
Solution
A.The downward pressure of the Hg in a barometer is
3) the same (as) the pressure of the atmosphere.
B. A water barometer is 13.6 times taller than a Hg
barometer (DHg = 13.6 g/mL) because:
1) H2O is less dense
22
Atmospheric Pressure
Atmospheric pressure is the
force per unit area exerted into a
surface by the weight of air
above that surface.
Atmospheric pressure is calculated in various
units. The following equivalence is the most
commonly used.
Temperature
It is a measure of the thermal
energy of molecules or atoms of a
substance.
Temperature too has many units as
pressure.
The relationship between these
scales can be summarized as
follows:
F= (9/5)C + 32
K= C + 273
Gas Laws
There are six main gas laws
associated with the behavior of
gases:
1.Boyles Law
2.Charles' Law
3.Charles-Gay-Lussacs law
4.Combined Gas Law
5.Avogadro's law
6.Daltons law of partial pressure
THE GAS
LAWS
BOYLES LAW
The
inverse
relationship
between pressure and volume
It states that the volume of a
sample
of
gas
changes
inversely with the pressure of
the gas as long as the
temperature and the amount
of the gas remain constant.
Boyles Law
Applicable only if: Temperature
stays constant
Applicable to:
1.Ideal gases at any temperature
2.Real gases which behave
approximately as ideal gases
specially at high temperatures.
P1V1 = P2V2
SAMPLE PROBLEMS:
1. A tank of nitrogen has a
volume of 14.0 L and a
pressure of 760.0 mmHg.
Find the volume of the
nitrogen when its pressure is
changed to 400.0 mmHg
while the temperature is
held constant.
CHARLES LAW
States that the Kelvin temperature
and the volume of a gas are directly
related when there is no change in
pressure or amount of gas.
The relationship between volume
and temperature was first observed
by French physicist and balloonist
Jacques Charles.
Charles' Law
Applicable only if: Pressure stays
constant
Applicable to:
1.Ideal gases at any temperature
2.Real gases which behave
approximately as ideal gases
specially at low pressures.
V1 V2
T1 T2
V1 V2
T1 T2
SAMPLE PROBLEMS
1. A balloon has a volume of
2500.0 mL on a day when
the temperature is 30.00C. If
the temperature at night
falls to 10.00C, what will the
volume of the balloon if the
pressure remains constant?
GAY-LUSSACS LAW
Temperature
and
pressure relationship
P1 P2
T1 T2
n1 n 2
V1 V2
SAMPLE PROBLEMS:
1. The gas left in a used
aerosol can is at a
pressure of 100 kPa at
270C. If the can is thrown
onto a fire, what will the
internal
pressure
be
when its temperature
reaches 9270C?
.
The
pressure
in
automobile tire is 200 kPa
at a temperature of 270C.
At the end of a journey on
a hot sunny day, the
pressure has risen to 223
kPa.
What
is
the
temperature of the air in
the tire?
AVOGADROS LAW
V1 V2
n1 n2
SAMPLE PROBLEMS
If 23.1 g of oxygen
occupies a volume of 5.0
L
at
a
particular
pressure
and
temperature,
what
volume will 2.5 g of
oxygen
gas
occupy
under
the
same
conditions?
Determine
the
volume
in
liters
occupied by 0.202
mol of a gas at STP.
How many oxygen
molecules are in 3.3
liters of oxygen gas
at STP?
Determine
the
volume
in
liters
occupied by 14.0 g
of N2 at STP.
What
volume
is
occupied by 4.02 x
1022 molecules of 22
g of H2 at STP?
When P is
maintained
constant,
V/T = k. Therefore
the system obeys
When T is
maintained
constant, PV =
k. Therefore the
system obeys
the Boyles law.
SAMPLE PROBLEMS:
1. A given mass of gas has a
volume of 800.0 mL at
23.00C and 300.0 torr. What
would the volume of the gas
be at 27.00C and 600.0 torr of
pressure? The amount of gas
is constant.
PV= nRT
Where:
At STP,
P= 1.0 atm= 101.325 kPa
V= 22.4 L
n= 1.0 mole
T= 273 K
R= 0.0821 atm x L/ mol x K
= 8.31kPa x L/ mol x K
SAMPLE PROBLEMS:
Summary
Ideal gas
equation
PV =nRT
When
either
mass
or the
no. of
moles
are
given
When T1 =
T2
Gas law
problems
When the
mass of a
given gas
is
constant
When P1=
P2
Charless
Boyles law
law
PV= k
V/T = k
Combined
gas equation
(PV)/T = k
When V1=
V2
Charles-Gay
Lussacs law
P/T = k
DALTONS LAW
At constant volume and
temperature, the total
pressure exerted by a
mixture of gases is
equal to the sum of the
partial pressures of the
component gases.
Ptotal=
P1+P2+P3
SAMPLE PROBLEMS
Determine
the
total
pressure of a gas mixture
that contains oxygen,
nitrogen, and helium if
the partial pressures of
the gases are 20.0 kPa,
46.7 kPa, and 26.7 kPa
respectively.