Professional Documents
Culture Documents
Chemical
Bonding
Ionic bonding
Electrostatic attraction
b/w oppositely charged
ions
Ions form crystal lattice
orderly pattern
Maximizes attraction b/w
oppositely charged ions
Minimizes repulsions
among like-charged ions.
So
See graph
Coulombs law
Coulombs Law:
used to calc nrg of
interaction b/w a pair
of ions
Q1 and Q2 = charges
on ions
R = distance b/w ion
centers (in nm)
k = 2.31 x 10-19 Jnm
Lattice energy
Modified form of
Coulombs law
Only difference is k
(value depends on
ions in crystal lattice)
Measures stability of
crystal lattice
Lattice nrg as
charge of ions and
radius
.
Practice Problem #1
Practice Problem #2
Covalent bonding
Shared equally:
Shared unequally:
Formed b/w....
Bonding of H2
Silicon a semiconductor
Doped silicon
Bonding models
Fundamental properties of
models
Lewis Structures
A few reminders
Practice Problem #3
Draw the Lewis structures for
C2H2
ICl4-
NO2
Review: Resonance
Practice Problem #4
Practice Problem #5
a)
b)
c)
d)
Practice Problem #6
VSEPR
See example
Practice Problem #7
1) SnCl3-
2) O3
3) SF4
4) IF5
Bent around O
Hybridization
Degenerate orbitals
sp hybridization
sp2 hybridization
sp3 hybridization
Practice Problem #8
Give the expected hybridization of the
central atom in the following molecules:
a)
SF4
b)
XeF2
c)
PF6-
d)
CO
Sigma () bonding
Centered on line
running b/w 2 atoms
sharing a pair of es
Shared e pr occupies
space b/w the two
atoms
bond =
bond
Can form from
overlap of.
Pi () bonding
Represents shared e- pr
above and below the
bond.
Formed using the p
orbitals perpendicular to
bond axis
Parallel p orbitals share
an e- pr, forming a bond
Forms from sideways
overlap of
orbitals.
Can also form from
overlap of d orbitals, but
we wont consider these.
Easy as 1-2-3!
Single bonds =
Double bonds =
Triple bonds =
bond
bonds
bonds
Practice problem #9
Determine # of sigma & pi bonds in the
following molecules:
1.
C2H2
2.
C3H4
3.
CH3COCOCH3
a)
b)
c)
Predicting molecular
polarity
Caused by difference in
electronegativity of the bonded
atoms
c) O2:
b) CS2:
d) IF3