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FOR ELECTRODE
POTENTIAL (E):
Et = E0 + RT/nF ln [Mn ] where;
+
Notes:
The arrangement of metals in order of
their standard electrode potential
gives the electrochemical series
(Table 1).
A metal with a more ve potential will
displace any other below it in the
series from its salt solution , thus iron
will displace copper or mercury from
their salt solutions.
System E0(volts)
Li/Li+
K/K+
-2.92
Mg/Mg2+ -2.37
Al/Al3+ -1.33
Zn/Zn2+ -0.44
Fe/Fe2+ -0.44
System E0(volts)
Cd/Cd2+
-0.40
Sn/Sn2+ -0.13
H2(pt)/H+
0.00
Cu/Cu2+
+0.34
Hg/Hg2+
+0.79
Ag/Ag+
+0.80
Silver tree
+0.77
H2/2H+
Fe2+/Fe
0.00
-0.44
Notes:
The higher E0 , the stronger the oxidizing power
of its oxidant and the weaker the reducing
power of its reduced form.
The most powerful oxidizing agent are those at
the top (highly +ve) and the most powerful
reducing agent are at the bottom (highly
ve)
If any two redox systems are combined , the
stronger oxidizing agent gains electrons from
the stronger reducing agent with the
formation of weaker reducing and oxidizing
agents.
Cl2/Cl-=(E0+1.36V), Fe3+/Fe2+(E0=+0.77V)
Cl2
strong
oxidizing agent
reducing
2 Fe2+
Fe3+
+ 2 Cl-
Strong
reducing agent
agent
agent
Effect of [H+]
The oxidation potential of an oxidizing agent containing
oxygen increases by increasing acidity and vice versa
Potassium permenganate:
MnO4- + 8H+ +5e
Mn2+ + 4H2O
EMnO4-/Mn2+=E0 + 0.0591 log [MnO4-[H+]8/[Mn2+]
5
Potassium dichromate:
Cr2O72- + 14H+ + 6e
2Cr3+ + 7H2O
E = E0 + 0.0591/6 log [Cr 2O72-][H+]14 / [Cr3+]2
(Cr2O7/Cr3+)
AsO43- + 2I- + 2H +
AsO3
3-
+I2 + H2O
H+
2+