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Speaker: Yi-Chang Wu (
)
d98524013@ntu.edu.tw
PSE Laboratory
Department of Chemical
Extractive Distillation
Ref: http://www.aspentech.com/products/aspen-plus.cfm
More Detailed
Properties analysis
Properties of pure component and mixtures (Enthalpy,
density, viscosity, heat capacity,etc)
Phase equilibrium (VLE, VLLE, azeotrope calculationetc)
Parameters estimation for properties models (UNIFAC
method for binary parameters, Joback method for boiling
pointsetc)
Data regression from experimental deta
Process simulation
pump, compressor, valve, tank, heat exchanger, CSTR,
PFR, distillation column, extraction column, absorber,
filter, crystallizeretc
Lesson Objectives
Familiar with the interface of Aspen Plus
Learn how to use properties analysis
Learn how to setup a basic process
simulation
Problem Formulation 1:
Calculation the mixing
properties of two stream
10
0
0
10
50
1
?
?
?
0
9
6
15
80
1
?
?
?
?
?
?
?
?
1
?
?
?
?
?
?
?
?
10
?
?
?
Mass Balance
Energy Balance
Enthalpy
Entropy
Problem Formulation 2:
Flash Separation
120
T-x
T-y
Saturated Feed
P=1atm
F=100 kmol/hr
zwater=0.5
zHAc=0.5
T=105 C
P=1atm
T ( C)
115
110
105
100
0.0
0.2
0.4
0.6
0.8
1.0
Problem Formulation 3:
Dehydration of Acetic Acid by
Distillation
(Optional) Column
1.0
Duty ?
0.6
yWater
Reflux
ratio ?
0.8
0.4
0.2
0.0
0.0
0.2
0.4
0.6
xWater
0.8
1.0
Outline
Startup in Aspen Plus (Basic Input) (45 min)
User Interface
Basic Input: Setup, Components, Properties.
Properties Analysis (1 hour)
Pure Component
Mixtures (phase equilibrium)
Running Simulation (1 hour)
Blocks (Unit Operations)
Streams (flow streams)
Results
11
14
Status message
15
More Information
16
Data Browser
The Data Browser is a sheet and form
viewer with a hierarchical tree view of the
available simulation input, results, and
objects that have been defined
17
Basic Input
The minimum required inputs to run a
simulation are:
Setup
Components
Properties
Streams
Blocks
Property Analysis
Process Simulation
18
Setup Specification
Run Type
Input mode
19
Components
Specification
Input components
with Component name or Formula
20
Input components
21
Specification
To do this
Click this
button
Find
User Defined
Elec Wizard
Reorder
Review
22
Find Components
Click Find
23
Find Components
(contd)
24
Properties
Process type(narrow the number of
methods available)
25
26
Assistant Wizard
27
Reference: http://www.et.byu.edu/groups/uolab/files/aspentech/
28
NRTL
29
NRTL Binary
Parameters
30
31
Pure Component
Temperature-Dependent
Properties
CPIGDP
-1
Liquid density
DHVLD
P-1
Heat of vaporization
Liquid thermal
conductivity
33
Example: PLXANT-1
(Extended Antoine
Equation)
Corresponding Model
34
Example: CPIGDP-1
(Ideal Gas Heat Capacity
Equation)
Corresponding Model
35
Summary
36
File Type
Extensio Forma
n
t
Description
Document
*.apw
Binary
Backup
*.bkp
ASCII
History
*.his
Text
37
Overview of Property
Analysis
Use this
form
To generate
39
Reminding
When you start properties analysis,
you MUST specify components ,
properties model, and
corresponding model
parameters. (Refer to Part I)
40
To generate
41
42
Available Properties
Property (thermodynamic)
Availability
Constant pressure
heat capacity
Heat capacity
ratio
Constant volume
heat capacity
Free energy
departure
Free energy
departure
pressure
correction
Free energy
Enthalpy
Fugacity
coefficient
Fugacity
coefficient
pressure
correction
Property
(transport)
Thermal
conductivity
Surface tension
Viscosity
Vapor pressure
Density
43
Example1: CP (Heat
Capacity)
1. Select property (CP)
4. Specify range of temperature
2. Select phase
5. Specify pressure
Add N-butyl-acetate
3. Select component
Example1: Calculation
Results of CP
Data results
45
Example2: H (Enthalpy)
3. Select component
46
Example: Calculation
Results of H
Data results
47
To generate
48
Example: T-XY
1. Select analysis type (Txy)
5. Specify pressure
Example: calculation
result of T-XY
Data results
Example: Generate XY
plot
Property Analysis
Generic
Use this
form
To generate
55
Ternary Map
5. Specify pressure
6. Specify temperature
(if LLE is slected)
7. click Go to generate the results
Data results
To generate
59
Conceptual Design
Azeotrope Analysis
Azeotrope Analysis
1. Select components (at least two)
2. Specify pressure
Error Message
Ternary Maps
Ternary Maps
3. Select property method
1. Select three components
2. Specify pressure
Ternary Maps
Change pressure or
temperature
10
0
0
10
50
1
?
?
?
0
9
6
15
80
1
?
?
?
?
?
?
?
?
1
?
?
?
?
?
?
?
?
10
?
?
?
69
Setup Specification
Select Flowsheet
70
71
Adding a Mixer
72
73
74
Red arrow(Right):
Blue arrow: Water
Product (Required; if
decant for Free water
mixing material streams) of dirty water.
75
76
Reconnecting Material
Streams (Feed Stream)
Right Click on the stream and
select Reconnect Destination
77
Reconnecting Material
Streams (Product
Stream)
Right Click on the stream and
select Reconnect Source
B1
1
78
Specifying Feed
Condition
Right Click on the stream
and select Input
79
Specifying Feed
Condition
You must specify two of the following
conditions:
Temperature
Pressure
Vapor fraction
Specifying Feed
Condition (contd)
1
81
82
Run Simulation
Click to run the simulation
Run
Step
Stop
Reinitializ
e
Status of Simulation
Results
Message
Means
Results
available
Results with
warnings
Results with
errors
Input Changed
Stream Results
86
1
Substream: MIXED
Mole Flow kmol/hr
WATER
BUOH
BUAC
Total Flow kmol/hr
10
0
10
0
9
9
0
6
6
10
15
25
180.15 1364.0 1544.2
Total Flow kg/hr
28
66
18
0.1858 1.7402 1.8705
Total Flow cum/hr
2
1
09
70.087
Temperature C
50
80
58
Pressure bar
2
1
1
Vapor Frac
0
0
0
Liquid Frac
1
1
1
Solid Frac
0
0
0
Enthalpy kcal/mol -67.81 94.372 83.747
6
6
Enthalpy kcal/kg 3764.0 1037.7 1355.8
3
7
2
- 87
Enthalpy Gcal/hr -0.6781 1.4155 2.0936
88
89
90
91
92
93
Connect Streams
94
Pump Specification
1. Select Pump or turbine
3. Efficiencies (Default: 1)
95
Run Simulation
Click to generate the results
97
98
Streams Results
99
Calculation Results
(Mass and Energy
Balances)
4
10
9
6
25
71.20
10
-83.69
-95.46
824.29
100
Exercise
10
0
0
10
50
1
?
?
?
0
5
0
15
70
1
?
?
?
0
0
15
15
40
1
?
?
?
?
?
?
?
?
1
?
?
?
?
?
?
?
?
4
?
?
?
?
?
?
?
?
2
?
?
?
101
Example 2: Flash
Separation
120
T-x
T-y
Saturated Feed
P=1atm
F=100 kmol/hr
zwater=0.5
zHAc=0.5
T=105 C
P=1atm
T ( C)
115
110
105
100
0.0
0.2
0.4
0.6
0.8
1.0
Input Components
Thermodynamic Model:
NRTL-HOC
Association parameters
of HOC
Binary Parameters of
NRTL
Binary Analysis
T-xy plot
1. Select analysis type (Txy)
5. Specify pressure
6. Select property method
Data results
Generate xy plot
Flash Separation
120
T-x
T-y
Saturated Feed
P=1atm
F=100 kmol/hr
zwater=0.5
zHAc=0.5
T=105 C
P=1atm
T ( C)
115
110
105
100
0.0
0.2
0.4
0.6
0.8
1.0
Saturated Feed
(Vapor fraction=0)
P=1atm
F=100 kmol/hr
zwater=0.5
zHAc=0.5
Flash2: Specification
T=105 C
P=1atm
Required Input
Incomplete
Connot click to run simulation
Stream Results
Saturated Feed
P=1atm
F=100 kmol/hr
zwater=0.5
zHAc=0.5
T=105 C
P=1atm
57.342 kmol/hr
zwater=0.432
zHAc=0.568
Distillation Separation
RR ?
QR ?
Saturated Feed
(Vapor fraction=0)
P=1.2atm
F=100 kmol/hr
zwater=0.5
zHAc=0.5
Radfrac: Configuration
Radfrac: Column
Pressure
Run Simulation
Click to run simulation
Check Convergence
Status
Stream Results
Again
Smarter Way
Design Specs:
Specification
Design Specs:
Components
Very: Specifications
Selection of Adjusted
Variables
Run Simulation
Click to run simulation
Check Convergence
Status
Check Convergence
Status
Column Performance
Summary
Summary of Condenser
Summary of Reboiler
Plot Wizard
Plot Types
Composition Profiles
Temperature Profiles
Examples:
1.IPA-Water-DMSO
Isopropyl Alcohol
Water
Dimethyl Sulfoxide
COMPONENTS SPECIFICATION
Input components
with Component name or Formula
Click Find
167
RENAME COMPONENTS ID
Isopropyl Alcohol
Water
Dimethyl Sulfoxide
168
NRTL
169
170
171
IPA
IPA
H 2O
Comp,j
H 2O
DMSO
DMSO
aij
-1.2449
aji
1.7524
bij
185.4
115.2787
586.801
bji
777.3
-25.0123
-1130.215
cij
0.50
0.3
0.30
172
Ternary Maps
Ternary Maps
1. Select three components
3. Select property method
2. Specify pressure
Ternary Maps
Change pressure
DMSO
4.0
3.5
3.0
2.5
2.0
1.5
1.0
0.0
0.5
1.0
1.5
2.0
2.5
3.0
when
Entrainer feed
1
Azeotrope feed
3.23
yH 2O / xH 2O 0.118 / 0.153
(A-F)/(E-F)
10
2.5
0.25
1.8
10
0.5
2.43
10
7.5
0.75
2.9
10
10
3.23
10
12.5
1.25
3.5
10
15
1.5
3.7
10
17.5
1.75
3.86
10
20
3.98
10
22.5
2.25
4.08
10
25
2.5
4.16
10
27.5
2.75
4.22
10
30
4.28
4.5
DMSO
A-F
(kmol/h)
4.0
3.5
3.0
2.5
2.0
1.5
1.0
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Extractive Distillation
SETUP SPECIFICATION
Run Type
Input mode
188
Add Units-Sets
Add Units-Sets
REPORT OPTIONS
COMPONENTS SPECIFICATION
Input components
with Component name or Formula
Click Find
192
RENAME COMPONENTS ID
193
NRTL
194
195
196
IPA
IPA
H 2O
Comp,j
H 2O
DMSO
DMSO
aij
-1.2449
aji
1.7524
bij
185.4
115.2787
586.801
bji
777.3
-25.0123
-1130.215
cij
0.50
0.3
0.30
197
RENAME STREAM
Feed
(Saturated Liquid Feed)
Vapor fraction = 0
P = 2 atm
F = 100 kmol/hr
z IPA =0.5
z WATER =0.5
EF
P = 2 atm
T = 184.5 oC
F = 100 kmol/hr
z DMSO =1
MAKEUP
P = 2 atm
T = 25 oC
F = 0 kmol/hr
z DMSO =1
BLOCK INPUT
BLOCK INPUT
BLOCK INPUT
RUN SIMULATION
Click to run simulation
Check result
DESIGN SPECS/VARY
VERY: SPECIFICATIONS
RUN SIMULATION
DESIGN SPECS/VARY
VERY: SPECIFICATIONS
RUN SIMULATION
D1
D2
RECYCLE STREAM
RECYCLE STREAM
RECYCLE STREAM
TEAR
SUMMARY OF REBOILER
B1
B2
TRAY SIZING
237
TRAY SIZING
238
TRAY SIZING
239
TRAY RATING
240
TRAY RATING
241
242