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4 Group 2
What is the outcome from syllabus?
Candidates should be able to:
(a) describe the reactions of the elements with oxygen and water
(b) describe the behaviour of the oxides with water
(c) describe the thermal decomposition of the nitrates and carbonates
(d) interpret, and make predictions from, the trends in physical and
chemical properties of the elements and their compounds
(e) explain the use of magnesium oxide as a refractory lining material
and calcium carbonate as a building material
(f) describe the use of lime in agriculture
5.3 Group 2
Alkaline metal:
ns2
Be
Mg
Ca
Sr
Ba
Ra
12+
Mg
5.3 Group 2
BERYLLIUM
STRONTIUM
MAGNESIUM
BARIUM
CALCIUM
RADIUM
5.3 Group 2
The Flame Color:
Element
Color
Element
Color
Li
Scarlet
Be
Na
Yellow
Mg
Lilac
Ca
Brick-red
Rb
Red
Sr
Crimson
Cs
Blue
Ba
Apple-green
5.3 Group 2
Increasing electronegativity
Increasing
electronegativity
II
III
IV
Li
Be
Period 2
Na
Mg
Al
Si
Period 3
Diagonal relationships ( )
The untypically large electronegativities of Period 2 elements
(caused by their small size) mean that they are in some ways
more typical of elements one group to the right than to elements
of their own group.
For example: Be(OH)2 + 2H+ Be2+ + 2H2O
Be(OH)2 + 2OH [Be(OH)4]2
5.3 Group 2
The physical properties of Group 2:
Electron
Metallic
First +
Tm/K
arrangement radius/nm Second IE/
kJ mol-1
Tb/K
Density
/g cm-3
Mg
Magnisum
[Ne]3s2
0.160
2189
922
1380
1.74
Ca
Calcium
[Ar]4s2
0.197
1735
1112
1757
1.54
Sr
Strontium
[Kr]5s2
0.215
1614
1042
1657
2.60
Ba
Barium
[Xe]6s2
0.224
1468
998
1913
3.51
5.3 Group 2
Magnesium oxide
2Mg (s) + O2 (g)
2MgO (s)
a. in the air
b. in oxygen
5.3 Group 2
2
.
.
.O .
oxygen ion
2
.
..OO
.
peroxide ion
. ..
..OO
superoxide ion
The reason that there are different types of oxides is related to the
sizes of the ions:
O2 > O22 > O2
If the cation is too small, it is not easy for enough peroxide or
superoxide ions to cluster round it to form a stable crystal
lattice. For example, Lithium can only forms the normal oxide.
5.3 Group 2
5.3 Group 2
Reaction with water
Mg (s) + 2H2O (l)
slowly
steam
rapidly
Beryllium does not react directly with water all. The rest of the Group
II metals react with increasing rapidity on descending the group.
5.3 Group 2
Oxide reaction with water
MgO (s) + H2O (l)
Mg(OH)2 (aq)
Partially soluble
5.3 Group 2
Reaction with acids
Mg (s) + H2SO4(aq)
5.3 Group 2
Thermal stability describes how easily or otherwise a compound will
decompose on heating. Increased thermal stability means a higher
temperature is needed to decompose the compound.
Group II
Carbonates,
CO32
Nitrates,
NO3
Mg
Ca
Sr
Ba
Mg
Ca
Sr
Ba
NO2 + O2-
5.3 Group 2
Which one of the following equations represents the
reaction that occurs when calcium nitrate is heated
strongly?
A. Ca(NO3)2 Ca(NO2)2 + O2
B.
5.3 Group 2
Which one of the following elements is likely to have
an electronegativity similar to that of aluminium?
A. Barium
B. Beryllium diagonal relationship
C. Calcium
D. Magnesium
E. Strontium
5.3 Group 2
Which one of the following statements is true?
A. All nitrates of Group II metals are decomposed by heat
to give the oxide NO2
coins
Ship
cosmetics
pipe
Melting point/
MgO
2852
CaO
2614
SrO
2430
BaO
1918
refractory
material
As M2+ cationic size increases down the Group, the ionic bonds
become weaker, hence, less energy is needed to break the
bonds and a low melting point is expected.
C. ionic
D. metallic
CaCO3(limestone)
+ CO2
Ca(OH)2(slaked lime)
+ H2O
CaO(lime)
+
2+
2.
Ca(OH)
+
2H
(aq)
Ca
(aq) + 2H2O
2
3. Ca(OH)
2. calcium hydroxide
3. potassium nitrate
temporary hardness
permanent hardness
calcium stearate
B. CaCO
C. MgCO3
D. Mg(NO3)2
Chemical
Formula
Chemical Reaction
Mg(OH)2
Mg(OH)2 + 2H+
Mg2+ + 2H2O
CaCO3
CaCO3 + 2H+
Ca2+ + H2O + CO2 (g)
NaHCO3
NaHCO3 + H+
Na+ + H2O + CO2 (g)
Al(OH)3
NaAl(OH)2CO3
NaAl(OH)2CO3 + 4H+
Na++ Al3++ 3H2O +
CO2(g)
SO42-
CrO42-
C2O42-
Mg2+
1.5
1830
8500
5.7
Ca2+
0.13
47
870
0.05
Sr2+
0.07
0.71
5.9
0.29
Ba2+
0.09
0.009
0.01
0.52
decreases
down the
group
NaCl (s)
Hsolu
Na+(aq) + Cl(aq)
Hlatt =
Hhyd =
772 kJmol-1
776 kJmol-1
Na+(g) + Cl(g)