Additives

ever creative and

innovative for the
polymer industry

Profile of
Foundation 1917
Business
Chemicals & Foods
Paid-in capital
206 Million US$
Turnover 2005
Consolidated: 1.5 Billion US $
Single:
1.1 Billion US$
A member of Furukawa Group

corporation

ADEKA Worldwide Location

R&D Lab. and Plants in Japan

3 R&D Lab.

SOHMA

KUKI

OGU

KASHIMA-NISHI

URAWA
KASHIMA

CHIBA
AKASHI

MIE
6 Plants

Qualitiy Assurance System

Quality Assurance very important

1t Stabilizer hundreds tons of resin

ISO 14001 certified in 1996

earliest of all Japanese manufacturers

ISO 9001 certified in 2002

OHSAS certified in 2001

Organisation in Europe

Sales Profile
Net Sales: $ 1.5 billion (2005/04-2006/03)

Polymer Additives

Foods
IT related
Chemicals

Other Chemicals

Epoxy Resins
Surfactants
Lubricants
Others

ADDITIVES PRODUCT LINE UP

Antioxidants (AO Series)

UV Absorber (LA Series)

POLYOLEFINS &
ENGINEERING
PLASTICS

Plastic Articles

Plastic Articles

Hindered Amine Light

Stabilizers (LA Series)

Automotive Applications

Nucleators / Clarifiers

Automotive Applications
Food Packaging

(NA Series)
Flame Retardants
(FP Series)

Electronic Appliances
Construction Applications

Plasticizers

General Purpose &

High Performance

Stabilizers

General Purpose &

High Performance

PVC

ANTIOXIDANTS
Sulphor containing AO

Phenolic AO
ADK STAB AO-20

ADK STAB AO-80

ADK STAB AO-26

ADK STAB AO-412S

Antioxidant with low

extractability for PP fibres

High performance antioxidant for

PP fibres, engineering plastics

Antioxidant for w&c (crosslinked

PE)

Thiosynergist for high

temperature applications

ADK STAB AO-30

PALMAROLE AO.OH.98

PALMAROLE AO.S.STDP

General purpose antioxidant for

styrenics

Special antioxiant for polyamides

General purpose thiosynergist

ADK STAB AO-40

PALMAROLE AO.OH.330

Antioxidant for elastomers and

styrenics

Antioxidant with low extractability

ADK STAB AO-50F

PALMAROLE AO.OH.570

General purpose antioxidant

Specific antioxidant for POM and

styrenics

ADK STAB AO-60

General purpose antioxidant

Phosphites AO

Binary Blends

ADK STAB HP-10

ADK STAB PEP-36

High performance phosphite for

polyolefins such as LLDPE

High performance phosphite with

high hydrolysis resistance and
thermal stability

ADK STAB PEP-8HT

ADK STAB 1178

General purpose phosphite for

polymers such as polyolefins,
styrenics

TNPP

ADK STAB PEP-24G

ADK STAB 2112

General purpose process stabiliser

for polyolefins

General purpose processing

antioxidant

Full range of liquid phosphites. Costabilization of PVC and

elastomers

- ADK STAB A611: AO 60/2112 (1:1)

- ADK STAB A612: AO 60/2112 (1:2)
- ADK STAB A514: AO 50/2112 (1:4)
Blends ADK STAB AO60/2112 with different ratios
Blends with phenolic phosphites

NUCLEATING AGENTS
ADK STAB NA-11UH
Organic phosphate salt providing increased stiffness, whilst maintaining impact properties and cycle time reduction

ADK STAB NA-901 / NA-902

New generation designes for benzoates replacement

PALMAROLE MI.NA.08 / PALMAROLE MI.NA.20

General purpose nucleating agents (benzoates)

CLARIFYING AGENTS
ADK STAB NA-21
Metal salt of organic phosphate providing increased transparency of homo and random PP as well as enhancement of mechanical properties. Excellent thermostability, no
odour, no deposit

ADK STAB NA-71

New clarifying agent particularly for blow moulding applications

METAL DEACTIVATORS

ANTISTATIC AGENTS

ADK STAB CDA-1

ADK STAB ZS-90

ADK STAB AS-113

PALMAROLE STAT-09

ADK STAB CDA-6

For deactivation of iron and other

metallic contaminants

Specifically for PC/ABS alloys

Distilled GMS for polyolefins

High temperature copper deactivator

PALMAROLE MDA.P.10

PALMAROLE MDA.P.11

Traditional copper deactivator

Mainly used in polyolefin for wire

and cable application

FLAME RETARDANTS
Phosphate-based low volatility flame retardants
ADK STAB FP-700 / FP-600

Intumescent system
ADK STAB FP-2100J / FP-2200

New nitrogen-phoshorus based FR with high flame retardancy and

good physical properties
Can be processed at high temperature
Excellent colour stability
High water resistance
Approx. 20% loading in PP is sufficient to attain UL-94/V-0 rating
(1,6mm)

*Physiological effects of CO;

at 1200 ppm, headache, dizziness and nausea within 20 minutes; Death within 1 hour

CO-STABILIZERS
ADK CIZER EP-17

PALMAROLE HT

Epoxy.Acid neutraliser

Synthetic hydrotalcite. Acid

neutraliser

BLOWING AGENTS

Extrusion process

Injection moulding process

PE / PP Resins
BA.M2.E / BA.F2.E / BA.K2.E

BA.M4.E / BA.F4.E

are mainly used for sink mark removal

are mainly used for extruded profiles and sheets

applications with coarse or medium cells structure

BA.M4.E / BA.F4.E / BA.M7.E

BA.K2.E / BA.F3.EF

are mainly used for weight reduction

are mainly used for extruded films and sheets

applications with very fine cells structure

PS / ABS Resins

PS Resins

BA.F2.S / BA.K2.S

BA.K2.S1 / BA.K3.EF

are mainly used for sink mark removal

are mainly used for extruded films and sheets with

very fine cell structure, for thermoforming application

BA.F4 / BA.K5.S
are mainly used for weight reduction

Engineering Resins
BA.K2.S / BA.K2.P
are mainly used for sink mark removal

BA.F4.S / BA.K5.S / BA.C5.E

are mainly used for weight reduction

PET Resins
BA.F4.S / BA.K4.S / EXP 141-92B
are mainly used for extruded sheets with medium and
fine cells structure respectively thermoforming
applications

ADDITIVES PREPARATIONS
ADDITIVES PREPARATIONS
Melt blends (MBA) and/or compacted blends (CB) of additives

ADDITIVES MASTERBATCHES
Both cutom-made and proprietary

HIGH PERFORMANCE COMPOUNDS

ORGATER
PBT based compounds (reinforced, fireproofed, tailor-made color)

TRIBOLOGICAL COMPOUNDS TISMO REINFORCED

COMPOUNDS
Especially suitable for small-size precision parts

PALMAROLE BMNY BZ TL

TOLL COMPOUNDING

Compound highly filled with Bronze

beads

On various engineering plastics

UV ABSORBER

HALS

Absorb UV light for polymer protection or UV

screening

Provide very efficient light and heat protection for plastics and
coatings

ADK STAB LA-31RG

ADK STAB LA-46

ADK STAB LA-53

ADK STAB LA-63

Extremely low volatility and

especially suited for engineering
plastics

Triazine type of UV absorber with

excellent thermostability

Methylated HALS

High molecular weight light stabiliser

specially for use in thin section products

ADK STAB LA-62

ADK STAB LA-81

Liquid, also for coatings

New NOR-HALS

Benzophenones
PALMAROLE LS.BO.013

PALMAROLE LS.BO.087

Benzotriazoles

ADK STAB LA-502 and LA-402 XP

PALMAROLE LS.BT.080

PALMAROLE LS.BT.141

PALMAROLE LS.BT.100

PALMAROLE LS.BT.550

Particularly for filled and/or pigmented PP with low extractability, no

discoloration and excellent light stability HALS

PALMAROLE HALS 77

Weatherability of LDPE film

after sulfor fumigation

Formulation
LDPE(100) / ADK STAB AO-60(0,05) / ADK STAB 2112(0,05)
Process
Extrusion at 200C, Press at 180C to 80m thick film
Weathering test
Sunshine weather meter at 63C, water spray

PALMAROLE HALS 94

STABILIZERS AND PLASTICIZER FOR PVC

For flexible PVC applications

ADK STAB RUP-100 series: Ca Mg Zn stabilizers

for wire & cable PVC applications
Excellent electrical, colour holding and thermal ageing
used in automotive, building wire, power cable applications
for example

70C to 105C service temperature: ADK STAB RUP 185 E/ RUP

110ET / RUP 112
above 105C (automotive class III); ADK STAB RUP 190 / ADK STAB
RUP 167 ET

ADK STAB AC-series:

Nonyl phenol-free Ba Zn stabilizers, to be used with co-stabilizers
for calandering PVC application
Excellent transparency, heat stability and colour holding
Used in flexible and semi-rigid films and sheets:
Furniture and decorative applications, stationery films, roofing membranes, pond liners, swimming
pools, civil engineering liners, adhesive & marking films etc.

ADK STAB SC-series, SP-series:

Liquid & solid Ca Zn stabilizers, to be used with co-stabilizers
for other flexible S-PVC applications
for example
ADK STAB SP-96 used for food-contact pipe, hoses ad sheet

Custom-made stabilizer: Lead-free formulations

for special PVC based automotive applications and Plastisol / E-PVC
Customized recipes according to specifications and processing methods taking into account low VOC
requirements, special ageing and demoulding requirements

STABILIZERS AND PLASTICIZER FOR PVC

For rigid PVC applications
ADK STAB RX-200 series
for rigid PVC extrusion applications

Suitable for

Description

Dosage

Window profiles

Ca/Mg/Zn

Thin coloured outdoor profiles (rain gutter)

Core stabilizers

Inddor or highly filled applications: cladding,

edge bands, cable ducts etc

Or
One-packs

2,5 6 PHR

Wood Profile Composite (WPC)

(corestabilizers+customized
processing package)

Foamed applications

ADK STAB RX-300 series

fort rigid PVC injection applications

Suitable for

Description

Dosage

Sewer fittings

Ca/Mg/Zn

Pressure fittings

Core stabilizers

Outdoor (gutter fittings)

Or

2,5 6 PHR

Air coolers

One-packs

Other moulded accessories

(corestabilizers+customized
processing package*)

ADK STAB RX-500 series

Internal / external lubricants for ADK STAB RX-series

Description
Lubricants
Based on balanced eszter,
PE, OPE
and specific types

Suitable for

Dosage

All PVC rigid formulations including following

ingredients
0,5 2 PHR
Core stabilizers (ADK STAB RX-200 & RX-300
series
Polymer processing aid, plus pigments &
fillers

(*) customized processing packaging = lubricants plus polymer processing aid

ADEKA PALMAROLE ADDITIVES & CO-STABILIZERS FOR PVC

Blowing agents for rigid PVC
Foamed PVC pipes 3 layers
Palmarole EXP 141/95

specially for lead systems

micro granules also available for CaZn and Tin stabilizers

Foamed rigid PVC sheets and boards

Palmarole MB.BA.10

micro granules-endo/exo combination

Palmarole BA.HX.01

powder combination of endo/exo

Palmarole EXP 141/58

powder combination of endo/exo

Co-stabilizers & light stabilizers

ADK STAB AO-50, ADK STAB AO-60 hindered phenolic antioxidants
ADK STAB PEP-8HT/ 135-A / TPP / HP-10 etc. liquid / solid phospites
Palmarole S.SBM, Palmarole S.PBM etc. Beta diketone derivates
Palmarole LS.BO series generic Benzophenone UV absorbers
Palmarole LS.BT series generic Benzotriazole UV absorbers
ADK STAB LA-series HALS (secondary, tertiary), NOR-HALS and Triazine

Other Process & end-use additives

ADK STAB ATC-1
ADK STAB ATC-7R
ADK STAB NPO-3 E

proprietary co-additives

Anti-Chalking Effect
anti plate out

PLASTICIZERS PRODUCT RANGE

Product type

Description

Application

Trimilitates
ADK CIZER C-8 (TOTM)

C-8 (2-Ethylhexyl)

ADK CIZER C-8 L

Linear C-8

ADK CIZER C-810 L

Linear C8- C10

ADK CIZER C-79 E

Linear C7-9

ADK CIZER C-79EA

Linear C7-9

Wire & Cable, Automotive

Polymeric
ADK CIZER PN-series

Polyadipates

ADK CIZER PX-series

Polyadipates

ADK CIZER RS-series

Polymeric

Rubber

Experimental PX-943

proprietary

Automotive

Experimental PX-957

proprietary

Automotive

ADK CIZER LV-70

proprietary

Anti-static

ADL CIZER LV-838

proprietary

Anti static

Film, general purpose

Others

Contact:

Ing. Mag.(FH) Martin BERMANN

Area Sales Manager
Austria & Eastern Europe

ADEKA PALMAROLE

103, rue de Strasbourg

FR - 68300 SAINT-LOUIS, France
-------------------------------------------------Mobile: ++ 43 664 413 40 72
Home Office Phone: ++43 2252 251 481
Home Office Fax: ++43 2252 251 481
Mail: mbermann@adeka-palmarole.com
Web: www.adeka-palmarole.com