Professional Documents
Culture Documents
Speaker: Yi-Chang Wu ()
d98524013@ntu.edu.tw
PSE Laboratory
Department of Chemical Engineering
Nation Taiwan University
Extractive Distillation
D2
XIPA=0.999
NFE
NT = 24
Extractive
distillation column NF2 = 9
NT = 41
NFE = 7
NFF = 35
F2
IPA-water feed (FF)
D2
XWater=0.999
Entrainer
recovery column
NF2
NFF
P = 3 atm
T = 25oC
F = 100 kmol/hr
X IPA =0.5
X WATER =0.5
B2
Entrainer recycle
Entrainer makeup
Ref: http://www.aspentech.com/products/aspen-plus.cfm
More Detailed
Properties analysis
Properties of pure component and mixtures (Enthalpy,
density, viscosity, heat capacity,etc)
Phase equilibrium (VLE, VLLE, azeotrope calculationetc)
Parameters estimation for properties models (UNIFAC
method for binary parameters, Joback method for boiling
pointsetc)
Data regression from experimental deta
Process simulation
pump, compressor, valve, tank, heat exchanger, CSTR, PFR,
distillation column, extraction column, absorber, filter,
crystallizeretc
5
Lesson Objectives
Familiar with the interface of Aspen Plus
Learn how to use properties analysis
Learn how to setup a basic process simulation
3
Mixer
Pump
10
0
0
10
50
1
?
?
?
0
9
6
15
80
1
?
?
?
?
?
?
?
?
1
?
?
?
?
?
?
?
?
10
?
?
?
Mass Balance
Energy Balance
Enthalpy
Entropy
Problem Formulation 2:
Flash Separation
120
T-x
T-y
Saturated Feed
P=1atm
F=100 kmol/hr
zwater=0.5
zHAc=0.5
T=105 C
P=1atm
T ( C)
115
110
105
100
0.0
0.2
0.4
0.6
0.8
1.0
1.0
Water
Acetic Acid
Saturated Feed
P=1.2atm
F=100 kmol/hr
zwater=0.5
zHAc=0.5
Reflux
ratio ?
Water
xwater=0.99
0.6
20
40
0.4
0.2
Duty ?
39
0.8
yWater
xHAc=0.99
Acetic Acid
0.0
0.0
0.2
0.4
0.6
xWater
0.8
1.0
Outline
Startup in Aspen Plus (Basic Input) (45 min)
User Interface
Basic Input: Setup, Components, Properties.
Properties Analysis (1 hour)
Pure Component
Mixtures (phase equilibrium)
Running Simulation (1 hour)
Blocks (Unit Operations)
Streams (flow streams)
Results
11
12
14
Help
Setup
Components
Properties
Streams
Blocks
Data Browser
Next
Check Result
Stop
Reinitialize
Step
Start
Control Panel
ProcessFlowsheet
Flowsheet Windows
Process
Windows
ModelLibrary
Library (View|
Model
(View| Model
ModelLibrary
Library) )
Stream
Status message
15
More Information
16
Data Browser
The Data Browser is a sheet and form viewer with a
hierarchical tree view of the available simulation
input, results, and objects that have been defined
17
Basic Input
The minimum required inputs to run a simulation
are:
Setup
Components
Properties
Streams
Blocks
Property Analysis
Process Simulation
18
Setup Specification
Run Type
Input mode
19
Components Specification
Input components
with Component name or Formula
20
Input components
21
Specification
To do this
Find components in the databanks
User Defined
Elec Wizard
Reorder
Review
22
Find Components
Click Find
23
24
Properties
Process type(narrow the number of
methods available)
25
26
Assistant Wizard
27
Yes
Yes
WILSON
NRTL
UNIQAC
etc.
UNIF-LL
UNIFAC
UNIF-LBY
UNIF-DMD
Liq-Liq
ELECNRTL
No
Yes
Yes
Yes
NRTL
UNIQAC
etc.
Interaction
Parameters
Available?
Liq-Liq
No
No
No
Yes
Electrolyte
Yes
Interaction
Parameters
Available?
No
Property Method
Choice
SR-POLAR
PRWS
RKSWS
PRMHV2
RKSMHV2
Polar or
T < Tci
Yes
No
PENG-ROB
PR-BM
LK-PLOCK
RK-SOAVE
RKS-BM
No
WILS-NTH, WILS-HOC,
NRTL-NTH, NRTL-HOC,
UNIQ-NTJ, UNIQ-HOC,
Dimers
UNIF-HOC
PSRK
RKSMHV2
Degree of
Polymerization
No Pseudo
Components
Yes
CHAO-SEA
GRAYSON
BK10
Yes
Hexamers
No
High Pressure?
No
WILS-HF
Vapor-phase
Association?
BK10
IDEAL
No
Reference: http://www.et.byu.edu/groups/uolab/files/aspentech/
28
NRTL
29
30
31
Pure Component
Temperature-Dependent Properties
CPIGDP-1
CPSDIP-1
DNLDIP-1
Liquid density
DHVLDP-1
Heat of vaporization
PLXANT-1
MULDIP
Liquid viscosity
KLDIP
SIGDIP
UFGRP
Example: PLXANT-1
(Extended Antoine Equation)
Corresponding Model
Click ? and then click where you dont know
34
Example: CPIGDP-1
(Ideal Gas Heat Capacity Equation)
Corresponding Model
35
Summary
36
File Type
Extension
Format
Description
Document
*.apw
Binary
Backup
*.bkp
ASCII
History
*.his
Text
Problem
Description
*.appdf
Binary
To generate
Binary
Residue
Pure
Ternary
Azeotrope
Ternary maps showing phase envelope, tie lines, and azeotropes of ternary
systems
This feature locates all the azeotropes that exist among a specified set of
components.
39
Reminding
When you start properties analysis, you MUST
specify components , properties model, and
corresponding model parameters. (Refer to
Part I)
40
To generate
Binary
Residue
Pure
Ternary
Azeotrope
Ternary maps showing phase envelope, tie lines, and azeotropes of ternary
systems
This feature locates all the azeotropes that exist among a specified set of
components.
41
42
Available Properties
Property (thermodynamic)
Property (transport)
Availability
Free energy
Constant pressure
Enthalpy
heat capacity
Heat capacity ratio
Fugacity coefficient
Constant volume heat Fugacity coefficient
capacity
pressure correction
Free energy departure
Vapor pressure
Free energy departure
Density
pressure correction
Enthalpy departure
Entropy
Enthalpy departure
Volume
pressure correction
Enthalpy of
Sonic velocity
vaporization
Entropy departure
Thermal conductivity
Surface tension
Viscosity
43
3. Select component
Data results
45
Example2: H (Enthalpy)
3. Select component
6. Select property method
46
Data results
47
To generate
Binary
Residue
Pure
Ternary
Azeotrope
Ternary maps showing phase envelope, tie lines, and azeotropes of ternary
systems
This feature locates all the azeotropes that exist among a specified set of
components.
48
Example: T-XY
1. Select analysis type (Txy)
5. Specify pressure
Data results
To generate
Binary
Residue
Pure
Ternary
Azeotrope
Ternary maps showing phase envelope, tie lines, and azeotropes of ternary
systems
This feature locates all the azeotropes that exist among a specified set of
components.
55
Ternary Map
5. Specify pressure
6. Specify temperature
(if LLE is slected)
Data results
Property Analysis
Conceptual
Design
(Optional)
Use this form
To generate
Binary
Residue
Pure
Ternary
Azeotrope
Ternary maps showing phase envelope, tie lines, and azeotropes of ternary
systems
This feature locates all the azeotropes that exist among a specified set of
components.
59
Conceptual Design
Azeotrope Analysis
Azeotrope Analysis
1. Select components (at least two)
2. Specify pressure
Error Message
Ternary Maps
Ternary Maps
3. Select property method
1. Select three components
2. Specify pressure
Ternary Maps
Change pressure or
temperature
3
Mixer
Pump
1
10
0
0
10
50
1
?
?
?
0
9
6
15
80
1
?
?
?
?
?
?
?
?
1
?
?
?
?
?
?
?
?
10
?
?
?
69
Setup Specification
Select Flowsheet
70
71
Adding a Mixer
72
73
74
Red arrow(Right):
Blue arrow: Water
Product (Required; if
decant for Free water
mixing material streams) of dirty water.
75
76
77
B1
78
79
81
82
Run Simulation
Click to run the simulation
Run
Step
Stop
Reinitialize
Means
The run has completed normally, and results are
present.
Input Changed
85
Stream Results
86
Substream: MIXED
Mole Flow kmol/hr
WATER
BUOH
BUAC
Total Flow kmol/hr
Total Flow kg/hr
Total Flow cum/hr
Temperature C
Pressure bar
Vapor Frac
Liquid Frac
Solid Frac
Enthalpy kcal/mol
Enthalpy kcal/kg
Enthalpy Gcal/hr
Entropy cal/mol-K
Entropy cal/gm-K
Density kmol/cum
Density kg/cum
Average MW
Liq Vol 60F cum/hr
10
0
0
10
180.1528
0.18582
50
2
0
1
0
-67.81
-3764.03
-0.6781
-37.5007
-2.0816
53.81564
969.5038
18.01528
0.1805
0
9
6
15
1364.066
1.74021
80
1
0
1
0
-94.3726
-1037.77
-1.41559
-134.947
-1.48395
8.619647
783.851
90.93771
1.617386
10
9
6
25
1544.218
1.870509
70.08758
1
0
1
0
-83.7476
-1355.82
-2.09369
-95.6176
-1.54799
13.36534
825.5604
61.76874
1.797886
87
88
89
90
91
92
93
Connect Streams
94
Pump Specification
1. Select Pump or turbine
3. Efficiencies (Default: 1)
95
Run Simulation
Click to generate the results
97
98
Streams Results
99
Calculation Results
(Mass and Energy Balances)
1
2
3
Mixer
Pump
1
4
10
9
6
25
71.20
10
-83.69
-95.46
824.29
100
Exercise
1
2
3
4
Mixer
5
Pump
10
0
0
10
50
1
?
?
?
0
5
0
15
70
1
?
?
?
0
0
15
15
40
1
?
?
?
?
?
?
?
?
1
?
?
?
?
?
?
?
?
4
?
?
?
?
?
?
?
?
2
?
?
?
101
Saturated Feed
P=1atm
F=100 kmol/hr
zwater=0.5
zHAc=0.5
T=105 C
P=1atm
T ( C)
115
110
105
100
0.0
0.2
0.4
0.6
0.8
1.0
Input Components
Binary Analysis
T-xy plot
1. Select analysis type (Txy)
5. Specify pressure
Data results
Generate xy plot
Flash Separation
120
T-x
T-y
Saturated Feed
P=1atm
F=100 kmol/hr
zwater=0.5
zHAc=0.5
T=105 C
P=1atm
T ( C)
115
110
105
100
0.0
0.2
0.4
0.6
0.8
1.0
Saturated Feed
(Vapor fraction=0)
P=1atm
F=100 kmol/hr
zwater=0.5
zHAc=0.5
Flash2: Specification
T=105 C
P=1atm
Stream Results
Saturated Feed
P=1atm
F=100 kmol/hr
zwater=0.5
zHAc=0.5
T=105 C
P=1atm
57.342 kmol/hr
zwater=0.432
zHAc=0.568
Distillation Separation
1
2
RR ?
xwater=0.99
20
Saturated Feed
P=1.2atm
F=100 kmol/hr
zwater=0.5
zHAc=0.5
39
QR ?
40
xHAc=0.99
Saturated Feed
(Vapor fraction=0)
P=1.2atm
F=100 kmol/hr
zwater=0.5
zHAc=0.5
Radfrac: Configuration
1
2
xwater=0.99
20
Saturated Feed
P=1.2atm
F=100 kmol/hr
zwater=0.5
zHAc=0.5
39
40
xHAc=0.99
1
2
xwater=0.99
20
Saturated Feed
P=1.2atm
F=100 kmol/hr
zwater=0.5
zHAc=0.5
39
40
xHAc=0.99
Run Simulation
Click to run simulation
Stream Results
Again
Smarter Way
Very: Specifications
Run Simulation
Click to run simulation
Summary of Condenser
Summary of Reboiler
Plot Wizard
Plot Types
Composition Profiles
Temperature Profiles
Examples:
1.IPA-Water-DMSO
Isopropyl Alcohol
Water
Dimethyl Sulfoxide
COMPONENTS SPECIFICATION
Input components
with Component name or Formula
Click Find
167
RENAME COMPONENTS ID
Isopropyl Alcohol
Water
Dimethyl Sulfoxide
168
NRTL
169
170
171
IPA
IPA
H2 O
Comp,j
H2 O
DMSO
DMSO
aij
-1.2449
aji
1.7524
bij
185.4
115.2787
586.801
bji
777.3
-25.0123
-1130.215
cij
0.50
0.3
0.30
172
Ternary Maps
Ternary Maps
1. Select three components
3. Select property method
4. Select phase (VLE,
LLE)
5. Select report Unit
2. Specify pressure
Ternary Maps
Change pressure
DMSO
4.0
3.5
3.0
2.5
2.0
1.5
1.0
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Entrainer feed
when
1
Azeotrope feed
yIPA / xIPA 0.861/ 0.346
3.23
yH 2O / xH 2O 0.118 / 0.153
(A-F)/(E-F)
10
2.5
0.25
1.8
10
0.5
2.43
10
7.5
0.75
2.9
10
10
3.23
10
12.5
1.25
3.5
10
15
1.5
3.7
10
17.5
1.75
3.86
10
20
3.98
10
22.5
2.25
4.08
10
25
2.5
4.16
10
27.5
2.75
4.22
10
30
4.28
4.5
DMSO
A-F
(kmol/h)
4.0
3.5
3.0
2.5
2.0
1.5
1.0
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Extractive Distillation
D2
XIPA=0.999
NFE
NT = 24
Extractive
distillation column NF2 = 9
NT = 41
NFE = 7
NFF = 35
F2
IPA-water feed (FF)
D2
XWater=0.999
Entrainer
recovery column
NF2
NFF
P = 3 atm
T = 25oC
F = 100 kmol/hr
X IPA =0.5
X WATER =0.5
B2
Entrainer recycle
Entrainer makeup
SETUP SPECIFICATION
Run Type
Input mode
188
Add Units-Sets
Add Units-Sets
REPORT OPTIONS
COMPONENTS SPECIFICATION
Input components
with Component name or Formula
Click Find
192
RENAME COMPONENTS ID
193
NRTL
194
195
196
IPA
IPA
H2 O
Comp,j
H2 O
DMSO
DMSO
aij
-1.2449
aji
1.7524
bij
185.4
115.2787
586.801
bji
777.3
-25.0123
-1130.215
cij
0.50
0.3
0.30
197
RENAME STREAM
Feed
(Saturated Liquid Feed)
Vapor fraction = 0
P = 2 atm
F = 100 kmol/hr
z IPA =0.5
z WATER =0.5
EF
P = 2 atm
T = 184.5 oC
F = 100 kmol/hr
z DMSO =1
MAKEUP
P = 2 atm
T = 25 oC
F = 0 kmol/hr
z DMSO =1
BLOCK INPUT
BLOCK INPUT
BLOCK INPUT
RUN SIMULATION
Click to run simulation
Check result
DESIGN SPECS/VARY
VERY: SPECIFICATIONS
RUN SIMULATION
DESIGN SPECS/VARY
VERY: SPECIFICATIONS
RUN SIMULATION
D1
D2
RECYCLE STREAM
RECYCLE STREAM
RECYCLE STREAM
TEAR
SUMMARY OF REBOILER
B1
B2
TRAY SIZING
237
TRAY SIZING
238
TRAY SIZING
239
TRAY RATING
240
TRAY RATING
241
242