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f = fiber
m = matrix
Remembering: E = s/e and
note, this model
corresponds to the upper
bound for particulate
composites
Composite Strength: Transverse Loading
In transverse loading the fibers carry less of
the load and are in a state of isostress
s
c
= s
m
= s
f
= s e
c
= e
m
V
m
+ e
f
V
f
f
f
m
m
ct
E
V
E
V
E
1
transverse modulus
Remembering: E = s/e
and note, this model
corresponds to the lower
bound for particulate
composites
Estimate of Ec and TS for discontinuous fibers:
-- valid when
-- Elastic modulus in fiber direction:
-- TS in fiber direction:
efficiency factor:
-- aligned 1D: K = 1 (aligned )
-- aligned 1D: K = 0 (aligned )
-- random 2D: K = 3/8 (2D isotropy)
-- random 3D: K = 1/5 (3D isotropy)
(aligned 1D)
Values from Table 16.3, Callister 7e. (Source for
Table 16.3 is H. Krenchel, Fibre Reinforcement,
Copenhagen: Akademisk Forlag, 1964.)
Composite Strength
c
f
d
t
s
15 length fiber
Particle-reinforced Fiber-reinforced Structural
(TS)
c
= (TS)
m
V
m
+ (TS)
f
V
f
E
c
= E
m
V
m
+ KE
f
V
f
Aligned Continuous fibers
Examples:
From W. Funk and E. Blank, Creep deformation of
Ni3Al-Mo in-situ composites", Metall. Trans. A Vol.
19(4), pp. 987-998, 1988. Used with permission.
-- Metal: g'(Ni
3
Al)-a(Mo)
by eutectic solidification.
Composite Survey: Fiber
Particle-reinforced Fiber-reinforced Structural
matrix: a (Mo) (ductile)
fibers: g (Ni
3
Al) (brittle)
2 mm
-- Ceramic: Glass w/SiC fibers
formed by glass slurry
E
glass
= 76 GPa; E
SiC
= 400 GPa.
(a)
(b)
fracture
surface
From F.L. Matthews and R.L. Rawlings,
Composite Materials; Engineering and
Science, Reprint ed., CRC Press, Boca
Raton, FL, 2000. (a) Fig. 4.22, p. 145 (photo
by J. Davies); (b) Fig. 11.20, p. 349
(micrograph by H.S. Kim, P.S. Rodgers, and
R.D. Rawlings). Used with permission of
CRC
Press, Boca Raton, FL.
Discontinuous, random 2D fibers
Example: Carbon-Carbon
-- process: fiber/pitch, then
burn out at up to 2500C.
-- uses: disk brakes, gas
turbine exhaust flaps, nose
cones.
Other variations:
-- Discontinuous, random 3D
-- Discontinuous, 1D
Composite Survey: Fiber
Particle-reinforced Fiber-reinforced Structural
(b)
fibers lie
in plane
view onto plane
C fibers:
very stiff
very strong
C matrix:
less stiff
less strong
(a)
efficiency factor:
-- random 2D: K = 3/8 (2D isotropy)
-- random 3D: K = 1/5 (3D isotropy)
E
c
= E
m
V
m
+ KE
f
V
f
Stacked and bonded fiber-reinforced sheets
-- stacking sequence: e.g., 0/90 or 0/45/90
-- benefit: balanced, in-plane stiffness
Adapted from Fig. 16.16,
Callister 7e.
Composite Survey: Structural
Particle-reinforced Fiber-reinforced Structural
Sandwich panels
-- low density, honeycomb core
-- benefit: light weight, large bending stiffness
honeycomb
adhesive layer
face sheet
Adapted from Fig. 16.18,
Callister 7e. (Fig. 16.18 is
from Engineered Materials
Handbook, Vol. 1, Composites, ASM International, Materials Park, OH, 1987.)
Composite Manufacturing Processes
Particulate Methods: Sintering
Fiber reinforced: Several
Structural: Usually Hand lay-up and
atmospheric curing or vacuum
curing
2000 The McGraw-Hill Companies, Inc., Irwin/McGraw-Hill
Open Mold Processes
Only one mold (male or female) is needed and may be made of any material such as wood,
reinforced plastic or , for longer runs, sheet metal or electroformed nickel. The final part is
usually very smooth.
Shaping. Steps that may be taken for high quality
1. Mold release agent (silicone, polyvinyl alcohol, fluorocarbon, or sometimes, plastic
film) is first applied.
2. Unreinforced surface layer (gel coat) may be deposited for best surface quality.
Hand Lay-Up: The resin and fiber (or pieces cut from prepreg)
are placed manually, air is expelled with squeegees and if
necessary, multiple layers are built up.
Hardening is at room temperature but may be improved by heating.
Void volume is typically 1%.
Foam cores may be incorporated (and left in the part) for greater shape
complexity. Thus essentially all shapes can be produced.
Process is slow (deposition rate around 1 kg/h) and labor-intensive
Quality is highly dependent on operator skill.
Extensively used for products such as airframe components, boats, truck bodies,
tanks, swimming pools, and ducts.
A spray gun supplying resin in two converging streams into which roving is
chopped
Automation with robots results in highly reproducible production
Labor costs are lower
SPRAY-UP MOLDING
Cut and lay the ply or prepreg under computer control and without tension; may allow
reentrant shapes to be made.
Cost is about half of hand lay-up
Extensively used for products such as airframe components, boats, truck bodies,
tanks, swimming pools, and ducts.
Tape-Laying Machines
(Automated Lay-Up)
Filament Winding
Ex: pressure tanks
Continuous filaments wound onto mandrel
Adapted from Fig. 16.15, Callister 7e. [Fig. 16.15 is
from N. L. Hancox, (Editor), Fibre Composite Hybrid
Materials, The Macmillan Company, New York,
1981.]
Filament Winding Characteristics
Because of the tension, reentrant shapes cannot be produced.
CNC winding machines with several degrees of freedom (sometimes 7) are
frequently employed.
The filament (or tape, tow, or band) is either precoated with the polymer or is drawn
through a polymer bath so that it picks up polymer on its way to the winder.
Void volume can be higher (3%)
The cost is about half that of tape laying
Productivity is high (50 kg/h).
Applications include: fabrication of composite pipes, tanks, and pressure vessels.
Carbon fiber reinforced rocket motor cases used for Space Shuttle and other
rockets are made this way.
Pultrusion
Fibers are impregnate with a prepolymer, exactly positioned with guides, preheated, and
pulled through a heated, tapering die where curing takes place.
Emerging product is cooled and pulled by oscillating clamps
Small diameter products are wound up
Two dimensional shapes including solid rods, profiles, or hollow tubes, similar to
those produced by extrusion, are made, hence its name pultrusion
Composite Production Methods
Pultrusion
Continuous fibers pulled through resin tank, then preforming die
& oven to cure
Adapted from Fig. 16.13,
Callister 7e.
Production rates around 1 m/min.
Applications are to sporting goods (golf club shafts), vehicle drive shafts (because of the
high damping capacity), nonconductive ladder rails for electrical service, and structural
members for vehicle and aerospace applications.
PREPREG PRODUCTION PROCESSES
Prepreg is the composite industrys term for continuous fiber
reinforcement pre-impregnated with a polymer resin that is only partially
cured.
Prepreg is delivered in tape form to the manufacturer who then molds
and fully cures the product without having to add any resin.
This is the composite form most widely used for structural applications
Manufacturing begins by collimating a series of spool-wound continuous
fiber tows.
Tows are then sandwiched and pressed between sheets of release and
carrier paper using heated rollers (calendering).
The release paper sheet has been coated with a thin film of heated resin
solution to provide for its thorough impregnation of the fibers.
PrePreg Process
The final prepreg product is a thin tape consisting of continuous
and aligned fibers embedded in a partially cured resin
Prepared for packaging by winding onto a cardboard core.
Typical tape thicknesses range between 0.08 and 0.25 mm
Tape widths range between 25 and 1525 mm.
Resin content lies between about 35 and 45 vol%
PrePreg Process
The prepreg is stored at 0C (32 F) or lower because thermoset matrix undergoes
curing reactions at room temperature. Also the time in use at room temperature must be
minimized. Life time is about 6 months if properly handled.
Both thermoplastic and thermosetting resins are utilized: carbon, glass, and aramid
fibers are the common reinforcements.
Actual fabrication begins with the lay-up. Normally a number of plies are laid up to
provide the desired thickness.
The lay-up can be by hand or automated.
PrePreg Process
Composites are classified according to:
-- the matrix material (CMC, MMC, PMC)
-- the reinforcement geometry (particles, fibers, layers).
Composites enhance matrix properties:
-- MMC: enhance s
y
, TS, creep performance
-- CMC: enhance K
c
-- PMC: enhance E, s
y
, TS, creep performance
Particulate-reinforced:
-- Elastic modulus can be estimated.
-- Properties are isotropic.
Fiber-reinforced:
-- Elastic modulus and TS can be estimated along fiber dir.
-- Properties can be isotropic or anisotropic.
Structural:
-- Based on build-up of sandwiches in layered form.
Summary
Microelectromechanical Systems
(MEMS)
An introduction
What are MEMS?
(Micro-electromechanical Systems)
Fabricated using micromachining technology
Used for sensing, actuation or passive micro-structures
Usually integrated with electronic circuitry for control
and/or information processing
3-D Micromachined Structures
Linear Rack Gear Reduction Drive
Triple-Piston Microsteam Engine
Photos from Sandia National Lab. Website: http://mems.sandia.gov
3-D Micromachined Structures
Movies from Sandia National Lab. Website: http://mems.sandia.gov
2 dust mites on an optical
shutter
Deflection of laser light using
a hinged mirror
Applications: Sensors
Pressure sensor:
Piezoresistive sensing
Capacitive sensing
Resonant sensing
Application examples:
Manifold absolute pressure (MAP) sensor
Disposable blood pressure sensor
(Novasensor)
Piezoresistive Pressure Sensors
Pressure
Piezoresistive elements
SiO
2
p
+
Si
<100> Si
substrate
Applications: Sensors
Acceleration
Air bag crash sensing
Seat belt tension
Automobile suspension control
Human activity for pacemaker control
Vibration
Engine management
Security devices
Monitoring of seismic activity
Angle of inclination
Vehicle stability and roll
Inertial sensors
Accelerometers
M
Inertial mass
F=Ma
Spring
F=kx
Damping
F=Dv
Static deformation:
k
Ma
k
F
d
static
Dynamic behavior
Ma F kx
dt
dx
D
dt
x d
M
ext
2
2
M
k
r
D
M
Q
r
Resonance frequency
Quality factor
Capacitive Accelerometers
Stationary Polysilicon fingers
Based on ADXL accelerometers, Analog Devices, Inc.
Spring
Inertial Mass
Anchor to
substrate
Displacement
Applications: Actuators
Texas Instruments Digital Micromirror Device
TM
Array of up to 1.3 million mirrors
Invented by Texas Instruments in 1986
For an animated demo of this device, go to http://www.dlp.com/dlp_technology/
Each mirror is 16 mm on a side with a pitch of 17 mm
Resolutions: 800x600 pixels (SVGA) and 1280x1024 pixels (SXGA)
Some future applications
Biological applications:
Microfluidics
Lab-on-a-Chip
Micropumps
Resonant microbalances
Micro Total Analysis systems
Mobile communications:
Micromechanical resonator for resonant circuits and filters
Optical communications:
Optical switching
Microfluidics / DNA Analysis
In the future, a complete DNA sequencing systems should include:
Amplification (PCR)
Detection (electrophoresis)
Fluid preparation and handling (pumps, valves, filters, mixing and rinsing)
MEMS !
Basic microfabrication technologies
Deposition
Chemical vapor deposition (CVD/PECVD/LPCVD)
Epitaxy
Oxidation
Evaporation
Sputtering
Spin-on methods
Etching
Wet chemical etching
Istropic
Anisotropic
Dry etching
Plasma etch
Reactive Ion etch (RIE, DRIE)
Patterning
Photolithography
X-ray lithography
Summary: MEMS fabrication
MEMS technology is based on silicon
microelectronics technology
Main MEMS techniques
Bulk micromachining
Surface micromachining
LIGA and variations
Wafer bonding
MEMS Resources
Reference Books
Nadim Maluf, An Introduction to Microelectromechanical
Engineering (Artech House, Boston,2000)
M. Elewenspoek and R. Wiegerink, Mechanical Microsensors
(Springer-Verlag, 2001)
Hctor J. De Los Santos, Introduction to
Microelectromechanical (MEM) Microwave Systems (Artech
House, Boston, 1999)
Websites
Sandia National Lab: http://mems.sandia.gov
Berkeley Sensors and Actuators Center: http://www-
bsac.eecs.berkeley.edu
MEMS Clearinghouse: http://www.memsnet.org/
Some companies with MEMS products
Accelerometers Analog Devices:
http://www.analog.com/technology/mems/index.html
Digital Light Processing Projector- Texas Instruments:
http://www.dlp.com
Micro-electrophoresis chip Caliper Technologies:
http://www.calipertech.com
Plastics History
General properties: more durable, harder, tough, light.
Typical uses: automobile parts, construction materials.
Plastic types: Thermosets
Examples:
Unsaturated Polyesters: lacquers, varnishes, boat hulls, furniture
Epoxies and Resins: glues, coating of electrical circuits,
composites: fiberglass in helicopter blades, boats,
Plastic types: Elastomers
General properties: these are thermosets, and have rubber-like properties.
Typical uses: medical masks, gloves, rubber-substitutes
Examples:
Polyurethanes: mattress, cushion, insulation, toys
Silicones: surgical gloves, oxygen masks in medical applications
joint seals
General properties: low melting point, softer, flexible.
Typical uses: bottles, food wrappers, toys,
Examples:
Polyethylene: packaging, electrical insulation, milk and water bottles, packaging film
Polypropylene: carpet fibers, automotive bumpers, microwave containers, prosthetics
Polyvinyl chloride (PVC): electrical cables cover, credit cards, car instrument panels
Polystyrene: disposable spoons, forks, Styrofoam
Acrylics (PMMA: polymethyl methacrylate): paints, fake fur, plexiglass
Polyamide (nylon): textiles and fabrics, gears, bushing and washers, bearings
PET (polyethylene terephthalate): bottles for acidic foods like juices, food trays
PTFE (polytetrafluoroethylene): non-stick coating, Gore-Tex (raincoats), dental floss
Plastic types: Thermoplastics
Plastics Processing: Extrusion
Injection
Parts of the injection screw
Screw
Head and check ring
Plastics Processing: Injection Molding
- Probably the most common, most important, most economical process
Plastics Processing: Blow molding
heated glass
3-piece mold
(a) The hollow piece of heated glass (parison)
is first created by a blow mold
(see text-book Fig 17.25)
(b) The mold is put together
(c) Plunger and hot air push the
glass up
(d) Hot air blows the glass out towards
the mold surface
(e) Mold comes apart, bottle is removed
heated glass
3-piece mold
(a) The hollow piece of heated glass (parison)
is first created by a blow mold
(see text-book Fig 17.25)
(b) The mold is put together
(c) Plunger and hot air push the
glass up
(d) Hot air blows the glass out towards
the mold surface
(e) Mold comes apart, bottle is removed
- similar to glass blow-molding -
Plastics Processing: Thermoforming
Sheet of plastic Heated (soft) Molded using a shaped die
Vacuum thermoforming
Plastics Processing: Compression and Transfer Molding
used mostly for thermosetting polymers
mold is heated and closed using pressure
plastic flows to fills the cavity
flash must be trimmed by finishing
dishes, handles for cooking pots
skis, housing for high-voltage switches
some rubber parts like shoe soles
and even composites such as fiber-reinforced parts
Plastics Processing: Injection Molding
- Probably the most common, most important, most economical process
Plastics Processing: Injection Molding
Cycle of operation for injection molding
Injection Molding: geometry of the mold
Basic components:
mold pieces (define the geometry of the part), AND
sprue, gates, runners, vents, ejection pins, cooling system
Blow Molding
Introduction
Plastic formation process-manufacture of bottles
and hollow-shaped parts
Competitive with other processes, injection molding
Advantages; cycle is very short (low cost), lower
mold cost than injection molding, high production
rates in producing hollow parts with small or large
opening
Blow molding process; general
steps
Melting the resin- done in extruder
Form the molten resin into a cylinder or tube (this
tube is called parison)
The parison is placed inside a mold, and inflated so
that the plastic is pushed outward against the cavity
wall
The part is allowed to cool in the mold and is then
ejected
The part is trimmed
Parison
Blowing step in the blow molding
process
Blow Molding Process
The parison can be formed by
Extrusion process
Injection molding process
Extrusion blow molding
Parison is formed from by forcing the plastic through
an extrusion die.
Material enters the die, flow around the mandrel so
that extrudate would be cylindrical
The die would have a hole at the center so that air
could be blown into the cylinder
In some blow molding operations, the air is introduced
from the bottom through an inlet
Thermoforming Process
Thermoforming
Process used to shape thermoplastic sheet into
discrete parts
Basic principles
Heat a thermoplastic sheet until it softens
Force the hot and pliable material against the
contours of a mold by using either mechanical, air or
vacuum pressure
Held against mold and allow to cool, and plastics
retains its shape
Thermoforming process is differed from other
plastic processing because the material is not
melted, lower pressures are required to
thermoform (the mold materials is less sturdy
materials compared to other processings)
Disadvantage; generates greater amount of
scrap, cost of the sheet materials is raised
(because of separate sheet-forming step),
limited design parts (parts with sharp bends and
corners are difficult to be produced), process
results in internal stresses
Summary of advantages &
disadvantages of thermoforming process
Forming Process
The techniques of forming process can be grouped
into several types;
Fundamental Vacuum forming
Pressure forming
Plug-assist forming
Reverse draw forming
Free forming
Matched-die forming, etc
The term Fundamental is used to emphasize that
this is the simplest method of vacuum forming
Glossary: Sag point- the condition (temperature,
time, thickness, etc) at which a sheet begins to sag
inside the thermoforming oven
Forming Process: Fundamental
Vacuum forming
The material is
clamped into a frame
Material is heated,
begin to sag, the
center of materials
moves downward and
seal against the mold
Vacuum is applied to
the back of the mold
(outside pressure of
the air pushes the
plastic against the
mold)
Forming Process: Fundamental
Vacuum forming
Uneven wall thicknesses are observed in this
technique
As the sheet touch the mold, the thickness at the
location become fixed, further stretching occur in the
area that have not yet touched the mold, typically at
he corner.
Therefore the thinnest area occur at the corner, near
the clamp
Forming Process: Pressure
forming
Positive air
pressure from the
top of the plastic
used to force the
materials against
the mold
Pressure forming
Methods
The materials is clamped and heated
Softening sheet is transferred to the mold area and
the seal is made
Air pressure is introduced and force the plastic
against the mold
The pressure is applied quickly to prevent the sheet
from cooling
Advantages;
Mold cycle can be faster than fundamental vacuum
forming
Sheet can be formed at lower temperature, because
the forcing pressure is high
Greater dimensional control
Pressure forming
Plug-Assist Forming
In this system, a plug is used to force the material
into the mold
Generally the plug will not pushed the material
completely into the mold, then a vacuum is applied
to draw the materials against the cavity walls
Instead a vacuum, air pressure could be used to
force the parts against the walls
new thermoplastic composite material
that can be used to make thermoforming
plug assists, it displays tremendous
dimensional stability and low thermal
conductivity. Designed to replace
Syntactic foam, machined aluminum
and wood for plug assists.
Plug-Assist Forming
Better wall thickness uniformity than obtained from
vacuum and pressure forming
Plugs can be made of metal, wood or thermoset
materials
The plug should be 10% to 20% smaller in length
and width than the female cavity
Plug-Assist Forming
Reverse draw forming
Is used when very deep draws are needed
In this technique, the material is heated to
the sag point, and then blown away from the
mold
The purpose of blowing is to thin the material
in the center of the sheet
The size of the bubble is controlled by an
electric eye. When the buble reachest the
correct size, the pressure is topped and the
plug press the material to the mold
The vacuum is activated through the mold to
draw the plastic against the mold wall
(a) Reverse draw step to
Pre-stretch the material
(b) plug-assist and vacuum
Forming step
Reverse draw forming: Plug
assist air slip forming
Free forming
The forming is done without a mold, especially those
where very high optical quality is required
Touching the mold can result in undesirable
changes in the surface quality of the part
Complexity of shapes of parts is limited
Often used for canopies
The part is expanded
with air pressure
The size of the bubble
is monitored by an
electrical eye
When the bubble
reach the desired
shape, air pressure is
reduced to a level that
maintains the size
while the part cools
Free forming
Some parts with very complicated shapes, can best
be formed if both plug and cavity mold are used
together
These mold must be matched so that it can be fit
together
Matched die forming
Matched die forming
Material is heated to the
sag point, and then
transferred to the molding
station, where the plug and
cavity molds are brought
together to squeeze the
material
No vacuum or air pressure
is applied during the
forming process
Material is mechanically
pressed into the shape
defined by matched molds,
and allow to cool while the
mold continue to press
against it
Thermoforming Machine
Not as complicated or costly as other plastic
processing machine that melt the plastic
materials
Element of the machine; heating chamber or
oven, method for removing the material from
the oven, and locating it so that the sheet
and the mold can be brought into airtight
contact
Machine can be single-mold batch system or
continuous, highly automated machine
Single-station thermoforming
machine
Heating the
sheet
Clamping the
sheet
Moving the sheet
and mold into
proper
relationship for
forming, a
vacuum or
pressure system
Critical operation parameters
The most important sheet property is
thickness (variation in thickness over the
sheet should be kept under 5%)
Uniformity from sheet to sheet is desired, so
that the processing parameter can be kept
constant, i.e. melt index, if one sheet has a
lower melt index than another, the amount of
heat to achieve the same formation will be
higher than in the sheet with lower melt
index
Other variables that might change from
sheet to sheet are density, molecular
orientation, etc
Key parameters during the forming operations;
Speed of vacuum application- vacuum should be
applied as quickly as possible
Temperature of the mold- the mold is normally at
room temperature, or temperature below solidification
point of the plastic
Size of the bubble
Plug size
Critical operation parameters
Male and Female mold
Female mold- a mold in which the part is pressed into a
cavity
Draw ratio
Is used to estimate the amount of wall thickness
variation that might occur
High draw ratio result in excessive thinning and wall
nonuniformities
Draw ratio = depth of part / width of part
Area ratio
Give some approximation of the amount of thinning that
will be experienced by the plastic sheet when it is
transformed
Area ratio = area of the sheet before forming
area of the part after forming
If the sheet is 200 cm2, and will be thermoformed into a
part that has total area of 400cm2, the area ratio is 1:2
Area ratio x desired thickness of finished part = minimum
original thickness (thickness of the blank)
The overall average thickness of the part will therefore
be one-half of original thickness
The area ratio is often used to calculate the size of the
unformed sheet that must be used to make a particular
part
Determine the thickness of the blank for
fundamental vacuum thermoforming, assuming
that the thickness of the finished part is uniform.
The finished dimensions of the part to be made
is 60 x 50 x 5 cm prepared by 2mm thick blank.
Consider the allowance for clamping and mold
clearance = 2 cm on each side
1. Dimension of blank (with allowance)= 64 x 54 cm
2. Calculate surface are of the part
50 x 60 x 1 side = 3000 cm2
50 x 5 x 2 sides = 500 cm2
60 x 5 x 21 sides = 600 cm2
Total area of finished part = 4100 cm2
3. Thermoforming area of the blank= 60 x 50
= 3000 cm2
4. Area ratio = 3000/4100
5. Thickness of the blank
= 2 mm/0.7317 = 2.73 mm