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The negative ions formed are relatively heavier as
compared to free electrons and, therefore, under a
given electric field the ions do not attain sufficient
energy to lead cumulative ionization in the gas.
Thus, these processes represent an effective way
of removing electrons from the space which
otherwise would have contributed to form
electron avalanche.
This property, therefore, gives rise to very high
dielectric strength for SF6.
The gas not only possesses a good dielectric
strength but it has the unique property of fast
recombination after the source energizing the
spark is removed.
The dielectric strength of SF6 at normal pressure
and temperature is 23 times that of air and at 2
atm its strength is comparable with the
transformer oil.
Although SF6 is a vapour, it can be liquefied at
moderate pressure and stored in steel cylinders.
Even though SF6 has better insulating and arc-
quenching properties than air at an equal pressure,
it has the important disadvantage that it can not be
used much above 14 kg/cm2 unless the gas is
heated to avoid liquefaction.
Application of Gases in Power System
The gases find wide application in power system
to provide insulation to various equipments and
substations.
The gases are also used in circuit breakers for arc
interruption besides providing insulation between
breaker contacts and from contact to the enclosure
used for contacts.
The various gases used are
(i) air (ii) oxygen (iii) hydrogen (iv) nitrogen (v)
CO2 and (vi) electronegative gases like sulphur
hexafluoride, arcton etc.
The various properties required for providing
insulation and arc interruption are:
(i) High dielectric strength.
(ii) Thermal and chemical stability
(iii) Non-inflammability.
(iv) High thermal conductivity.
(v) Arc extinguishing ability.
(vi) Commercial availability at moderate cost