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MATERIALS SCIENCE
CHAPTER 5
CORROSION & PREVENTION METHODS
• Negative electrode
Cathode
=
0.340 + 0.440
= 0.780 V
• Example:
• One half of an electrochemical cell consists of
a pure nickel electrode in a solution of ions;
the other is the cadmium electrode immersed
in the solution. Write the spontaneous overall
reaction and calculate the voltage that is
generated.
• Solution:
Galvanic series- represents the relative
reactivity of a number of metals and
commercial alloys in seawater
TEST 2 MEC
281
• 4 APRIL 2009
• 2.00 – 4.00 PM
• CHAPTERS: 3, 4, 5 & 6
Corrosion rate
• The rate of material removal as a
consequence of the chemical action
W= (ItM)/nF ………….…....(3)
I
From eq. (5), Corrosion rate, H/t = {( corr)(M)}/(nFρ) ……….....
(6)
where this rate is in unit cm/s.
The normal practice, unit of Corrosion rate, CR are in mpy and
mm/yr.
CR = { (128,704.7 x Icorr x M)/ n ρ } unit mpy
Aluminum helicopter
blade has corroded near
where it was in contact
with a steel
counterbalance.
Stress Corrosion Cracking (SCC)
• The SCC occurred because of the
simultaneous effects of tensile stress and
corrosion. Stress may be internally or
externally applied. Internal stresses are
produced by non-uniform deformation during
cold working, by unequal cooling from high
temperatures, and by internal structural
rearrangement involving volume changes.
Stresses induced by press and shrink fits, and
those in rivets and bolts are internal stresses.
Stress Corrosion Cracking
(SCC)
◆ Intergranular ...
Stress Corrosion Cracking
(SCC)
◆ Transgranular ...
Erosion-corrosion
• Corrosion accelerated by impact by solid
particles
• These may remove metal, or they may just
remove oxide and allow metal to corrode more
quickly
• Erosion corrosion is commonly found in
piping, especially at bends, elbows and
abrupt changes in pipe diameter-
position where the fluid changes
direction or flow suddenly becomes
turbulent. Propellers, turbine blades,
valves and pumps are also susceptible to
this form of corrosion.
Pitting Corrosion
• As the name suggests, pitting is an
extremely localised attack that results in
pits, i.e., holes of various sizes. They are
called holes because that the diameter of the
attack is generally small and that the depth-
to-diameter ratio is often greater than 1.
They may sometimes cluster together to give
a look of rough surfaces.
Mechanism …
Crevice corrosion
Crevice corrosion is a localized form of corrosion
usually associated with a stagnant solution on the
micro-environmental level. Such stagnant
microenvironments tend to occur in narrow crevices
such as those formed under gaskets, washers,
insulation material, fastener heads, surface deposits,
disbonded coatings, threads, lap joints and clamps,
under porous deposits and in many other similar
situations.
Example of Crevice
corrosion
Introduction
The easier technique to prevent corrosion occurred:
i. Understand the theory of all types of corrosion.
ii. The factors influenced corrosion rate.
Revision:
For example;
Application in fresh water
• Suitable metal: cast iron, steel, Al alloys, Cu alloys and
some stainless steel.
d)Availability of materials
– Consideration for future availability for repairs
or replacement or alternative replacement
materials.
2. Environmental alteration
• Decrease the velocity of corrosive fluid
• Use lower temperature
• Remove O2 from water solution by deaerated process
• Reduce the concentration of corrosive ions in a solution
• Adding inhibitors in system
– Scavengers type- react with and virtually eliminate a
chemically active species in solution such as dissolved O2
• Important condition:
– coating must be nonreactive in the corrosive
environment.
– Resist to mechanical damage that exposes
the bare metal to corrosive environment.
• Types of material for coating:
– Metals (Metallic coating); Ceramic (Inorganic
coating) & Polymers (Organic coating)
• Metallic coating
– Acts as sacrificial anodes instead of coated
metal.
– i.e: steel are coated with Zinc-plated or tin-
plated.
– Metal coating are plated by electro plating
process.
– metal./ part to be plated is made as cathode.
The electrolyte is a solution of a salt of the
metal to be plated and direct current is
applied.
• Inorganic coating/ceramic coating
– i.e reaction vessels can also be lined with
corrosion-resisitant teflon.
– Stable, adherent, nonporous, noconducting oxide
layer.
– i.e glass fused coating a steel.
• Organic coating
– Polymeric material, pints, varnish.
– Cheaper.
5. Cathodic protection
• Generally, Cathodic protection can be applied to
all types of corrosion but involve highly coast.
• The principle of cathodic protection is
connecting the metal (body) to be protected with
an external anode or (to the electrical DC
current) so that all areas of the metal surface
become cathodic and therefore do not corrode.
STEEL PROTECTED
PIPE SURFACE
UNPROTECTED
SURFACE
• Structures that are commonly protected by cathodic
protectionare the exterior surfaces of:
– Pipelines
– Ships’ hulls
– Storage tank bases
– Jetties and harbour structures
– Steel sheet, tubular and foundation pilings
– Offshore platforms, floating and sub sea
structures
• Cathodic protection is also used to protect the
internal surfaces of:
– Large diameter pipelines
– Ship’s tanks (product and ballast)
– Storage tanks (oil and water)
– Water-circulating systems.
Criteria for sacrificial anodes
• A corrosion potential that is sufficiently
negative for the specific application; in
general, alloying additions are made to
make the potential more negative than that
of the unalloyed basis metal
•Negative
terminal of
powers source
is connected to
the structure to
be protected.
•Positive
terminal is
joined to an
inert anodic
(i.e. graphite)
•The anode is usually surrounded by high conductivity
backfill material such as coke breeze, gypsum or
bentonite which improve electric contact between the
anode and surrounding soil.
CORROSION &
PREVENTION METHODS
TQ