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CHAPTER 2 :
PHASE DIAGRAM
Rasdi bin Deraman
Jabatan Kejuruteraan Mekanikal
UiTM Pulau Pinang
OBJECTIVE
After completing this chapter, students should be able
to :
Nuclei
Small
equiaxed
zone
Columnar
grains
a) b)
Figure : Schematic illustration of two cast structures of metals solidified in a square mold:
(a) pure metals; (b) alloys
METALLIC SOLID SOLUTION
Most metals are combined to form
alloy in order to impart specific
characteristic.
Figure : This is a schematic illustrating how the lattice is strained by the addition of
substitutional and interstitial solute. Notice the strain in the lattice that the solute atoms
cause.
2.2.2 Substitutional Solid Solutions
Solutions can also occur in the solid state and with the
same range of solubility as described for liquids.
Tm,A
liquidus line
Solidus line
2.4.3 Binary Phase Diagrams for No Solid Solution
The elements are dissimilar that their solubility in other
is nearly can negligible.
The figure below shows element A and B cannot
dissolves with each other. The elements are only
completely soluble in the liquid state but completely
insoluble in the solid state.
Temperature
L
Liquidus line
A+L B+L
Eutectic
temperature Solidus line
Eutectic point
A+B
A B
Composition
2.4.4 Binary Phase Diagrams for Limited Solid Solution
The elements are dissimilar that their solubility in other is
nearly can negligible.
Temperature
Liquid, L
Solidus
Solidus line
α α +L β+L β
line
Eutectic
temperature
Solvus α +β Solvus
line
line Eutectic point
A B
Composition
2.5 THE GIBBS PHASE RULE
Phase diagram describe thermodynamic equilibrium
condition. Number of phases in equilibrium limited by
thermodynamics.
This is described by Gibbs phase rule:
p+f=c+n
p = number of phases present
f = number of degrees of freedom
(state variables : Temperature, Pressure
and composition)
c = no. of components
n = no. of noncompositional variables
(n= 1 for alloy/ceramic, n= 2 for condensate)
Examples
Ice-water-steam : 3 distinct phases
solid
liquid
Pressur
e
gas
Temperature
T1 T2 T3
P1
solid
liqui
Pressur
d
P2
e
Temperature
T1 T2
Temperature
d
P1
e
gas
T1
Temperatur
e
Three phases – zero degree of
freedom
When the degree of freedom is equal to zero, it is called
invariant point.
Phase rule for binary system , c=2 (A and B)
F=3-P
S
WL =
R+ S
Cα − Co
WL =
Temperature = 1250 ºC
Cα − CL
Composition = 35 wt%Ni-65 wt % Ni
Phases present = α + Liquid
Example:
Based on the diagram below, determine the phase present,
the chemical composition and relative phase amount at the
composition and temperature 53 wt% Ni and 1300 ºC
respectively.
Solution:
Example:
Based on the diagram below, determine the phase present,
the chemical composition and relative phase amount at the
compo. and temp. 30 wt% Sn and 200 ºC respectively.
Solution:
Example:
Based on the diagram below, determine the phase
present, the chemical composition and relative phase
amount at the eutectic point and slightly below eutectic
temperature.
Solution:
Eutectic temp. (TE)
a.k.a. triple point.
CE
Eutectic concentration (CE) :
Figure : Copper-silver phase diagram
Min. melting temp. composition (CE)
Microstructural development during slow cooling
• Different composition
will give different L1
cooling curves. Freezing
zone S1
A B C D
Solid
Liquid
Liquid + Solid
Solid
2.8 VARIOUS TYPE OF ALLOY TRANSFORMATIONS
FOR BINARY PHASE DIAGRAMS
2.8.1 Eutectice Transformations
In the eutectic reaction the single liquid phase transforms
simultaneously into the two solid phases form at the eutectic
temperature. The eutectic reaction can be written as,
→ α +β
L cooling
+
2.8.2 Peritectic alloy transformations
For example,
L (5.4% Ni) + δ (4.0% Ni) 1517 C
γ (4.3% Ni)
o
2.8.3 Monotectic transformation
The monotectic reaction occurs where at a specific temp.
the liquid solution of composition L1 transforms into a solid
α -phase and a second liquid of composition L2 which is
different from L1. The equation reads:
L1 cooling
→ α + L2
The monotectic
transformation occurs
at 955oC at a comp.of
36% Pb. From 955oC
down, pockets of lead-
rich melt are entrapped
in the solid Cu alpha-
phase.
2.8.4 Eutectoid transformation
γ + β cooling
→ α
2.8.6 Monotectoid transformation
54
The Iron-Iron Carbide Phase
Iron Carbide Phase Diagram (Fe-
Fe3C)
Alpha, α Ferrite: - -
-Very low
solubility
of carbon.
- BCC structure.
- Max solid
solubility of 0.022
wt% C at 727°C
and the solubility
of carbon in
ferrite decreases
to 0.008 wt%C at
0°C.
55
Iron Carbide Phase Diagram (Fe-
Fe3C)
Austenite, γ :
- Interstitial solid
solution of C
in γ iron.
- FCC structure.
- Solubility of C
is 2.11% at
1148°C and
0.77% at
727°C.
56
Iron Carbide Phase Diagram (Fe-
Delta, δ iron
Fe3C)
- BCC structure
- Max. %C : 0.09
at 1495 ℃
Cementite, Fe3C : -
Intermetallic
compound.
- 6.67% C and
93.33% Fe.
- Orthorombic
structure
- Brittle
57
• MICROSTRUCTURE
CHANGES
3) Eutectoid reaction.
727 ℃
γ (0.77 %C) α (0.02 %C) + Fe3C (6.67
%C)
59
Slow Cooling of Plain Carbon
Steel
• Eutectoid plain carbon steel: If a
sample is heated up to 7500C and held
for sufficient time, structure will
become homogeneous• Belowaustenite.
eutectoid temperature,
layers of ferrite and cementite
are formed. Pearlite.
60
• The microstructure of eutectoid
Slow Cooling of Plain Carbon Steel
(Cont..)
• Hypoeutectoid plain carbon steel: If a sample
of 0.4% C is heated up to 9000C, it gets
austenitized, γ .
• Further cooling gives rise to α and pearlite.
Pearlite
61
Slow Cooling of Plain Carbon Steel
(Cont..)
• Hypereutectoid plain carbon steel: If a
1.2% C sample is heated up to 9500C and
held for sufficient time, it entirely gets
austenitized.
• Further cooling results results in
eutectoid cementite and pearlite.
62
Formation of pearlite
• Two-dimensional morphology of pearlite, apparently
consisting of alternating layers of cementite and ferrite.
63
Eg 2: Sketch of microstructural changes for a
steel containing 0.4 % C as it is cooled from
within the austenite phase region to below
eutectoid temp.
SOLUTION:
Euctectoid
65
HYPOEUTECTOID STEEL
T(°C)
1600
δ
1400 L
(Fe-C
γ γ γ γ+L System)
γ γ 1200 L+Fe3C
Fe3C (cementite)
1148°C
(austenite)
γ γ 1000
γ γ γ+Fe3C
α r s
α γ
γ 800 727°C
γ αγ αR S
wα =s/(r+s) 600 α+Fe3C
wγ =(1-w α)
400
0.77
α 0 Co1 2 3 4 5 6 6.7
α pearlite C o, wt% C
α w
pearlite =wγ
wα =S/(R+S) 100µm Hypoeutectoid
wFe3C =(1-w α) steel
66
HYPEREUTECTOID STEEL
T(°C)
1600
δ
1400 L
(Fe-C
γ γ γ γ+L System)
γ γ 1200 L+Fe3C
Fe3C (cementite)
1148°C
(austenite)
γ γ 1000
γ γ γ+Fe3C
Fe 3C
γ γ 800 r s
γ γ α R S
wFe3C =r/(r+s)600 α+Fe3C
wγ =(1-w Fe3C)
400
0.77
0 1 Co 2 3 4 5 6 6.7
pearlite C o, wt% C
wpearlite =wγ
wα =S/(R+S) 60µm Hypereutectoid
wFe3C =(1-w α) steel
67
SUMMARY OF Fe-Fe3C P.D
68
A carbon steel alloy containing 0.3 wt% C when cooled
just below eutectoid temperature level. Determine:
a) The relative amount of proeutectoid α ferrite form.
b) The relative amount of eutectoid α ferrite form.
c) Sketch the microstructure of item (a) and (b)
respectively.
Mar 2005
With the aid of a neat sketch, describe the
microstructural changes which take place
when a 1.1 wt% plain carbon steel is slowly
cooled from the austenite region just above
the upper critical temperature line.
Sep 2001
A carbon steel alloy containing 0.5 wt% C when cooled
from the austenite region crosses the A3 line. Describe
with neat sketches the microstructural changes that take
place during the slow cooling of this steel from the
austenite region. 70
Example
3.
A 0.90% C hypereutectoid plain-carbon steel is slowly
cooled from 900°C to a temperature just slightly above
727°C. Calculate the weight percent proeutectoid
cementite and weight percent austenite present in the
steel.
Example 4
A 0.25% C hypoeutectoid plain-carbon steel is slowly cooled from
950°C to a temp. just slightly below 727°C. Calculate:
(a) the weight percent proeutectoid ferrite in the steel.
(b) the weight percent eutectoid ferrite and weight percent
eutectoid cementite in the steel.
71
Example
5.
What is the Carbon concentration of an iron-carbon alloy
for which the relative amount (fraction) of total ferrite is
0.94?
Note: ; Angstrom = m
MARK = 3/100