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dw 1 p g C z Fz dt z
Energy
Many Different Forms
Kinetic Internal Potential
Mechanical
Chemical
Electrical
(courtesy F. Remer)
Energy
Internal
Internal energy = kinetic + potential energy of the molecules or atoms of a body (e.g. parcel) Kinetic energy = translation, rotation, vibration of the molecules or atoms
(courtesy F. Remer)
E = constant
(EKinetic + EPotential + EInternal + EChemical +
Work of Expansion
Work is a Form of Mechanical Energy Work = Force x Distance
d W = F Dx
Force Distance x
(courtesy F. Remer)
Work of Expansion
Work is Performed When Air Expands
F
(courtesy F. Remer)
Work of Expansion
Work Performed by a System on Its Environment Is Positive
dW > 0
F
(courtesy F. Remer)
Work of Expansion
Work Performed on a System by Its Environment Is Negative
dW < 0
(courtesy F. Remer)
Work of Expansion
Similar to a Piston
Volume Increases
F
(courtesy F. Remer)
Work of Expansion
Change in Volume Causes Work!
dW FDx
F
Dx Piston Moved Distance Dx
dW p dV
V2
V1
p dV
Internal Energy
Joules Law
Air
Thermally Insulated
(courtesy F. Remer)
Internal Energy
Joules Law
Air
Thermally Insulated
(courtesy F. Remer)
Internal Energy
Joules Law
Air expands to fill container
Change in volume
Air Valve Open Air
(courtesy F. Remer)
Internal Energy
Joules Law
First Law of Thermodynamics
Air Valve Open Air
dq du pda
Which means
du 0
(courtesy F. Remer)
Internal Energy
Joules Law
Air
Air
Valve Open
Tells us how Polly Parcels thermodynamic properties (temperature, pressure, volume, mass) will change as she rises or sinks in her environment.
(courtesy F. Remer)
Isochoric Process
Changes in
Heat Added or Removed Temperature Pressure
p
273K 373K
V
(courtesy F. Remer)
Isobaric Process
Changes in
Heat Added or Removed Temperature Volume
p
273K 373K
V
(courtesy F. Remer)
Isothermal Process
Changes in
Heat Added or Removed Pressure Volume
p
273K 373K
V
(courtesy F. Remer)
What happens to Polly for an isothermal process? How much work does she do in going from V1 to V2?