Professional Documents
Culture Documents
Review of Exothermic
Reactants
Ep is higher than Products Ep. Now, we must consider the activation energy (the energy needed so that the reactants bonds will break and reform to make product)
Review of Endothermic
Reactants
Ep is lower than Products Ep. Need to add more energy to the system for the forward reaction to take place. Still need to consider activation energy
Activated Complex
Is
the short-lived, unstable structure formed during a successful collision between reactant particles. Old bonds of the reactants are in the process of breaking, and new products are forming Ea is the minimum energy required for the activation complex to form and for a successful reaction to occur.
smaller the activation energy, the faster the reaction will occur regardless if exothermic or endothermic. If there is a large activation energy needed, that means that more energy (and therefore, time) is being used up for the successful collisions to take place.
Sample Problem
The
following reaction has an activation energy of 120kJ and a H of 113kJ. 2NO2 2NO + O2
Draw and label a potential energy (activation energy) diagram for this forward reaction. Calculate the activation energy for the reverse reaction (if the reaction went backwards)
Another Problem
The
following hypothetical reaction has an activation energy of 70kJ and a H of 130kJ A+BC+D
Draw and label a potential energy diagram for the reaction Calculate the activation energy for the reverse reaction.
of what is occuring during a chemical reaction for both endothermic and exothermic.
KNOW
Practice:
1.
2.
Answer to #2
The activation energy (Ea) for the forward reaction is shown by (a):