Professional Documents
Culture Documents
Frank R. Leslie,
B. S. E. E., M. S. Space Technology, LS IEEE
3/15/2010, Rev. 2.1 fleslie @fit.edu; (321) 674-7377 www.fit.edu/~fleslie
In Other News . . .
The new town of Destiny (south of Yeehaw Junction, FL) will grow various biocrops to evaluate their profitability for biofuels The Farm to Fuel program is receiving significant funding from the Florida Dept of Agriculture
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Overview: Bioenergy
Bioenergy consists of biomass (biological mass) used in the production of energy; http://www.bioproducts-bioenergy.govBiomass Phototrophs use light to survive and propagate Chemotrophs (like us) eat phototrophs (vegetables and salads)! Salads topped with biodiesel and acetic acid!
CO2 + H2O >--solar energy and chlorophyll CH2O + O2,
or carbohydrate and oxygen While biomass combustion releases CO2 into the atmosphere, new plants require CO2 to grow, balancing the process for no net CO2 over a long time
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13.3 Energy Extraction and Preparation 13.3.1 Dry Biomass 13.3.2 Wet Biomass 13.3.3 Gaseous Biomass 13.3.4 Energy Conversion 13.4 Environmental Aspects 13.0 Conclusion
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http://www.eia.doe.gov/cneaf/solar.renewables/page/biomass/biomass.gif
The Midwest is now using less biomass while the West use is rising
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http://www.bioproducts-bioenergy.gov/
http://tonto.eia.doe.gov/state/state_energy_profiles.cfm?sid=FL
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http://www.sierraclub.org
13.3 Energy Extraction and Preparation Dry biomass may have some residual moisture but only requires physical preparation like chipping to fire it
Some research is being done to see if long trees can be directly fired on a metal conveyor belt Wet biomass can absorb more heat energy from a furnace than it can supply; the biomass must be externally dried to burn Small biomass pellets are made from wood scraps and sawdust There are pellet-burning stoves with a screw conveyor feed
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www.harmanstoves.com/
Placed in oven heated by what would otherwise be waste heat Using solar thermal energy air-heaters
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13.3.1 Biofarms: Trees, Shrubs, and Grasses Energy tree farms are grown to produce a sustainable crop suitable for chipping and combustion Switchgrass, sugar beets, and sugar cane residual waste are likely possibilities Counterculture groups are pushing biohemp for various reasons and agendas growing hemp is illegal in the US -- Controlled Substances Act of 1971 These groups claim trace levels of THC (tetrahydrocannibinol), active ingredient of marijuana, shouldnt make it a controlled substance Mostly in the tips of leaves The Drug Enforcement Agency has free food and housing for you available should you grow it anyway!
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13.3.1 Biofarms: Bagasse (processed cane) The stalks of the sugar cane are squeezed to get the juice out to make sugar
The wet fibrous residue is called bagasse A bioenergy version could be developed to make a cane maximized for energy, yet it would still yield sugar juices The leaves could be burned as well; now discarded or burned off in the fields
Jaggery: making from sugar cane juice
NREL
www.tide-india.org/ images/big-images/conservi...
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Agricultural waste A boiler receives the combustion heat and produces steam The boiler supplies steam to a condensing steam turbine-generator unit generating about 25 to 60 MW
Coal plants can cofire biomass or convert completely to burn only biomass
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13.3.1.2 Municipal Solid Wastes (MSW) Municipal waste streams may have anything in it that people want to throw away -- its a mix
Air blast and magnetic separation can select different streams to go in various piles Permanent magnets first extract the steel and iron Alternating current electromagnets use the eddy current effect to remove nonferrous metals (Al, Cu) Light paper and plastic will stratify in an air column to remove them from heavier substances (metal and bottles) Hand sorting can pick out some of whats left Without this process, pollutants arent removed
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13.3.1.3 Industrial Waste Streams (IWS) Industrial wastes differ from municipal wastes in that they are often separated or categorized as outputs from specific processes Its relatively easy to have pure waste streams all of one material, like wood strips, pallets, trim scrap Paper products are a possibility, but dioxin content can cause air pollution Any wet waste stream will require drying before burning Could require more energy to dry than can be extracted from it
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Treated with hydrogasification at high pressure and low temperatures to produce a gas or biofuel oil
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www.bridgewater.edu
13.3.2.1.1 Hydrofarms: Water Hyacinth, etc. Impoundments containing water plants can clean effluent water by extracting nutrients that should be kept out of lakes and streams Harvesting by boats uses wide conveyor belts that lift the weed onto the boat The wet weeds are heavy and hard to pack densely
www.water-hyacinth.com
This is uneconomic in most areas Drying is by dumping in fields for sun drying
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www.water-hyacinth.com
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http://boonie-maps.home.att.net/Orlando_Wetlands/doq_map.jpg
This tertiary cleaning process extracts nutrients and flows the water through long channel lakes and ponds
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Manure lagoons at Consolidated Animal Feeding Operations (CAFO) pose a stored pollution problem
Lagoon dam breaches have poisoned nearby streams and killed thousands of fish in NC Anaerobic digestion allows methane gas recovery
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40 billion Btus of methane per 100,000 people per year Florida methane could yield 20 trillion Btus per year Cost would be $6 to $8 per million Btu At present, filtered sewage sludge is often bulk dumped (sprayed) on agricultural pastures The methane gas from a sewage lagoon can be recovered by a bioenergy process, reducing the sludge before disposal A cruise ship is like a small city -- where does the sewage go?
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See http://www.homepower.com/files/HP93_32.pdf for an excellent discussion on how to make it A $20 million biodiesel plant is being built for Utahs Smithfield Foods, Inc. to convert swine waste into biodiesel If fryer oil smells like french fries, does this stuff smell like pork chops? A local company, Brevard Biodiesel, is experimenting with developing a local market for biodiesel SynFuel (Grant) is working to make syngas from glycerol, a biodiesel byproduct
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Methanol and crystal lye are used in processing some 48 gallon batches 5 parts oil to 1 part methanol plus titration of the mixture with 0.1% lye to reach a ~8.5 pH Mixture separates after several hours
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http://www.homepower.com/files/HP93_32.pdf
The bottom part is glycerin, and can be used to make soap [do you smell like French fries after a bath?]
http://www.veggievan.org
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http://www.homepower.com/files/HP93_32.pdf
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http://www.forester.net/mw_0303_controlling.html
13.3.3.1 Methane
Methane, CH4, is a likely future hydrogen gas source The four H atoms allow more hydrogen to be produced per molecule of methane Cracking or pyrolysis changes the molecules to yield hydrogen and CO, which is also combustible The combination of methane and COx is known as biogas and can be made from acetic acid, produced from glucose by microorganisms Methane hydrates exist in cold, deep water in the ocean, but are difficult to extract without methane release
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Collecting and burning the methane is clearly better than letting it escape to the air Landfill gas cleanup is necessary because of the many other VOCs that should be kept out of the air
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13.3.4.1 Conversion: Direct Combustion Refuse Derived Fuel (RDF) can be fired (burned) directly or in combination with conventional fuels
Some processing, such as cleaning, chopping, etc. may be needed for handling or air pollution avoidance Fluidized grate furnaces blow air in beneath the grate, and this keeps the burning mass in seething flotation as it burns
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13.3.4.2 Conversion: Anaerobic Digestion Bacteria produce acetic acid (found in vinegar) Methane gas 50% to 80%, $2.50/kft3 (1976) Microgy Cogeneration Systems, Inc. is building a 25 MW digestion plant Essex Junction Wastewater Treatment facility in Essex Junction, Vermont treats 1.7 million gallons of waste water per day and will produce 400 MW electricity per year to reduce plant costs Price of electricity is estimated at $0.02 per kWh
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13.3.4.3 Conversion: Fermentation Enzymes can change cellulose into sugars, which can then be fermented into alcohol Cane sugar, C6H12O6 2C2H5OH + 2CO2 Fermentation of corn or other biomass will produce ethanol The use of food stocks in this way might be seen as a poor use of food Brewery spillage or waste and outdated soda can be filtered, cleaned, and reprocessed to produce fuel
It is denatured with 15% gasoline to discourage drinking and avoid Federal liquor law taxes Fermentation of stillage refuse can also produce methane
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13.3.4.4 Conversion: Pyrolysis Fast pyrolysis is heating biomass without oxygen to decompose it into vapors, aerosols and char
The liquid has ~one-half the heating value of fuel oil The process is tuned to produce liquid rather than charcoal Low-quality producer gas can be cleaned to remove CO2 and N2, then this synthesis gas reacted as 2H2 + CO CH3OH to yield methanol
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13.3.4.5 Conversion: Other Hydrogasification Low temperature and high pressure produces ethane & methane plus CO2 A catalyst aids the process Hydrogenation Waste + Steam and CO forms low-sulfur oil having 16000 Btu/pound heating value Used to make peanut butter and margarine
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13.4.1 Some Environmental Biomass Views Policies or viewpoints of the Sierra Club (a large environmental organization) may be found at
http://www.beyondgrass.org/greenpower/archives/Florida%20Sierra%20Biomass%20 or at http://sierraclub.org/policy/conservation/biomass.asp
The reuse or recycling of wastes is necessary prior to land filling or biomass combustion to avoid more toxics introduced into the air and water In many cases, separation of undesirable materials is so difficult that combustion should be avoided Municipal waste streams have heavy metals, toxins, pesticides, etc.; whatever someone wanted to get rid of
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13 Conclusion: Biomass
Renewables are a very small contributor to present Florida energy sources Biomass energy is the predominate renewable energy source in Florida; little wind or sun, surprisingly Unfortunately, most of present production is from municipal solid waste (MSW) that should be avoided or phased out due to heavy metal contaminants
http://www.eia.doe.gov/cneaf/electricity/st_profiles/florida/fl.html#t1
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Questions?
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References: Books/Periodicals
Blackburn, John O. Solar Florida: A Sustainable Energy Future. Winter Park: Florida Conservation Foundation, 1993. ISBN 0-913297-07-1. Cheremisinoff, Paul N., and Thomas C. Regino. Principles and Applications of Solar Energy. Ann Arbor: Ann Arbor Science, 1978. ISBN 0-250-40247-5. Brower, Michael. Cool Energy. Cambridge MA: The MIT Press, 1992. 0-262-02349-0, TJ807.9.U6B76, 333.7940973. Boyle, Godfrey. Renewable Energy, Second Edition. Oxford: Oxford University Press, 2004, ISBN 0-19-26178-4. (my preferred text) Duffie, John and William A. Beckman. Solar Engineering of Thermal Processes. NY: John Wiley & Sons, Inc., 920 pp., 1991 Srensen, Bent. Renewable Energy, Second Edition. San Diego: Academic Press, 2000, 911 pp. ISBN 0-12-656152-4. Durkee, Scott. Getting off the Petroleum Grid with Biodiesel. Home Power, No.93, pp. 32-39, 2003.
Tickell, Joshua. From the Fryer to the Fuel Tank. Ashland OH: BookMasters, 2001? www.veggievan.org
http://www.wnbiodiesel.com/ Willie Nelson
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http://www.solwest.org/news/page1.htm#feature2 story by Jennifer Barker on a biomass plant http://gis.joensuu.fi/termit/termeng/frame.htm Bioenergy glossary http://www.bioproducts-bioenergy.gov/ US Govt. Bioenergy Office http://www.bioproducts-bioenergy.gov/about/glossary.asp Bioenergy definitionshttp://florida.sierraclub.org/issues/energy.html Florida Chapter on Energy http://florida.sierraclub.org/issues/energylinks.html links to sustainability and renewable organizationshttp://www.energycentral.com/sections/search/site_search.cfm enter biomass http://www.homepower.com/files/HP93_32.pdf on biodiesel fuel http://www.biomass.org/ Lobbying group http://www.forester.net/msw.html More than you ever wanted to know about trash http://www.forester.net/mw_0303_controlling.html Smelly trash and suppression http://www.pnl.gov/biobased/bcf.stm Hydrogenation http://www.coppicing.com/ on cutting plants to the ground and letting them regrow http://www.veggievan.org Biodiesel production http://www.brevardbiodiesel.org http://journeytoforever.org http://biodiesel.org http://changingworld.tech.com __________________________________________________________________________________www.dieoff.org. Site devoted to the decline of energy and effects upon population www.ferc.gov/ Federal Energy Regulatory Commission www.google.com/search?q=%22renewable+energy+course%22 solstice.crest.org/ dataweb.usbr.gov/html/powerplant_selection.html http://www.eere.energy.gov/state_energy/tech_biomass.cfm?state=FL
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Notes bioenergy
P. 827, 725 in Sorenson Biomass fuel costs twice fossil fuel
www.seco.cpa.state.tx.us/.../ re_renew_maps_bio_poten.htm