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What is a Phase?
Phase is a form of material having characteristic structure and properties. Phase can be continuous (air in the room) or discontinuous (salt grains in the shaker). Gas, liquid or solid. Pure substance or solution (uniform structure throughout).
What is a Phase?
Graphic mapping of the natural tendencies of a material or a material system. Primary variables:
Temperature-Composition Diagrams
Engineering processes conducted at atmospheric pressure (P/T variations). The most common: temperaturecomposition phase diagrams.
Cooling Curves
Cooling Curves
Pure Metals
Alloys
Alloys A + B
100%
100%
Phase Diagrams
ISSUES...
When we combine two elements...
what equilibrium state do we get?
In particular, if we specify...
--a composition (e.g., wt%Cu - wt%Ni), and --a temperature (T)
then...
How many phases do we get? What is the composition of each phase? How much of each phase do we get?
watersugar system
Solubility limits. Degree of solubility determines properties. Types of Metals I-Two metals completely soluble in each other. II- Two metals soluble in liquid state and insoluble in solid state. III-Two metals soluble in liquid state and partially soluble in solid state.
Complete Solubility
Degree of solubility depends on temperature At max. solubility, 183 C: lead holds up to 19.2 wt% tin in a single phase solution, and tin holds up to 2.5wt% lead and still be a single phase.
Partial solid solubility -When temperature is decreased, the amount of solute that can be held in solution decreases in a continuous manner. -If a saturated solution of tin in lead is cooled from 183C, the material will go from a single-phase solution to a two-phase mixture as a tin-rich second phase precipitates from solution. -This change in structure can be used to alter and control the properties in a number of engineering alloys.
Contd
Utilization of Diagrams
These can be used to determine
Phase diagrams
Let us discuss the phases as function of T, Co, P. For
--binary systems: just 2 components. --independent variables: T and Co (P = 1atm is always used).
Phase Diagram for Cu-Ni system
Examples:
Cu-Ni phase diagram
Phase diagrams :
Examples:
composition of phases
Cu-Ni system
a S2 100 % % by mas L2 S 2
L2 a L2 S 2 100% % by mass
Examples:
Cu-Ni system
S 43 35 73wt % WL R S 43 32 W R R S
= 27wt%
Example problem
Givendata : X 36% of B a 36% of B L2 72% of B S 2 18% of B Compute liquid phase and solid phase % amounts by mass.
Tie lines for calculating the %ages of phases present at a particular temperature
% Liquid = ? % eutectic =
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Cast Irons
-Iron-Carbon alloys of 2.11%C or more are cast irons. -Typical composition: 2.04.0%C,0.5-3.0% Si, less than 1.0% Mn and less than 0.2% S. -Si-substitutes partially for C and promotes formation of graphite as the carbon rich component instead Fe3C.
Summary
Phase diagrams are useful tools to determine:
--the number and types of phases, --the wt% of each phase, --and the composition of each phase
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Example problem
Givendata : X 36% of B a 36% of B L2 72% of B S 2 18% of B Compute liquid phase and solid phase % amounts by mass.
Tie lines for calculating the %ages of phases present at a particular temperature
Thanks
Solid Solution
A homogeneous crystalline structure in which one or more types of atoms or molecules may be partly substituted for the original atoms and molecules without changing the structure