Amna Crude Oil

National Oil Corporation
Libyan Petroleum Institute
Crude oil assay

Amna crude oil
Work Order No. LPI- 00344/11/IL02/2008

Client: National Oil Corporation
Date of Issue: Nov., 2008
Prepared by:
Industrial Laboratories & Production Technologies Department
All copyrights are reserved to (NOC and LPI). Neither this report nor any part may be
reproduced or transmitted in any means, electronic or mechanical, including photocopying,
microfilming and recording or by any information storage and retrieval system, nor the
included data and results used, without the written permission of (NOC and LPI).
DAP-PL-4086.00

Document No. LPI-LAB-004-04
Amna Crude Oil
Evaluation of Amna Crude Oil

This assay is a part of a series of crude oil evaluation reports have been prepared for
Crude oil marketing department of National Oil Corporation. A bout 60 Liters of
Crude oil sample was collected from Sirt oil Company. A homogenous sample has
been collected on 4 th August 2008 from shipping line at Rasslanuf terminal, the
sample was collected according to standard method ASTM D4057.
The analysis of crude oil sample was carried out using well recognized standard
procedures given in ASTM, IP and UOP methods. The distillation of crude oil was
carried out using a batch fractionation unit made according to ASTM D-2892 method
& ASTM D-1160 method.
The crude oil was distilled under atmospheric and vacuum pressure and the
atmospheric residue was further distilled to obtain distillate fractions. Distillate
fractions corresponding to true boiling point up to 550+0C were collected.
List of Tables
Table 1
Table 2
Table 3
Table 4
Table 5
Table 6
Table 7
Table 8
Table 9
Table 10
Table 11
Table 12
Table 13
Appendix
Crude oil General Tests

TBP Distillation of Crude Oil
Detailed Hydrocarbon Analysis of (70-175 oC) Fraction
Detailed Hydrocarbon Analysis by Group Types
Detailed Hydrocarbon Analysis by Carbon Number
GC-Carbon Distribution of Crude Oil
Yield and Inspection of Light Naphtha Cut
Yield and Inspection of Heavy Naphtha

Yield and Inspection of Kerosene Cut
Yield and Inspection of Atmospheric Gas Oil Cut
Yield and Inspection of Vacuum Gas Oil Cut
Atmospheric Residue 350+ 0C
Vacuum Residue 550+ 0C
TBP Graphical Data of Crude Oil
1
Libyan Petroleum Institute; Gargarish Road-km7 P.O. Box: 6431 Tel: 4830022-27 / 4836821-23 Fax: 4830031-4836820
DAP-PL-4086.00

Amna Crude Oil
TABLE (1)
CRUDE OIL GENERAL TESTS
DESCRIPTION
METHOD
Density@ 15 C, g/ml
Specific gravity@60/60 0F
API gravity
Flash point ( PMCC ), oC
Reid vapour pressure, psi
Hydrogen sulphide, ppm
Water and sediment content, vol.%
Sulphur content, wt.%
Pour point, oC
Kinematic viscosity @ 70 oF, cSt
@ 100 oF, cSt
Asphaltenes content, wt.%
Conradson carbon residue, wt. %
Ash content, wt.%
Characterisation factor
Salt content (as Nacl) mg/l
Vanadium, ppm
Nickel, ppm
Calcium, ppm
Potassium, ppm
0.8396
0.8405
36.9
<-35
4.9
1.27
0.15
0.112
+18
10.6215
0.28
1.86
0.008
12.3
11.7
0.318
3.171
0.911
0.149
ASTM D-4052
Calculation
Calculation
ASTM D-93
ASTM D-323
IP 103
ASTM D-4007
ASTM D-4294
ASTM D-97
ASTM D-445
ASTM D-445
IP 143
ASTM D-189
ASTM D-482
UOP 375
IP 77
ASTM D 5708
ASTM D 5708
Dry ashing
Dry ashing
2
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Amna Crude Oil
Continued Table-1
Distillation Characteristics
METHOD
IBP
@ 760mmHg
5%
10%
20%
30%
40%
50%
60%
70%
80%
FBP
Recovery % vol.
Residue % vol.
Loss % vol.
54
108
133
187
246
297
344
365
368
371
72
27
1.0
ASTM D-86
Modified
3
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Amna Crude Oil

Table (2)
TBP Distillation of Crude Oil
Cut Temp C
Condensate
C5 - 70
70 - 90
90 - 110
110 - 130
130 - 150
150 - 175
175 - 195
195 - 215
215 - 235
235 - 255
255 - 275
275 - 295
295 - 315
315 - 335
335 - 350
350 - 370
370 - 400
400 - 440
440 - 460
460 - 480
480 - 500
500 - 520
520 - 550
550+
Yield
Cumulative Yield
wt.%
vol.%
wt.%
vol.%
0.90
3.75
2.57
2.52
3.04
3.25
3.27
3.11
2.97
3.33
3.31
3.81
3.67
3.55
3.32
2.41
3.28
4.27
5.00
3.04
3.13
2.55
2.96
2.55
24.44
1.32
4.80
3.02
2.89
3.49
3.62
3.58
3.33
3.12
3.46
3.39
3.89
3.72
3.58
3.32
2.40
3.25
4.19
4.86
2.92
2.99
2.41
2.79
2.38
21.25
0.90
4.65
7.22
9.74
12.78
16.03
19.30
22.41
25.38
28.71
32.02
35.83
39.50
43.05
46.37
48.78
52.06
56.33
61.33
64.37
67.50
70.05
73.01
75.56
100.00
1.32
6.12
9.14
12.03
15.52
19.15
22.73
26.06
29.19
32.65
36.04
39.93
43.65
47.23
50.56
52.95
56.20
60.39
65.25
68.18
71.16
73.58
76.37
78.75
100.00
Specific Gravity @
60/60F
0.5736
0.6571
0.6956
0.7149
0.7321
0.7537
0.7669
0.7838
0.7989
0.8096
0.8199
0.8229
0.8286
0.8337
0.8398
0.8447
0.8494
0.8558
0.8646
0.8743
0.8804
0.8878
0.8923
0.8992
0.9665
4
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Amna Crude Oil

Table (3)
Detailed Hydrocarbon Analysis of 70-175 oC Fraction (ASTM D5134)
PIONA Analysis (Identified Compounds Listed in Chromatographic order)
Compounds
Wt%
Vol.% Mol.% Compounds
Isobutane
0.166 0.223
n-C4
0.450 0.576
3-Methyl-1-Butene 0.401 0.475
n-C5
0.634 0.752
2,3DMC4
0.495 0.556
3MC5
0.361 0.404
n-C6
1.914 2.156
2,4DMC5
0.190 0.209
2,2,3TMC4
1.060 1.142
C6?
0.333 0.375
2MC6
0.498 0.545
1,1DMCC5
0.130 0.128
Benzene
2.257 1.909
2,2,4-TMC5
2.500 2.710
n-C7
2.785 3.028
cis-1,2DMCC5
0.862 0.835
MCC6
0.820 0.792
cis-2-Heptene
0.204 0.214
1,1,3-TMCC5
1.486 1.486
ECC5
10.470 10.158
2,3,3-TMC5
7.088 7.301
1,1,2-TMCC5
0.724 0.701
3,4DMC6(L)
0.418 0.434
3MC7
0.417 0.439
cis-1.3DMCC6
0.386 0.377
1,1DMCC6
0.608 0.583
C7?
0.142 0.155
0.333
0.903
0.667
1.025
0.670
0.488
2.590
0.219
1.227
0.450
0.576
0.154
3.370
2.553
3.224
1.024
0.974
0.242
1.545
12.437
7.237
0.753
0.426
0.426
0.401
0.632
0.165
Wt%
Vol.% Mol.%
Toluene
0.556 0.522
0.578
n-C8
1.765 1.867
1.802
2,2DMC7
0.109 0.113
0.099
2M4EC6
3.088 3.277
2.808
1,1 ,3TMCC6
0.738 0.709
0.682
1.804 1.553
1.982
m-Xylene
3.209 2.772
3.525
p-Xylene
3,3 ,4TMC6
1.245 1.250
1.132
4EC7
0.426 0.438
0.387
ctc-1,2,4TMCC6
0.149 0.141
0.138
3,3-DEC5
0.101 0.099
0.091
O-xylene+1,1,2TMCC6 0.324 0.274
0.356
TMC6 (2)?
1.291 1.323
1.147
n-C9
11.216 11.625 10.199
n-BCC5
2.176 2.063
2.010
3,3DMC8
0.981 0.988
0.804
n-Pbenzene
1.910 1.648
1.853
1M3Ebenzene
0.900 0.775
0.873
C9?
0.119 0.124
0.108
5MC9
2.062 2.106
1.690
1.384 1.170
1.343
1M2Ebenzene
0.299 0.306
0.245
2MC9
1.034 1.039
0.847
3EC8
1.354 1.373
1.110
3MC9
0.574 0.595
0.522
C9?
10.437 10.635 8.555
n-C10
0.700 0.586 0.680
1,2,3TMEbenzene
5
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Amna Crude Oil
Continued Table-3
Compounds
2,2,4TMC6
1,2,5DEbenzene
1M3IsoPbenzene
Wt%
Vol.% Mol.% Compounds
0.638 0.667
0.723 0.612
0.169 0.146
1.761 1.780
C11 Paraffin 3?
1,4DM2Ebenzene 0.370 0.314
1.767 1.801
C10?
0.223 0.223
1-Undecene
100.00 100.00
Total
0.581
0.629
0.147
1.314
0.321
1.448
0.169
100.00
Wt% Vol.% Mol.%
0.169 0.146
1M2n-Pbenzene+Unidentified 0.463 0.394
0.349 0.353
C11 Paraffin 2?
0.815 0.696
1,3DM4Ebenzene
0.401 0.403
C11?
0.092 0.080
Tert-1B2Mbenzene
4.480 4.502
n-C11
1M3IsoPbenzene
0.147
0.402
0.260
0.708
0.300
0.073
3.343
6
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Amna Crude Oil
Table (4)
PIONA Analysis (Hydrocarbon totals by group types)
Group Types
Wt%
Vol.%
Mol.%
Total Aromatics
Total Iso-Paraffins
15.121
27.763
12.929
28.851
16.262
26.366
Total Naphthenes
19.105
18.494
21.327
Total Olefins
0.828
0.911
1.078
Total n-Paraffins
33.846
35.363
31.974
Total Unknowns
3.337
3.452
2.993
Total
100.00
100.00
100.00
7
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Amna Crude Oil
Table (5)
PIONA Analysis (Totals by Carbon Number)
Group
Wt%
Vol.%
Mol.%
Ave. Mw.
Ave. Sp.Gr
Butanes
Pentanes
Hexanes
Heptanes
Octanes
Nonanes
Decanes
C11s
Total
0.615
1.036
5.360
17.160
21.285
26.765
20.474
7.306
100.00
0.798
1.226
5.399
17.205
21.020
26.602
20.409
7.340
100.00
1.235
1.693
7.569
20.242
22.215
24.682
16.907
5.457
100.00
58.105
71.354
82.587
98.868
111.745
126.471
141.228
156.140
116.627
0.577
0.632
0.743
0.746
0.757
0.753
0.750
0.745
0.748
8
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Amna Crude Oil
Table (6)
GC-Carbon Distribution of Crude Oil
Compounds
Wt.%
Mol.%
Fraction MW
MW Calculation
C3
iC4
nC4
iC5
nC5
C6
C7
C8
C9
C10
C11
C12
C13
C14
C15
C16
C17
C18
C19
C20
C21
C22
0.77
0.95
3.05
3.39
3.39
6.68
10.79
12.88
10.25
9.07
6.95
5.41
4.90
4.84
3.96
2.70
1.73
1.98
1.62
0.82
0.76
0.54
2.14
2.01
6.44
5.77
5.76
9.52
13.21
13.84
9.81
7.83
5.46
3.90
3.26
3.00
2.29
1.46
0.88
0.95
0.74
0.36
0.31
0.21
44.10
58.12
58.12
72.15
72.15
86.18
100.21
114.23
128.26
142.29
156.30
170.30
184.40
198.40
212.40
226.40
240.50
254.50
268.50
282.60
296.58
310.61
0.95
1.17
3.74
4.16
4.16
8.20
13.24
15.81
12.58
11.14
8.53
6.64
6.02
5.94
4.86
3.31
2.13
2.43
1.99
1.00
0.93
0.66
9
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Amna Crude Oil
Continued Table-6
Compounds
Wt.%
Mol.%
Fraction MW
MW Calculation
C23
C24
C25
C26
C27
C28
C29
C30
C31
C32
C33
C34
Total
0.45
0.44
0.25
0.22
0.17
0.17
0.15
0.11
0.10
0.13
0.15
0.23
100.00
0.17
0.16
0.09
0.07
0.05
0.05
0.04
0.03
0.03
0.04
0.04
0.06
100.00
324.64
338.66
352.69
366.72
380.74
394.77
408.80
422.82
436.85
450.88
464.91
478.93
0.55
0.54
0.31
0.27
0.20
0.20
0.18
0.13
0.13
0.16
0.19
0.28
122.73
10
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Amna Crude Oil
TABLE (7)
Yield and Inspection of Light Naphtha Cut
C5-70 0C
TBP Cut Points

Vol. % on Crude
Wt. % on Crude
Density@15C, g/ml
Specific gravity@ 60/60 F
API gravity
Reid vapour pressure@37.8 C, psi
Volume Average Boiling Point, (VABP), C
Sulphur content, wt. %
Octane Number; Research method
Octane Number; Motor method
Distillation,
IBP C
5%
10%
20%
30%
40%
50%
60%
70%
80%
90%
95%
FBP
Residue,vol.%
Losses, vol.%
Molecular weight
Lead content, ppm
4.80
3.75
0.6478
0.6481
86.8
12.2
57
0.010
75.1
71.3
34
43
46
48
51
54
58
59
62
65
68
73
79
2.0
2.0
80
<0.03
METHOD
ASTM D-4052
ASTM D-4052
Calculation
ASTM D-323
ASTM D-4294
ASTM D-2699
ASTM D-2700
ASTM D-86
Calculation
ICP-OES
11
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Amna Crude Oil

TABLE (8)
Yield and Inspection of Heavy Naphtha
70-175 0C
TBP Cut Points

Vol. % on Crude
Wt. % on Crude
Density@15C, g/ml
API gravity
Reid vapour pressure, psi
Characterization factor
Octane Number; Research method
Octane Number; Motor method
Distillation,
IBP C
5%
10%
20%
30%
40%
50%
60%
70%
80%
90%
95%
FBP
Residue % vol.
Loss% vol.
Molecular weight
Lead content, ppm
16.61
14.65
0.7355
0.7362
60.7
2.39
126.6
0.021
12.2
42.6
40.8
76
100
105
110
115
120
125
131
137
144
151
156
161
1.0
1.0
114.5
<0.03
METHOD
ASTM D-4052
Calculation
Calculation
ASTM D-323
Calculation
ASTM D-4294
UOP 375
ASTM D-2699
ASTM D-2700
ASTM D-86
Calculation
ICP-OES
12
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Amna Crude Oil

TABLE (9)
Yield and Inspection of Kerosene Cut
TBP Cut Points
Vol. % on Crude
Wt. % on Crude
Density15 C, g/ml
API gravity
Volume Average Boiling Point, (VABP) , C
Sulphur content. wt.%
Aniline point, C
Aromatic, vol.%
Paraffins+ Naphathenes, vol.%
Olefins, vol.%
K. Viscosity at -20 C, cSt
K. Viscosity at 37.8 C, cSt
K. Viscosity at 50 C, cSt
Flash point Tag, C
Freezing point , C
Cold filter plugging point, C
Pour point, , C
Saybolt colour
Copper corrosion
Molecular weight
Smoke point, mm
175-2350C
METHOD
9.94
9.41
0.7921
0.7929
47
11.9
198.4
0.044
65.4
8.20
90.7
1.10
4.3368
1.3909
63
-47
<-20
<-36
+30
1
157.5
25
ASTM D-4052
Calculation
Calculation
UOP 375
Calculation
ASTM D-4294
ASTM D-611
ASTM D-1319
ASTM D-1319
ASTM D-1319
ASTM D-445
Calculation
Calculation
ASTM D-56
ASTM D-2386
IP 309
ASTM D-97
ASTM D-156
ASTM D-130
Calculation
ASTM D-1322
13
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Amna Crude Oil

Continued Table-9
175-2350C
TBP Cut Points
METHOD
Distillation,
IBP
5%
10%
20%
30%
40%
50%
60%
70%
80%
90%
95%
FBP
Residue % vol.
Loss % vol.
180
186
188
190
192
194
197
200
203
206
212
216
228
1.0
1.0
ASTM D-86
14
DAP-PL-4086.00

Amna Crude Oil

TABLE (10)
Yield and Inspection of Atmospheric Gas Oil Cut
235-350 0C
TBP Cut Points

Vol. % on Crude
Wt.% on Crude
Density15 C, g/ml
API gravity
Characterization factor
Aniline point, C
K. Viscosity at 50 C , cSt
Pour point, C
Molecular weight
Calculated cetane index
Distillation, C
IBP
5%
10%
20%
30%
40%
50%
60%
70%
80%
90%
95%
FBP
Residue % vol.
Loss% vol.
20.35
20.07
0.8259
0.8266
39.7
12.1
281.2
0.079
81.8
3.3665
2.6359
-3
220.2
57.5
244
251
259
264
270
274
278
284
290
300
309
319
327
1.0
Nil
METHOD
ASTM D-4052
Calculation
Calculation
UOP 375
Calculation
ASTM D-4294
ASTM D-611
ASTM D-445
ASTM D-445
(ASTM D-97)
Calculation
ASTM D-976
ASTM D-86
15
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Amna Crude Oil
Continued Table-10
TBP Cut Points

Vanadium, ppm
Nickel, ppm
Calcium, ppm
Potassium, ppm
Sodium, ppm
235-3500C
METHOD
<0.005
<0.010
0.368
1.239
<0.040
ASTM D 5708
ASTM D 5708
Dry ashing
Dry ashing
Dry ashing
16
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Amna Crude Oil

TABLE (11)
Yield and Inspection of Vacuum Gas Oil Cut
350-5500C
Boiling Range
Vol. % on Crude
Wt. % on Crude
Density15 C, g/ml
API gravity
Aniline point, C
Pour point, C
Molecular weight
Distillation, C
IBP
5%
10%
20%
30%
40%
50%
60%
70%
80%
90%
95%
FBP
Residue % vol.
Loss% vol.
Vanadium, ppm
Nickel, ppm
Calcium, ppm
Potassium, ppm
Sodium, ppm
METHOD
25.85
26.78
0.8733
0.8742
30.4
12.4
435
0.127
100.0
-
20.2890
5.3105
+39
403
361
377
ASTM D-4052
Calculation
Calculation
UOP 375
Calculation
ASTM D-4294
ASTM D-611
ASTM D-445
ASTM D-445
ASTM D-445
(ASTM D-97)
Calculation
380
392
406
419
437
454
ASTM D-1160
463
481
488
511
535
1.0
Nil
<0.005
<0.010
0.492
0.105
1.256
ASTM D 5708
ASTM D 5708
Dry ashing
Dry ashing
Dry ashing
17
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Amna Crude Oil
TABLE (12)
Atmospheric Residue 350+ 0C
Boiling Range
350+ 0C
METHOD
Vol. % on Crude
Wt.% on Crude
Density@ 15 C, g/ml
Specific gravity@60/60 F
API gravity
Asphaltenes content, wt. %
n-Heptane Insolubles, wt. %
Pour point, C
K. Viscosity @ 37.8 C, cSt
K. Viscosity @ 50 C, cSt
K. Viscosity @100 C, cSt
Ash content ,wt.%
Calorific value, MJ/Kg gross
Calorific value, Kcal/Kg gross
Vanadium, ppm
Nickel, ppm
Calcium, ppm
Potassium, ppm
Sodium, ppm
46.98
51.22
0.9214
0.9221
22
0.30
0.11
0.177
+42
28.114
0.007
6.92
44.5
10614
0.502
5.853
2.386
0.381
4.565
ASTM D-4052
Calculation
Calculation
IP 143
ASTM D893
ASTM D-4294
ASTM D-97
ASTM D-445
ASTM D-445
ASTM D-445
ASTM D-482
ASTM D-189
Calculation
Calculation
ASTM D 5708
ASTM D 5708
Dry ashing
Dry ashing
Dry ashing
18
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Amna Crude Oil
TABLE (13)
Vacuum Residue 550+ 0C
Boiling Range
550+ 0C
Vol. % on Crude
Wt. % on Crude
Density@ 15 C, g/ml
Specific gravity@60/60 F
API gravity
Asphaltenes content wt. %
n-Heptane Insolubles, wt. %
Sulphur content , wt. %
Pour point, C
Ash content ,wt.%
Calorific value, MJ/Kg gross
Calorific value, Kcal/Kg gross
Vanadium, ppm
Nickel, ppm
Calcium, ppm
Potassium, ppm
Sodium, ppm
21.25
24.44
0.9659
0.9665
14.9
0.30
0.11
0.238
+45
398.902
0.016
14.4
43.7
10438
1.496
13.908
3.359
0.751
5.046
METHOD
ASTM D-4052
Calculation
Calculation
IP 143
ASTM D893
ASTM D-4294
ASTM D-97
ASTM D-445
ASTM D-445
ASTM D-482
ASTM D-189
Calculation
Calculation
ASTM D 5708
ASTM D 5708
Dry ashing
Dry ashing
Dry ashing
19
DAP-PL-4086.00

Amna Crude Oil
Appendix
TBP Curve
80.00
Accumulative wt.%
70.00
60.00
50.00
40.00
30.00
20.00
10.00
0.00
0
50
100
150
200
250
300
350
400
450
500
550
600
Tempreture,C
Fig.1 TBP versus accumulative yield (wt. %) on crude
20

Amna Crude Oil

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National Oil Corporation

Libyan Petroleum Institute

Crude oil assay

Work Order No. LPI- 00344/11/IL02/2008

Date of Issue: Nov., 2008

Amna Crude Oil

Evaluation of Amna Crude Oil

Crude oil General Tests

Yield and Inspection of Heavy Naphtha

Amna Crude Oil

Amna Crude Oil

Amna Crude Oil

Amna Crude Oil

Vol.% Mol.% Compounds

Amna Crude Oil

Vol.% Mol.% Compounds

Wt% Vol.% Mol.%

Amna Crude Oil

Amna Crude Oil

Amna Crude Oil

Amna Crude Oil

Amna Crude Oil

TBP Cut Points

Amna Crude Oil

TBP Cut Points

Amna Crude Oil

Amna Crude Oil

TBP Cut Points

Amna Crude Oil

TBP Cut Points

Amna Crude Oil

TBP Cut Points

Amna Crude Oil

Amna Crude Oil

Amna Crude Oil

Amna Crude Oil

Fig.1 TBP versus accumulative yield (wt. %) on crude

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