KENDRIYA VIDYALAYA SANGATHAN, CHENNAI-36 SUBJECT: CHEMISTRY CLASS XII MAX.MARKS :70 INSTRUCTIONS Answer all questions.

ions. Questions 1 to 8 carry one mark each. Questions 9 to 18 are short answer questions.and carry two mark each. Questions 19 to 27 are also short answer questions and carry three marks each. Questions 28 to 30 are long answer questions and carry five marks each. TIME:3HRS

1. Why NaCl crystals ar in yellow colour, when heated in an atmosphere of sodium vapour? 2. Analysis shows that nickel oxide has the formula Ni0.98O1.00.What fractions of nickel exist as Ni+2and Ni+3ions? 3. What is the half life of a first order reaction from their rate constant is 2min-1? 4. From the graph

Write the relation between slope and rate constant ? 5.Why Cr and Al do not dissolve in Con HNO3 ? 6.What are enzymes? 7. write the IUPAC name of the following compound? CH3 CHO

8.Write the major organic product in following equation. (CH3)3CBr + KOH ethanol + heat ?

9. (i) Atoms of element B from hcp lattice and those of the element A occupy 2/3 rd of tetra hedral voids.What is the formuls of the compound formed by the element A and B? (ii) What is the anti ferromagnetic material? 10.What effect of molar conductivity of strong and weak electrolytes on dilution? 11.(i)What are physical state of dispersed phase and dispersion medium of emulsion? (ii)What is the change on the sol formed when KI is added to excess of AgNO3? 12.What is coagulation ? Write any two coagulation methods 13.Bond angle in PH4+is higher than that in PH3. Why? 14.Complete the following reaction (i) Ca3P2 + H2O (ii) 3 Cl2 + 6NaOH 15.Carry out the following conversions. (i) formaldehyde to methanol (ii) propane to propane -1-ol 16. Explain following named reactions (i) Riemer Tiemann reaction (ii) Williamson synthesis 17. Write the basic increasing order of following AminesNH3, CH3CH2NH2, CH3NHCH3, (CH3)3N,

18. Complete the following reactions

19.(i)Glucose or sucrose are soluble in water but cyclohexane or benzene are insoluble in water.Explain (ii)write the zwitter ion structure of amino acids. (iii)Why cannot vitamin C stored in our body? 20. Write the monomers of following polymers (i)Bakelite (ii) Glyptal (iii) PVC

21. Write about food preservents. 22. (i) Can you store copper sulphate solutions in a zinc pot? Justify your answer. (ii) The standard electrode potential for Daniell cell is 1.1 V. Calculate the standard Gibbs energy for the reaction 23. The following results have been obtained during the kinetic studies of the reaction

[A]/mol L-1 Experiment

[B]/mol L-1

Initial rate of formation of [D]/mol L-1 6.0 10-3 7.2 10-2 2.88 10-1 2.40 10-2

I II III IV

0.1 0.3 0.3 0.4

0.1 0.2 0.4 0.1

24. Why is the reduction of a metal oxide easier if the metal formed is in liqui9d state at the temperature of reduction? 25. (i) What is the Basicity of H4P2O7? (ii) Elemnts of Group 16 generally show lower value of first I.P compared to the corresponding periods group 15.Why? (iii) Why is H2O is liquid and H2S a gas at room temperature? 26. (i) [NiCl4]2- is paramagnetic while [Ni(CO)4] is diamagnetic though both are tetrahedral.Why? (ii) Write the IUPAC names of [Co(NH3)6]Cl3, [Cr(NH3)6C l3].

27.Draw the major product in following equations.

28. (i) write the B.P order of following aqueous solutions 0.5M NaCl ,0.5M NH2CONH2, 0.5M CH3COOH, 0.5M K2Cr2O7 (ii)The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectively at 350K . Find out the composition of the liquid mixture if total vapour pressure is 600 mmof Hg. Also find the composition of the vapour phase. (OR) (i)What role does the molecular interaction play in a solution of alcohol and water? (ii) 2g of benzoic acid dissolved in 25g of benzene shows a depression in freezing point equal to 1.62K.Molal depression constant for benzene is 4.9K.Kg.mol-1. What is the percentage association of acid if it forms dimer in solution? 29.An element A exists as a yellow solid in standard state. It forms a volatile hydride B ,which is a foul smelling gas and is extensively used in qualitative analysis of salts. When treated with oxygen,B forms an oxide C which is a colourless, pungent smelling gas. This gas when passed through acidificKMnO4 solution decolourless it. Cgets oxidized to another oxide D in the presence of a heterogeneous catalyst. Identify A,B,C,D and also give the corresponding chemical equations. (OR) (i) Complete the following reactions. (a) XeF4 + PF5 (b) U + 3ClF3

(ii) Give the structures of pyrophosphoric acid, peroxy disulphuric acid and XeO3

30.Identify Ato E and write the reactions involved.