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  • CHE111P Gas Mixtures

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    Paolo Gochingco
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     DALTON’S LAW OF PARTIAL PRESSURE  T and V are constant  Pressure fraction = mole fraction  PT = PA + PB + PC +…….  AMAGAT’S LAW OF PARTIAL VOLUME  T and P are constant  Volume fraction = mole fraction  VT = VA + VB +VC +……  GIVEN: GAS MIXTURE CH7 C2H6 C3H8 COMPOSITION 87% 12% 1%  REQUIRED:     %comp. in wt. %comp. in vol. V(m3) if m=80 kg, T = 90C, P = 600kPa Density at STP (kg/m3)  CONDENSABLE GAS  Vapor, liquid at room temperature  NONCONDENSABLE GAS  Gas, gas

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     DALTON’S LAW OF PARTIAL PRESSURE  T and V are constant  Pressure fraction = mole fraction  PT = PA + PB + PC +…….  AMAGAT’S LAW OF PARTIAL VOLUME  T and P are constant  Volume fraction = mole fraction  VT = VA + VB +VC +……  GIVEN: GAS MIXTURE CH7 C2H6 C3H8 COMPOSITION 87% 12% 1%  REQUIRED:     %comp. in wt. %comp. in vol. V(m3) if m=80 kg, T = 90C, P = 600kPa Density at STP (kg/m3)  CONDENSABLE GAS  Vapor, liquid at room temperature  NONCONDENSABLE GAS  Gas, gas

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    116 views20 pages

    CHE111P Gas Mixtures

    Uploaded by

    Paolo Gochingco
     DALTON’S LAW OF PARTIAL PRESSURE  T and V are constant  Pressure fraction = mole fraction  PT = PA + PB + PC +…….  AMAGAT’S LAW OF PARTIAL VOLUME  T and P are constant  Volume fraction = mole fraction  VT = VA + VB +VC +……  GIVEN: GAS MIXTURE CH7 C2H6 C3H8 COMPOSITION 87% 12% 1%  REQUIRED:     %comp. in wt. %comp. in vol. V(m3) if m=80 kg, T = 90C, P = 600kPa Density at STP (kg/m3)  CONDENSABLE GAS  Vapor, liquid at room temperature  NONCONDENSABLE GAS  Gas, gas

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    DALTONS LAW OF PARTIAL PRESSURE

    T and V are constant Pressure fraction = mole fraction PT = PA + PB + PC +.

    AMAGATS LAW OF PARTIAL VOLUME


    T and P are constant Volume fraction = mole fraction VT = VA + VB +VC +

    GIVEN:
    GAS MIXTURE CH7 C2H6 C3H8 COMPOSITION 87% 12% 1%

    REQUIRED:

    %comp. in wt. %comp. in vol. V(m3) if m=80 kg, T = 90C, P = 600kPa Density at STP (kg/m3)

    CONDENSABLE GAS
    Vapor, liquid at room temperature

    NONCONDENSABLE GAS
    Gas, gases at room temperature

    SATURATION (PP = PV)


    Partial pressure of the vapor is equal to the vapor

    pressure at specified temperature.

    UNSATURATION (PP < PV)


    Partial pressure of the vapor is less than the vapor

    pressure at specified temperature

    DEW POINT
    Temperature at which the vapor starts to

    condense Example: dew point = 300C [H2O] PH2O = PVH2O at 300C Vapor pressure calculation (Antoine Equation) ln(p) = A B/C + T

    RELATIVE SATURATION (RS)


    Defined as the partial pressure of the vapor

    divided by the vapor pressure of the vapor at the temperature of the gas.

    MOLAL SATURATION (Sm)


    The ratio of the moles of vapor to the moles of

    vapor-free gas

    ABSOLUTE SATURATION (Sabs)


    Weight of vapor per weight vapor-free gas

    PERCENTAGE SATURATION (%S)

    If a gas at 600C and 101.6 kPa, has a molal humidity of 0.030, determine:
    the relative humidity
    the dew point of the gas (in 0C)

    PV @ 600C = 148.29 mmHg

    Given:
    RH = 85% PV @ 900F = 35.64mmHg T = 90 0F PT = 14.696 psia= 760 mmHg Required: a) Hm b) Habs c) Saturation temperature

    Transformation of a liquid into a vapor in a non-condensable gas.

    ENTERING, E
    Dry gas or Dry gas, water vapor

    LEAVING, L (dry gas, water vapor)

    VAPOR, V

    Change of a vapor in a non-condensable gas to liquid.


    ENTERING, E LEAVING, L (dry gas, water vapor) saturated

    Dry gas, water vapor

    CONDENSATE, C

    E, AIR CONDENSER V=30 m T= 1000C P=98.6kPa Dew pt. = 300C T=140C P = 101.9 Kpa C

    P @ 300C = 31.38 mmHg = 4.18kPa P @ 140C = 11.7 mmHg = 1.56kPa Unknown = fraction H2O condensed

    E, dry air

    L VAPORIZER T=200C P=100kPa Pv eth. Alc=5.76 kPa

    T=200C P=100kPa

    V=6.0 kg eth. Alc

    Unknown = VE

    18.10 18.11

    Dried material

    E Gas or Gas vapor Wet material

    Gas vapor

    Gas mixture L

    Absorbing medium(solvent/soln) F

    Gas mixture

    Leaving solution

    An absorber receives a mixture of air containing 12 percent carbon disulfide. The absorbing solution is benzene and the gas exits from the absorber with a CS2 content of 3 percent and a benzene content of 3 percent (because some of the benzene evaporates). What fraction of CS2 was recovered?

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