Professional Documents
Culture Documents
J.Chandra Babu
Environmental Engineer, HWM Division Central Pollution Control Board (Ministry of Environment & Forests) Parivesh Bhavan, East Arjun Nagar, Delhi - 110 032 (INDIA) E-mail : jcb.cpcb@nic.in Website : http://www.cpcb.nic.in
AREA SOURCES
fugitive dust VOCs landfill gas odours
LINE SOURCES
fugitive dust vehicle exhaust spills
UPTAKE
inhalation Dermal contact
Waste Dump Combustion facility / Industry Leachate (Ground Water Contamination movement) Traffic UPTAKE plants animals produce Lake fish Dermal contact Drinking water
Emissions to atmosphere from various types of human activities and uptake of contaminants from the environment
Waste falling in any of the categories prescribed in the Hazardous Waste (Management & Handling) Rules, 1989. 18 categories of wastes and regulatory quantities specified.
Example : Waste containing : Waste containing : Waste containing : Waste containing : Waste containing : CN Hg/As Halogenated HC Pesticide residue Pb/Cu/Cr/Ni (1 Kg/yr), (5 Kg/yr), (50 kg/yr), (5 kg/yr), (10 kg/yr) etc.
Hazardous Waste ( M & H ) Amendment Rules 2003: 36 processes with waste category listed under Schedule-1 5 Classes of waste substances with regulatory limit - Schedule-2 14 Characteristics (for import & export of HW)Sch.-3 (Part B) Hazardous Waste (M, H & TM) Rules, 2008: Same as that of the HW ( M & H ) Rules, 2003 with more clarity comprising 07 Chapters as follows: Chapter 1: Preliminary Chapter II: Procedures for handling hazardous wastes Chapter III: Procedure for recycling, reprocessing or reuse of HW Chapter IV: Procedure for import or export of hazardous waste Chapter V: Treatment, Storage and Disposal Facilities for HW Chapter VI: Packaging, Labeling and Transportation of HW Chapter VII: Miscellaneous
CHAPTER I RULE 2: APPLICATION: The HW (M, H and T) Rules, 2008 shall not apply to
Waste-water and exhaust gases as covered under the Water Act, 1974 and the Air Act, 1981and the rules made there under Wastes arising out of the operation from ships beyond five kilometers of the relevant baseline as covered under the provision of the Merchant Shipping Act, 1958 and the rules made there under Radio active wastes as covered under the provision of the Atomic Energy Act,1962 and the rules made there under Bio medical wastes covered under the Bio-Medical Wastes (Management and Handling) Rules,1998 made under the Act Waste covered under the Municipal Solid Wastes (Management and Handling) Rules,2000 made under the Act
Important Definitions : As per Rule 3 (l) of the HW ( M, H & TM) Rules, 2008:
Authorization :- permission for generation, handling, collection, reception, treatment, transport, storage, recycling, reprocessing, recovery, reuse and disposal of hazardous wastes granted under subrule(4) of rule 5. Disposal:- any operation which does not lead to recycling, recovery or reuse and includes physico-chemical, biological treatment, incineration and disposal in secured landfill. Environmentally Sound Management of Hazardous Waste:- taking all steps required to ensure that the hazardous wastes are managed in a manner which shall protect health and the environment against the adverse effects which may result from such waste. Facility :- any establishment wherein the processes incidental to the handling, collection, reception, treatment, storage, recycling, recovery, reuse and disposal of hazardous wastes are carried out.
c).
Transport : means off site movement of hazardous wastes by air, rail, road or water Treatment: a method, technique or process, designed to modify the physical, chemical or biological characteristics or composition of any hazardous waste so as to reduce its potential to cause harm Used oil:- means any oil a). any oil derived from crude oil or mixtures containing synthetic oil including used engine oil, gear oil, hydraulic oil, turbine oil, compressor oil, industrial gear oil, heat transfer oil, transformer oil, spent oil and their tank bottom sludges. b). suitable for reprocessing, if it meets the specification laid down in Part-A of Schedule-V but does not include waste oil Waste oil:- any oil which includes spills of crude oil, emulsions, tank bottom sludge and slop oil generated from petroleum refineries, installations or ships & used as fuel in furnaces for energy recovery, if it meets the specifications laid down in Part-B of Schedule-5 either as such or after reprocessing.
CHAPTER II: PROCDURE FOR HANDLING HAZARDOUS WASTE Rule 4: Responsibility of the Occupier (and Operator of the Facility) for handling of Hazardous Waste : The occupier shall be responsible: 1). for safe and environmentally sound handling of all HW generated in his establishment
2). Wastes generated shall be sent/sold to a registered and/or authorized recycler/reprocessor/reuser or shall be disposed of in an authorized disposal facility. All hazardous wastes transported shall be as per provisions shall give to the operator of a facility, adequate information as may be determined by the SPCB/PCC. The occupier shall take adequate steps while handling HW to: (i) contain contaminants and prevent accidents and limit their consequences on humans and the environment; and (ii) provide persons working on the site with information, training and equipment necessary to ensure their safety.
Rule 5:
(1). Every person who is engaged in generation, processing, treatment, package, storage, transportation, use, collection, destruction, conversion, offering for sale , transfer or the like of the HW shall require to obtain Authorization from the SPCB/PCC. (2). HW shall be collected, treated, re-cycled, re-processed, stored and disposed of only in such facilities as may be authorized by the SPCB; (3). Every person engaged in generation, processing, treatment, package, storage, transportation, use, collection, destruction, conversion, offering for sale, transfer or the like of the hazardous waste or occupier of the facility shall make an application in Form 1 to the SPCB;
Rule 6:
1). The SPCB/PCC may, if in its opinion the holder of the authorization has failed to comply with any of the conditions of the authorisation or with any provision of the Act or these Rules and after giving him a reasonable opportunity of being heard and after recording reasons thereof in writing cancel or suspend the authorisation issued under Rule 4 for such period as it considers necessary in the public interest. 2). Upon suspension or cancellation of the authorization, the SPCB may give directions to the person whose authorisation has been suspended or cancelled for the safe storage of the HW, and such person shall comply with such directions.
CHAPTER III :PROCEDURE FOR RECYCLING , REPROCESSING OR REUSE OF HW: Rule 8: Procedure or grant of registration:
(1) Every person desirous of recycling or reprocessing hazardous waste listed in Schedule-IV may make an application in Form-5 accompanied with a copy each of the following documents for the grant or renewal of registration:(a). (b). (c). (d). Consent to establish under Water Act, 1974 & Air Act,1981; Certificate of registration: District Industries Centre or any other authorised Government Agency Proof of installed capacity of the plant and machinery In case of renewal, certificate of compliance, from the SPCB or PCC or the Concerned Zonal Office of CPCB.
(2) The CPCB, on being satisfied may grant registration to such applicants stipulating therein necessary conditions for carrying out safe operations in the authorized place only.
(3) CPCB shall dispose of the application for registration within a period of 120 days of the receipt of such application complete in all respect; (4) The registration issued under sub rule 2 shall be valid for a period of five years from the date of its issue, unless the operation is discontinued by the unit or the registration is suspended or cancelled by the CPCB; (5) CPCB may cancel or suspend the registration granted , if the recycler has failed to comply with any of the conditions of the registration, or with any provisions of the Act or Rules made there under; (6) CPCB may after giving reasonable opportunity of being heard to the . applicant, by order, refuse to grant or renew the registration (7) The recycler or re-processor shall maintain records of hazardous wastes purchased and processed and shall file an annual return of its activities of previous year in Form 6 to the SPCB on or before the 30 th day of June of every year.
Rule 9: Conditions for Sale or Transfer of hazardous wastes for recycling: The occupier generating hazardous wastes listed in Schedule IV may sell it only to the recycler having a valid registration from the CPCB or any other agency designated by MoEF for recycling or recovery. Rule 10: Standards for recycling: The Central Government and CPCB may issue the guidelines for standards of performance for recycling processes from time to - time. Rule 11: Utilization of Hazardous Wastes: Utilization of hazardous wastes as a supplementary resource or for energy recovery or after processing shall be carried out by the units only after obtaining approval from CPCB.
Rule 14:
(1) (2)
Import and export of all the hazardous wastes listed in Schedule III shall be regulated unless otherwise stated in the said schedule. Subject to the provisions contained in Sub-rule (1): (i). The import or export of the Hazardous waste specified in Part A of Schedule III shall require Prior Informed Consent of the country from where it is imported or exported to and shall require the license from the DGFT and the prior written permission of the Central Government. The import of hazardous wastes listed in Part B of the Schedule III shall not require Prior Informed Consent (PIC) of the country from where it is imported; The import and export of the hazardous wastes not Part A and Part B of the Schedule III, but having the hazardous characteristics outlined in Part C of the said Schedule shall require the prior written permission of the Central Government, before it is imported into or exported from India, as the case may be.
(ii)
(iii).
4). The exporter shall ensure that no consignment is shipped before the No Objection Certificate is received from the importing Country. 5). The Exporter shall also ensure that the shipment is accompanied with the Movement Document in Form 9. 6). The exporter shall inform the Ministry of Environment and Forest upon completion of the transboundary movement. 7). The exporter of hazardous waste shall maintain the records of hazardous waste exported by him in Form 10 and the record so maintained shall be available for inspection.
(ii) adequate facilities and arrangement for treatment and disposal of wastes generated; and iii) a valid registration from CPCB and a proof of being an actual user, if required under these Rules. (3) The MoEF shall forward a copy of the permission granted under subrule (2) to the CPCB, the concerned SPCB, and the concerned Port and Customs authorities for ensuring compliance of the conditions of imports and safe handling of the hazardous waste. (4) The MoEF shall communicate the permission to the importer. (5) The Port and Custom authorities shall ensure that shipment is accompanied by the Movement Document in Form 9 and the test report of analysis of the hazardous waste consignment in question, from a laboratory accredited by the exporting country.
(6) The Custom authority shall collect three randomly drawn samples of the consignment (prior to clearing the consignment as per the provisions laid down under the Customs Act, 1962) for analysis and retain the report for a period of two years, in order to ensure that in the event of any dispute, as to whether the consignment conforms or not to the declaration made in the notification and Movement Document. (7) The importer of hazardous waste shall maintain the records of hazardous waste imported by him in Form 10 and the record so maintained shall be available for inspection. 8). The importer shall also inform the concerned SPCB and CPCB, the date and time of the arrival of the consignment of hazardous waste ten days in advance.
(2) In case of illegal import of the hazardous wastes, the importer shall re e port the waste in question at his cost within a - x period of ninety days by the concerned SPCB.
(2). The operator of a common facility or occupier of a captive facility shall design and set up TSDF as per the technical guidelines issued by CPCB from time to time and shall obtain approval from SPCB for designs & layout in this regard from time to time. (3). The SPCB shall monitor the setting up and operation of the TSDF regularly. (4). The operator of TSDF shall be responsible for safe and environmentally sound operation of the TSDF and its closure and post closure phase, as per the guidelines issued by CPCB from time to time. (5). The Operator of TSDF shall maintain records of HW handled by him in Form 03.
6)
Public parks
7) 8) 9)
: : :
Reserved forests etc., within wetlands within a notified zone around airports within 500 m within CRZ < 2 m below the GL as suggested by SPCB /PCC as per local conditions
10) Water Supply Well 11) Coastal Regulation Zone 12) Ground Water Table 13) Other criteria
: : : :
Landfill Liner and Cover Criteria: Liner Criteria: Base of the liner system shall be at least 2 m above the highest anticipated ground water table levels. Single or Double Liner based on depth of GWT: within 2 to 6 m beneath the base of landfill
Specifications of Geomembrane: Tensile Strength at Yield Tensile Strength at Break Tear Resistance Puncture Resistance > 18 KN/m > 30 KN/m > 150 N and > 25O N
Hazardous Waste
Leachate collection K 10-2 cm/sec
30 cm
150 cm
Sub Soil
3m
Note: At locations where clay availability is limited, amended soil will be constituted by mixing bentonite or any other suitable clay to locally available soil to achieve the desired permeability
1.5 mm HDPE Geomembrane Primary Composite liner 1.5 mm HDPE Geomembrane Secondary Composite liner
Hazardous Waste
Primary Leachate collection K 10 2 cm/sec Compacted clay/compacted amended soil K 10 7 cm/sec Secondary leachate collection/leak detection K 10 3 cm/sec Compacted clay/compacted amended soil K 10 7 cm/sec
30 cm 45 cm
30 cm 45 cm
Sub Soil
Vegetation
Top soil
60 cm
30 cm 60 cm
Regulatory (optional)
30 cm
Hazardous Waste
Cover System
(2)
CHAPTER VI Contd..
(2)
(3).
(4).
CHAPTER VI Contd..
Rule 21: Manifest System ( Movement Document to be used within the Country only): (1) The occupier shall prepare six copies of the manifest in Form 13 comprising of colour code indicated below and all six copies shall be signed by the transporter:
Purpose To be forwarded by the occupier to the SPCB To be retained by the occupier after taking signature on it from the transporter and the rest of the four copies to be carried by the transporter To be retained by the operator of the facility after signature To be returned to the transporter by the operator of facility after accepting waste To be returned by the operator of the facility to SPCB/PCC after treatment and disposal of wastes. To be returned by the operator of the facility to the occupier after treatment and disposal of wastes
Copy number with Colour Code Copy 1 (White) Copy 2 (Yellow) Copy 3 (Pink) Copy 4 (Orange) Copy 5 (Green) Copy 6 (Blue)
Manifest System
Form 13
Regulatory Authority (SPCB)
1w 2Y
6B 4O 3P
3, 4, 5 & 6 3, 4, 5 & 6 Copies of Manifest
5G
HW Generator (Occupier)
Copies of Manifest
Transporter
TSDF Operator
Manifest system contd. (2). The occupier shall forward copy 1 (white) to the SPCB, and in case the hazardous wastes is ikely to be transported through any transit State, the occupier shall prepare an additional copy each for intimation to such State and forward the same to the concerned SPCB before he hands over the hazardous wastes to the transporter. No transporter shall accept hazardous wastes from an occupier for transport unless it is accompanied by copies 3 to 6 of the manifest. The transporter shall submit copies 3 to 6 of the manifest duly signed with date to the operator of facility along with the waste consignment. Operator of facility upon completion of treatment and disposal operations of the hazardous wastes shall forward copy 5 (green) to the SPCB and copy 6 (blue) to the occupier and the Copy 3 (pink) shall be retained by the operator of the facility.
(3)
(4)
(5)
(2).
(3).
Rule 25: Liability of the Occupier, Transporter & Operator of a Facility and Importer:
1) The occupier, transporter and Operator of a Facility
shall be liable for all damages caused to the environment or third party due to improper handling of the hazardous waste or disposal of the HW. (2) The occupier and the operator of the facility shall be liable to pay financial penalties as levied for any violation of the provisions under these rules by the SPCB/PCC with the prior approval from CPCB.
SCHEDULE I
36 industrial processes with hazardous waste generating streams as listed under Schedule-1
S.No 1 Processes Petrochemical Processes and Pyrolytic Operations . HW Treatment Processes e.g Incineration, distillation, separation and concentration techniques Hazardous Waste 1.1 Furnace and reactor residue and debris 36.1. Sludge from wet scrubbers
36
SCHEDULE II
50 mg/kg 5000 mg/kg 20,000 mg/kg 50,000 mg/kg Characteristics
Schedule IV [See Rule 8 (1) and 9 List of Wastes requiring Registration for Recycling/Reprocessing
Waste Category (1) (2) (3) (4) (5) (6) (7) (8) (9) (10) (11) (12)
Brass Dross; Copper Dross Copper Oxide Mill Scale Copper Reverts, Cake & Residue
Wastes
Waste Copper and Copper Alloys Slags from copper processing for further processing or refining Slags from copper processing for further processing or refining Jelly filled Copper Cables Spent cleared metal catalyst containing copper Spent catalyst containing nickel, cadmium, zinc, copper, arsenic, vanadium and cobalt Zinc Dross-Hot dip Galvanizers SLAB Zinc Dross Bottom Dross
Schedule 4 contd
(13) (14) (15) (16) (17) (18) Zinc ash/skimming arising from galvanizing and die casting operations Zinc ash/skimming/other zinc bearing wastes arising from smelting and refining Zinc ash and residues including zinc alloy residues in dispersible form Spent cleared metal catalyst containing zinc Lead acid battery plates and other lead scrap/ashes/residues not covered under Batteries (Management & Handling) Rules, 2001. Components of waste electrical and electronic assembles comprising accumulators and other batteries included on list A, mercury-switches, activated glass cullets from cathode-ray tubes and other activated glass and PCB-capacitors, or any other component contaminated with Schedule 2 constituents (e.g. cadmium, mercury, lead, polychlorinated biphenyl) to an extent that they exhibit hazard characteristics indicated in part C of this Schedule. Paint and Ink sludges/residue Used Oil and Waste Oil As per specifications prescribed from time to time
(19) (20)
Schedule V ( Part A) [See Rule 3 (ze), and (zf) ] Specifications for Used Oil suitable for Reprocessing/Recycling
S.No. (1) 1 2 3 4 5 Parameter (2) Polychlorinated biphenyls (PCBs) Lead Arsenic Cadmium + Chromium+ Nickel Polyaromatic hydrocarbons (PAH) Max. Permissible Limits (3) < 2 ppm * 100 ppm 5 ppm 500 ppm 6%
Note: The detection limit is 2 ppm by Gas Liquid Chromatography (GLC) using Electron Capture Detector ( ECD)
Schedule VII : List of Authorities and Corresponding Duties Ministry of Environment & Forests ( MoEF)
Identification of HW; Permission to exporters/importers, Permission for transit of HW through India Sponsoring of training and awareness programme on HWM related activities
List of Authorities and Corresponding Duties contd.. Central Pollution Control Board ( CPCB)
Co-ordination of activities of SPCBs/PCCs Conduct training courses Recommend standards and specifications for treatment and disposal of HW and leachate standards Sector specific documentation to identify wastes streams for inclusion in HW Rules; Prepare guidelines to prevent/transport/minimize generation and handling of hazardous wastes Registration and renewal of registration of recyclers/re- processors.
DGFT :
Grant of license for import of HW Refusal of license for HW prohibited for import or export
List of Forms
Form 1 : Application for obtaining authorization from SPCB Form 2 : Form for grant of authorization by SPCB/PCC Form 3 : Form for maintaining of records by the Occupier or TSDF Form 4 :Form for filing annual returns by the Occupier or Operator of facility Form 5 :Form for application for grant/renewal of registration of industrial units for possessing ESM facilities for reprocessing or recycling Form 6 :Form for filing annual returns and records on recyclable HW by the recycler Form 7 :Application for import or export of HW for reprocessing/recycling/reuse Form 8 &9:Application for Transboundary Movement of HW and Transboundary Movement Document Form 10: Format for maintaining records of HW imported and exported Form 11:Transport Emergency Card Form 12:Marking of Hazardous Waste Container Form 13:Hazardous Waste Manifest Form 14:Format of Accident Report Form 15:Application for filing appeal against the order passed by CPCB/SPCB /PCC of the Union Territory
Yes
It is Non- Hazardous
No
Is it from 36 processes listed in Schedule-I ?
Yes
It is Hazardous
No
Is it containing substances listed in Schedule-II above the conc. limits ?
Yes
It is Hazardous
No
Is it listed in Schedule-III Part-A, B & C
Yes
It is Hazardous
No
It is Non- Hazardous
Hazardous Waste Classification as per HW (M, H & TM) Rules, 2008: India
Than Q