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Dispersion coecient and settling velocity of the solids in agitated
slurry reactors stirred with multiple rushton turbines
M. Nocentini, D. Pinelli, F. Magelli
DICMA-Department of Chemical, Mining and Environmental Engineering, University of Bologna, Viale Risorgimento 2,
40136 Bologna, Italy
Received 8 October 2001; accepted 22 February 2002
Abstract
The feature of solids distribution in tanks stirred with multiple Rushton turbines was investigated. Both transient and steady-state
experiments were performed in tanks of two scales with a variety of suspensions. The data were analysed with the axial sedimentation
dispersion model. The axial dispersion coecient of the solid phase was found not to dier from that of the liquid by more than 20%.
The eective particle settling velocity in the stirred medium was then determined. It is conrmed that this parameter is dierent from the
terminal settling velocity. Their ratio exhibits the same dependence on Kolmogoro microscale and particle size as obtained previously
with an indirect, approximate approach. ? 2002 Elsevier Science Ltd. All rights reserved.
Keywords: Chemical reactors; Mixing; Multiple Rushton turbines; Multiphase ow; Particulate processes; Solids distribution
1. Introduction
The knowledge of the spatial solids distribution in solid
liquid, agitated reactors is important for proper equipment
design and reliable process operationespecially when
through-ow mode is adopted.
The solids distribution is the result of two main compet-
ing actions, namely particle lift due to its interaction with
liquid ow and turbulence and particle tendency to settle.
Several models have been proposed for calculating solids
non-homogeneity that incorporate particle settling veloc-
ity (or particle drag coecient) and one or more param-
eters for describing macro-mixing phenomena. They span
from the simple one-dimensional model with axial disper-
sion and sedimentation (e.g. Magelli, Fajner, Nocentini, &
Pasquali, 1990) to two-dimensional (Penaz, Rod, & Re-
hakova, 1978; Sysova, Fort, Vanek, & Kudrna, 1984; Ku-
drna, Sysova, & Fort, 1986; Schempp & Bohnet, 1995)
or multi-zone sedimentationdispersion models (Yamazaki,
Tojo, & Miyanami, 1986) and two- or three-dimensional
network-of-zones models (Brucato & Rizzuti, 1988; Bru-
cato, Magelli, Nocentini, & Rizzuti, 1991; McKee et al.,
1994). Computational uid dynamics tools have also started
n=1
(n)
2
cos{n(1 )} n(Pe
S
}2) sin{n(1 )}
[(Pe
S
}2)
2
+ (n)
2
] cos{n}
exp[ {(Pe
S
}2)
2
+ (n)
2
}0], (2)
where Pe
S
= U
S
H}D
eS
and 0 = tD
eS
}H
2
. It is worth noting
that at steady state (that is when 0 ), Eq. (2) reduces
to the simple dimensionless prole (Magelli et al., 1990)
C() = Pe
S
exp(Pe
S
)
exp(Pe
S
) 1
. (3)
3.2. Data treatment
Each experimental solid concentration curve obtained
from the transient experiments at every selected elevation
was normalised and compared with the theoretical one, Eq.
(2). The parameter D
eS
was then determined with a best-t
procedure. This calculation required that the value of Pe
S
0
20
40
60
80
0.0 2.0 4.0 6.0 8.0
concentration (g L
-1
)
e
l
e
v
a
t
i
o
n
(
c
m
)
Fig. 2. Example of a solids concentration prole obtained under
steadystate conditions in tank 1
23B
. Horizontal lines: () turbine
location; (- - - - -) vertical elevation for the transients experiments. Pro-
les: (symbols) experimental values; (line) best-t theoretical prole.
was available for the same experimental condition. Thus,
this last parameter was calculated by matching Eq. (3) to
the solid concentration prole obtained with the steady-state
measurements (Magelli et al., 1990).
As shown in previous work, the experimental vertical
proles are characterised by singularities in correspondence
with the turbines and midway between the turbines (Bar-
resi & Baldi, 1987; Magelli et al., 1990; Bilek & Rieger,
1990; Pinelli, Nocentini, & Magelli, 2001) provided that
the particles are not too small (Yamazaki et al., 1986). This
fact suggested to chose the elevations where to detect the
transient curves in such a way as to minimise the departure
between the experimental and the theoretical proles. One
example of an actual concentration prole is shown in Fig.
2, with the best t theoretical curve as well as the positions
of the turbines and of the selected heights for the transient
experiments.
4. Results and discussion
4.1. Generic remarks
Figs. 3ac show three pairs of transient curves obtained
at three dierent elevations for the same operating con-
dition. As is apparent, the curve shape depends markedly
on . And so does the asymptotic value C(, ). In all
cases, the agreement between the experimental and the
1880 M. Nocentini et al. / Chemical Engineering Science 57 (2002) 18771884
-0.5
0.5
1.5
2.5
3.5
4.5
-5 0 5 10 15 20 25
time (s)
n
o
r
m
a
l
i
s
e
d
c
o
n
c
.
(
-
)
experim. curve
best fit curve
-0.2
0.2
0.6
1.0
1.4
1.8
-5 0 5 10 15 20 25
time (s)
n
o
r
m
a
l
i
s
e
d
c
o
n
c
.
(
-
)
experim. curve
best fit curve
-0.5
0.5
1.5
2.5
3.5
4.5
-5 0 5 10 15 20 25
time (s)
n
o
r
m
a
l
i
s
e
d
c
o
n
c
.
(
-
)
experim. curve
best fit curve
(b)
(a)
(c)
Fig. 3. Comparison of experimental and theoretical dimensionless curves
for transient experiments at selected elevations in tank 1
23B
. d
=0.79 mm;
water; (a) = 0.14; (b) = 0.42; and (c) = 0.91.
theoretical curves was fairly good. In passing, this fact justi-
es the use of the simple uid dynamic model adopted in this
study.
Two further aspects are worth mentioning. The overshoot
exhibited at = 0.14 was always (slightly) higher for the
theoretical curve than for the experimental one: this seems
to depend on the way the solids are actually introduced into
the reactor (point injection) and on the non-innite value
of the radial dispersion mechanism and coecient. As re-
gards the choice of the measurement positions, apart from
the above-mentioned requirement that the real-steady-state
concentration does not deviate from the theoretical prole
signicantly, values close to 0.60.7 are to be avoided. In-
deed, at these elevations the curves feature a smoothed peak
that cannot be easily recognised in the experimental curve
due to data noise, thus making parameter evaluation rather
inaccurate. For this reason, the curves at these elevations
were not considered.
4.2. Axial dispersion coecient
The values of the axial dispersion coecient for the solid
phase, D
eS
, were determined as outlined before. They were
usually slightly lower at =0.14 than at =0.41 and 0.91,
0.00
0.10
0.20
1'000
Re
D
e
S
/
N
D
2
10'000 100'000 1'000'000
Fig. 4. Dimensionless axial dispersion coecients for glass particles at the
two scales: (, ) d
=0.33 mm; ( , ) d
=0.23 mm; (, 4) d
=0.13 mm; () d
=0.98 mm; () d
being
equal to that found in the past on the basis of simplifying
assumptions.
With the pair of the mentioned parameters, the solid
distribution in tanks of high aspect ratio and stirred with
multiple Rushton turbines can be estimated via the simple
sedimentationdispersion model. Although the extrapola-
tion of the correlation U
S
}U
t
vs. z}d
:=H
+ U
S
C
S
|
:=H
= 0, (A.2)
D
eS
dC
S
d:
:=0
+ U
S
C
S|:=0
= C
S, av
Ho(t). (A.3)
The L-transforms of Eq. (1) with the condition (A.1) and
the transforms of Eqs. (A.2) and (A.3) are
D
eS
d
2
G
d:
2
U
S
dG
d:
SG = 0, (A.4)
D
eS
dG
d:
:=H
U
S
G|
:=H
= 0, (A.5)
D
eS
dG
d:
:=0
U
S
G|
:=0
= C
S, av
H. (A.6)
The solution of Eq. (A.4) has the form
G = K
1
exp(z
1
:) + K
2
exp(z
2
:), (A.7)
where the characteristic roots are
z
1, 2
=
U
S
(U
2
S
+ 4D
eS
S)
2D
eS
=Pe}2
(Pe
2
}4 + H
2
S}D
eS
)
and the constants K
1
and K
2
can be specied by means of
the boundary conditions as
K
1
=C
S, av
H exp(z
2
H)}(U
S
D
eS
z
1
)
[exp(z
1
H) exp(z
2
H)],
K
2
=C
S, av
Hexp(z
1
H)}(U
S
D
eS
z
2
)
[exp(z
1
H) exp(z
2
H)].
M. Nocentini et al. / Chemical Engineering Science 57 (2002) 18771884 1883
By substitution of these expressions into Eq. (A.7), the trans-
formed concentration is obtained as follows:
G(:, S) =
C
S, av
H
exp(z
1
H) exp(z
2
H)
exp(z
1
H) exp(z
2
:)
U
S
D
eS
z
2
exp(z
2
H) exp(z
1
:)
U
S
D
eS
z
1
,
(A.8)
whence
G(:, S)
C
S, av
=
H exp(U
S
:}2D
eS
)[: cos{:(H :)} U
S
}2D
eS
sin{:(H :)}]
Ssin{:H}
(A.9)
with :
n
=
[ (U
S
}2D
eS
)
2
S
n
}D
eS
].
The poles of the denominator of (A.9) are
S
n
=U
2
S
}4D
eS
n
2
2
D
eS
}H
2
. (A.10)
Anti-transformation of Eq. (A.9) with the method of the
residues gives Eq. (2).
Notation
C
S
local volumetric solids concentration, ML
3
C =C
S
}C
S, av
, dimensionless local solids concen-
tration, dimensionless number
C
S, av
average volumetric solids concentration, ML
3
D turbine diameter, L
D
eL
dispersion coecient for the liquid, L
2
T
1
D
eS
dispersion coecient for the solids, L
2
T
1
d