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0 and concave away from the x-axis whenever
|V(x) ~ E| <0.
AS. Show that there is no degeneracy in the bound states for one-dimensional
motion.74 Chapter 3: Schrodinger Equation as Eigenvalue-figenfunction Equation
‘AG. Consider the Schrédinger equation for a complex potential
Yoo + h(x)
in which both V; and V; are real. Is the Hamiltonian hermitian? Follow
through the derivation of the continuity equation (see chapter 1) with this
potential and find the additional terms that appear when V3 + 0. Provide
a physical interpretation of the result. What possible use can you think of
for such complex potentials?
A7. In the infinite well potential, we set V+ o» at the walls and V = 0 inside.
Suppose, instead, that the potential inside V = C, where C is a constant.
Calculate the energy levels.
REFERENCES.
M. Chester. Primer of Quantum Mechanics.
Fayyazuddin and Riazuddin. Quantum Mechanics.
P. Fong. Elementary Quantum Mechanics.
8. Gasiorowicz. Quantum Physics.
A. Sudbery. Quantum Mechanics and the Particles of NatureThe Solution of the Schrodinger
Equation in One Dimension
Tn tais cnapter we will consider some simple one-dimensional potential models
for you to gain experience with the solution of the time-independent Schré-
ddinger equation. Although the real world is three dimensional, it turns out that
‘our models will often simulate the real world well enough to make their study
worthwhile.
The simplest potential models we choose also emphasize the difference be-
tween classical and quantum descriptions of the motion of objects. One poten-
tial model we will discuss is the so-called square potential: The potential is
constant everywhere except at the two points where it changes quite discontin-
ously from zero to a finite constant value. If we think in terms of forces, the
force goes to infinity at the points of discontinuity, and is zero elsewhere. This
is not how forces in classical systems behave. But in quantum mechanics, the
square potentials give a pretty good description of some systems such as atomic
nuclei
Recall that the time-independent Schrédinger equation for a system is an
cigenvalue equation for its Hamiltonian. As such, for attractive potentials we
‘can have both positive and negative energy solutions.
If the total energy £ is less than zero, it means that the system is bound to
the attractive potential. In quantum mechanics, we are then looking at a local-
ized eigenfunction; the wave function must vanish as the distance from the or-
igin tends toward infinity. As in the case of the box, an infinite potential well,
such a restriction imposes discreteness on the energy spectrum. Such quantized
energy levels are found in atoms, molecules, nuclei, and so forth, and thus our
‘models are expected to lead to some insight into the physics of these systems.
‘The E> 0 solutions corresponding to an attractive potential are important for
7576 Chapter 4: ‘The Solution of the Schrddinger Equation in One Dimension
the study of scattering problems—scattering of a projectile from a target that
can be represented by a potential.
When the potential is repulsive, obviously only solutions with E > 0 are
possible. But what if £ is greater than zero, yet less than the value of the po-
tential? Classically the potential then is an impassable “barrier,” such as is pre-
sented to billiard balls on a pool table by the walls of the table. But this is the
strange thing about quantum mechanics: There is a finite probability that quan-
tum billiard balls can penetrate those walls and fall off the table. It is not easy
to play quantum pool! Since this is an exciting and new phenomenon, this is
where we will begin our discussion.
BARRIER PENETRATION: SQUARE BARRIER.
A square (also called rectangular) barrier (fig. 4.1) is defined as
Vix) =0, forx<—a
=e, for-a