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Fig 3.1
It will free man from the remaining chains, the chains of gravity which still time him to his planet. --Werner von Braun
The combustion reaction of hydrogen and oxygen is used to produce the explosive energy needed to power the space shuttle (Figure 3.2). The reaction is also being engineered to serve as a source of continuous energy for fuel cells in electric vehicles. What factors determine the explosiveness of the reaction of hydrogen and oxygen? In this lab, we will generate microscale quantities of hydrogen and oxygen and test their explosive nature, first separately, then in mixtures of various proportions. The goal in laymans terms: find the most powerful gas mixture and use it to launch a rocket across the room!
Fig 3.2
This activitys goal in terms of chemistry concepts is to generate hydrogen and oxygen and determine the optimum ratio for their combustion reaction to give water. The optimum ratio will be used to calculate the mole ratio for the reaction of hydrogen and oxygen in a chemical equation. The concept of limiting reactants will be used to explain the results obtained with various hydrogen/oxygen gas mixtures.
Set-up in the classroom is a Hoffman Apparatus (also pictured 3.3 as a slightly different set-up that functions on the same basic principle). Your instructor will explain exactly what is happening with this apparatus after the rockets have launched. This will allow you to brainstorm a bit before heading back to the laboratory and before you go for the classroom rocket record! 1. As you may have noticed in the diagram of the external tank on the space shuttle, youll be dealing with oxygen and hydrogen. The Hoffman Apparatus is designed to produce oxygen and hydrogen gas from water. What side do you think is hydrogen gas? Why? 2. Answer the following questions: Write the balanced chemical equation for the single replacement reaction of zinc and hydrochloric acid to generate hydrogen gas. Write the balanced chemical equation for the catalyzed decomposition of hydrogen peroxide to generate oxygen gas and water. Note: Since a catalyst is not really a reactant or product, it is usually written over the arrow.
Share your answers with your group and see if you all know the significance of the questions. As always, write an objective for this laboratory activity in your lab notebook.
Fig 3.3
4. Using the reaction of Zn reacting with HCl as an example, predict the products of the following reactions, and balance the equations. a) zinc b) magnesium c) magnesium + + + acetic acid hydrochloric acid sulfuric acid
5. (1) Predict the names of the products of the following reactions. (2) Write all of the formulas for the complete reaction. (3) Balance each reaction. (4) State what type of reaction it is. a) ammonium chloride + b) magnesium + silver nitrate fluorine
d) write the reaction for water decomposing e) calcium hydroxide + hydrochloric acid
CT
C R I T I C A L L Y
T H I N K I N G
How do I know?
What did your data say was the best ratio for launching the rocket? How does this relate to the balanced equation?
Why do I believe?
Why do the hydrogen and oxygen gas mixtures in the collection bulb not react as soon as they are collected? Note: Consider the role of the match and the properties of gas molecules at room temperature and relate this to previous units where we needed to give an input of energy.
Why do I care?
We will look again at reaction when we generate hydrogen fuel cells in more detail. What are some issues you see with this reaction as a means to generate energy for a car?