Equipments and Materials 1. Equipments : - beaker glass - reaction tube - pipette -measuring glass 2.

Materials : - 0,2 M CH3COOH - 0,1 M NaOH - 0,1 M HCl - Universal Indicator Procedure 1. Preparing acidic buffer solution a. Adding strong base NaOH into buffer solution a) Take 25 ml 0,2 M CH3COOH b) Take 25 ml 0,1 M NaOH c) Mix and into beaker glass, stir the mixture. d) determine the initial pH of buffer solution. e) add 4 drops of universal indicator into buffer solution. f) observe the color. g) add 1 ml 0,1 M NaOH into buffer solution (5 times) h) observes the changes in color. i) Determine the pH of buffer solution after adding NaOH j) add 5 ml 0,1 M NaOH into buffer solution (5 times) k) observes the changes in color. l) Determine the pH of buffer solution after adding NaOH b. Adding strong acid HCl into buffer solution a) Take 25 ml 0,2 M CH3COOH b) Take 25 ml 0,1 M NaOH c) Mix and into beaker glass, stir the mixture. d) determine the initial pH of buffer solution. e) add 4 drops of universal indicator into buffer solution. f) observe the color. g) add 1 ml 0,1 M NaOH into buffer solution (5 times) h) observes the changes in color. i) Determine the pH of buffer solution after adding HCl j) add 5 ml 0,1 M NaOH into buffer solution (5 times) k) observes the changes in color. l) Determine the pH of buffer solution after adding HCl c. Diluting buffer solution a) Take 25 ml 0,2 M CH3COOH

b) Take 25 ml 0,1 M NaOH c) Mix and into beaker glass, stir the mixture. d) determine the initial pH of buffer solution. e) add 4 drops of universal indicator into buffer solution. f) observe the color. g) add 5 ml aquades into buffer solution (10 times) h) observes the changes in color. i) Determine the pH of buffer solution after adding aquades j) Do over again step (g), (h), (i) until the volume of aquades added is 50 ml. Data and Analysis 1. Preparing Acidic Buffer Solution a. Adding strong base (NaOH) into buffer solution

Acid Component CH3COOH

Base component NaOH

Properties Acidic Basic

Initial pH 5 log 1,8

Color Orange

Volume NaOH added (ml) 1 1 1 1 1 5 5 5 5 5

Mol NaOH added 0,1 0,1 0,1 0,1 0,1 0,5 0,5 0,5 0,5 0,5

pH

Color Orange Orange Orange Orange Orange Orange Yellow Yellow Yellow Yellow

b. Adding strong acid into buffer solution Acid Component CH3COOH Base component NaOH Properties Acidic Basic Initial pH 5 log 1,8 Color Orange

Volume NaOH added (ml) 1 1 1 1

Mol NaOH added 0,1 0,1 0,1 0,1

pH

Color Orange Orange Orange Orange

1 5 5 5 5 5 c. Diluting buffer solution Acid Component CH3COOH Base component NaOH

0,1 0,5 0,5 0,5 0,5 0,5

Orange Orange Dark Orange Dark Orange Dark Orange Dark Orange

Properties Acidic Basic

Initial pH 5 log 1,8

Color Red

Volume Aquades added (ml) 5 5 5 5 5 5 5 5 5 5

pH

Color Red Red Red Red Red Red Bright Red Bright Red Bright Red Bright Red

Discussion 1. What is buffer solution 2. Mention acid component and base component of buffer solution you have made 3. Calculate the initial pH of your buffer solution 4. Conclude buffer capacity based on your experiment 5. There are two state affecting buffer capacity. Mention it 6. Which one has greater buffer capacity 7. What will happen if we add too much acid or base into buffer solution? 8. Remember about titration curve of (a) weak acid vs strong base and (b) weak base vs strong acid a. What is the initial pH of curve (a) b. What is the initial pH of curve (b) c. There are four points in curve (a) show buffer region, what are the component of buffer solution in this region? d. What is the pH of those buffer region in curve (a) e. There are four points in curve (a) show buffer region, what are the component of buffer

solution in this region? f. What is the pH of those buffer region in curve (b)