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Programming data for Spectrophotometer

and Spectroquant Test Kits


measured with a Reference Spectrophotometer
Date: October 24, 2006
Parameter
Acid capacity CT
to pH 4.3
(Total Alkalinity)
Alcohol CT
Alkalinity
Aluminium Test
Aluminium CT
Ammonium CT

Ammonium Test

Ammonium CT

Ammonium CT

Ammonium Test

Ammonium CT

AOX
Antimony
Arsenic Test
BOD CT
Boron Test
Boron CT

2)

4)

Catalogue
No.
1.01762.

Measuring
range
0.20-8.00

Unit
mmol/l OH

Reaction
time min
0+0

Cells

Wavelength
620 nm

16 mm
10 mm
10-400
mg/l CaCO3
16 mm
10 mm
deleted, see Reflectoquant Test 1.16130.0001. Additionally RQflex required.
see Acid capacity to pH 4.3
1.14825.0001
0.10-1.20
mg/l Al
2+0
10 mm 550 nm
0.020-0.200
50 mm
1.00594.0001
0.02 0.50
mg/l Al
5+0
16 mm 545 nm
10 mm
1.14739.0001
0.010-2.000
15 + 0
16 mm 690 nm
mg/l NH4-N
10 mm
+
0.01-2.58
mg/l NH4
16 mm
10 mm
1.14752.0001
0.05-3.00
5+5
10 mm 690 nm
mg/l NH4-N
0.03-1.50
20 mm
0.010-0.500
50 mm
+
0.06-3.86
mg/l NH4
10 mm
0.04-1.93
20 mm
0.013-0.644
50 mm
1.14558.0001
0.20-8.00
15 + 0
16 mm 690 nm
mg/l NH4-N
10 mm
+
0.26-10.30
mg/l NH4
16 mm
10 mm
1.14544.0001
0.5-16.0
mg/l NH4-N
15 + 0
16 mm 690 nm
10 mm
+
0.6-20.6
mg/l NH4
16 mm
10 mm
1.00683.0001
2.0-75.0
15 + 0
10 mm 690 nm
mg/l NH4-N
5-150
10 mm
+
2.6-96.6
mg/l NH4
10 mm
6-193
10 mm
1.14559.0001
4.0-80.0
mg/l NH4-N
15 + 0
16 mm 690 nm
10 mm
+
5.2-103.0
mg/l NH4
16 mm
10 mm
1.00675.0001
0.05-2.50
mg/l AOX
15 + 0
16 mm 445 nm
10 mm
2)
0.10-8.00
mg/l Sb
3+2
10 mm 620 nm
1.01747.0001
0.005-0.100
mg/l As
120 + 0 10 mm 525 nm
0.001-0.020
20 mm
1.00687.0001
0.5-3000
mg/l BOD
0+0
16 mm 500 nm
10 mm
1.14839.0001
0.050-0.800
mg/l B
12 + 2
10 mm 565 nm
1.00826.0001
0.05-2.00
mg/l B
60 + 0
16 mm 405 nm
10 mm

Factor

Measuring against

4)

dist. water
dist. water
dist. water
dist. water

4)

dist. water
dist. water
dist. water
dist. water
cell with blank
own blank
cell with blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
cell with blank
own blank
cell with blank
own blank
cell with blank
own blank
cell with blank
own blank
own blank
own blank
own blank
own blank
cell with blank
own blank
cell with blank
own blank
own blank
own blank
own blank
dist. water
dist. water
dist. water
dist. water
own blank
own blank
own blank

4)

0.877
1.18
1.13
1.53
1.23
0.615
0.246
1.58
0.792
0.316
4.26
5.75
5.49
7.41
7.84
10.6
10.1
13.6
27.8
55.6
35.8
71.5
36.4
49.1
46.8
63.3
4.00
5.40
3.45
0.0910
0.0455
13.5
18.2
0.328
1.38
1.86

These parameters are not ready-to-use test kits. You will find all detailed information in our application list on
the Internet homepage http://photometry.merck.de.
Please see programming data under non-linear calibration or absorption-concentration- table.

Remark:
own blank means distilled water and all reagents in the same quantity as used for the measuring sample preparation.
Separately prepared in standard test tubes and poured into the type of cell used.
cell with blank means the white capped ready-to-use blank sample in cell tests for use with round cell measurement. The
instrument must be equipped with a round cell holder.
dist. water means distilled water without reagents and poured into the type of cell used.
clear sample without reag. means sample must be colourless and turbid samples must be filtered.

Date: October 24, 2006

1 of 17

Parameter
Bromine Test

Catalogue
No.
1.00605.0001

Cadmium Test

1.01745.0001

Cadmium CT

1.14834.0001

Calcium Test

1.14815.0001

Calcium CT

1.00858.0001

Chloride CT

1.14730.0001

Chloride Test

1.14897.0001

Chlorine Test
(free chlorine)

1.00598.

Chlorine CT
(free chlorine)
Chlorine Test
(total Chlorine)

1.00595.0001
1.00602.

Chlorine Test
1.00599.0001
(free+total Chlorine)

Measuring
range
0.10-10.00
0.05-5.00
0.020-2.000
0.010-0.500
0.005-0.250
0.002-0.100
0.025-1.000

mg/l Br2

Reaction
time min
3+0

mg/l Cd

2+0

mg/l Cd

2+0

10-160
25-400
14-224
5-80
12-200
7-112
1)
1.0-15.0
1)
2.5-37.5
1)
1.4-21.0
10-250
25-625
14-350
10-250
25-625
14-350
5-125

mg/l Ca
mg/l CaCO3
mg/l CaO
mg/l Ca
mg/l CaCO3
mg/l CaO
mg/l Ca
mg/l CaCO3
mg/l CaO
mg/l Ca
mg/l CaCO3
mg/l CaO
mg/l Ca
mg/l CaCO3
mg/l CaO
mg/l Cl

8+0

10-250
2.5-25.0
0.05-6.00
0.02-3.00
0.010-1.000
0.03-6.00

mg/l Cl

0.05-6.00
0.02-3.00
0.010-1.000
0.05-6.00
0.02-3.00
0.010-1.000
0.03-6.00

Unit

3+0

0+0

1+0

mg/l Cl2

3+0

mg/l Cl2

3+0

mg/l Cl2

3+0

mg/l Cl2

3+0

Chlorine CT
1.00597.0001
mg/l Cl2
3+0
(free+total chlorine)
Chlorine (liquid)
1.00086.0001
3+0
0.03-6.00
mg/l Cl2
(free+total Chlorine) 1.00087.0001
0.010-1.000
1.00088.0001
1.00089.0001
Chlorine Test
1.14828.0001 replaced by 100599 or 100598 and 100602
Chlorine dioxide 1.00608.0001
0.10-10.00
mg/l ClO2
3+0
Test
0.05-5.00
0.020-2.000
Chlorine dioxide 1.14732.0001 replaced by 100608
Test
Chromate Test
1.14758.0001
0.05-3.00
0+0
mg/l Cr
0.03-1.50
0.010-0.600
0.11-6.69
mg/l CrO4
0.07-3.35
0.02-1.34
Chromate CT
1.14552.0001
0.05-2.00
mg/l Cr
0+0

Chromium bath

1)
2)

4)

2)

0.11-4.46

mg/l CrO4

20-400
10-200
4.0-80.0

g/l CrO3

0+0

Cells
10 mm
20 mm
50 mm
10 mm
20 mm
50 mm
16 mm
10 mm
10 mm
10 mm
10 mm
20 mm
20 mm
20 mm
10 mm
10 mm
10 mm
16 mm
16 mm
16 mm
10 mm
10 mm
10 mm
16 mm
10 mm
10 mm
10 mm
10 mm
20 mm
50 mm
16 mm
10 mm
20 mm
50 mm
10 mm
20 mm
50 mm
16 mm

Wavelength
550 nm

Factor

Measuring against

7.52
3.76
1.50
0.680
0.340
0.136
0.595
0.804
137
342
192
68.5
171
95.9
29.4
73.5
41.2

565 nm

4)

525 nm

114
153
107
28.2
3.33
1.67
0.667
2.47

dist. water
dist. water
dist. water
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
own blank
own blank
own blank
own blank
dist. water
dist. water
dist. water
dist. water

3.33
1.67
0.667
3.33
1.67
0.667
2.47

dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water

525 nm

550 nm
550 nm

500 nm
445 nm
550 nm

550 nm
550 nm

550 nm

550 nm

16 mm
50 mm

550 nm

2.47
0.667

dist. water
dist. water

10 mm
20 mm
50 mm

550 nm

6.33
3.16
1.27

dist. water
dist. water
dist. water

10 mm
20 mm
50 mm
10 mm
20 mm
50 mm
16 mm
10 mm
16 mm
10 mm
10 mm
20 mm
50 mm

550 nm

1.30
0.650
0.260
2.90
1.45
0.579
0.971
1.31
2.17
2.92
556
278
111

dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
cell with blank
dist. water
cell with blank
dist. water
dist. water
dist. water
dist. water

550 nm

445 nm

Handling details: see Appendix


These parameters are not ready-to-use test kits. You will find all detailed information in our application list on
the Internet homepage http://photometry.merck.de.
Please see programming data under non-linear calibration or absorption-concentration- table.

Date: October 24, 2006

2 of 17

Parameter
COD CT

Catalogue
No.
1.14560.0001

Measuring
range
4.0-40.0

mg/l COD

Reaction
time min
0+0

COD CT

1.14540.0001

10-150

mg/l COD

0+0

COD CT

1.14895.0001

15-300

mg/l COD

0+0

COD CT

1.14690.0001

50-500

mg/l COD

0+0

COD CT

1.14541.0001

25-1500

mg/l COD

0+0

COD CT

1.14691.0001

300-3500

mg/l COD

0+0

COD CT

1.14555.0001

500-10000

mg/l COD

0+0

COD CT
(Hg free)
COD CT
(Hg free)
Colour

1.09772.0001

10-150

mg/l COD

0+0

1.09773.0001

100-1500

mg/l COD

0+0

0.5-50.0

m-1

0+0

Colour
measurement
Copper Test

see Hazen Colour number


1.14767.0001

Copper CT

1.14553.0001

Copper bath

2)

Cyanide Test

1.09701.0001

Cyanide Test

1.14800.0001

Cyanide CT

1.14561.0001

Detergents
see Surfactants
Dissolved Oxygen see Oxygen
Ethanol
see Alcohol
Fluoride CT
1.14557.0001

1)
2)

0.10-6.00
0.05-3.00
0.02-1.20
0.05-8.00

mg/l Cu

5+0

mg/l Cu

5+0

10.0-80.0
5.0-40.0
2.0-16.0
0.010-0.500
0.005-0.250
0.002-0.100
0.010-0.500
0.005-0.250
0.002-0.100
0.010-0.500

g/l Cu

0+0

mg/l CN

10 + 0

mg/l CN

5+0

mg/l CN

10 + 0

5+0

mg/l F

5+0

mg/l HCHO

10 + 0

mg/l HCHO

5+0

1.14821.0001
0.5-12.0
mg/l Au
see Residual hardness or Total hardness
0-500
HZ or Pt/Co
0-250
0-100
0-1000
HZ or Pt/Co

0+0

1.14598.0001

Formaldehyde
Test

1.14678.0001

Formaldehyde
CT
Gold Test
Hardness
Hazen colour
number

1.14500.0001

0.10-1.50
0.025-0.500
0.10-2.00
1.0-20.0
0.10-8.00
0.05-4.00
0.02-1.50
0.10-8.00

Cells
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
50 mm

Wavelength
340 nm
445 nm
445 nm
445 nm
605 nm
605 nm
605 nm
445 nm
605 nm
445 mm
525 nm
620 nm

Factor

Measuring against

-41.7
-56.3
-217
-295
-222
-300
-397
-536
1667
2249
3226
4355
4608
6221
-238
-321
1923
2596
20.0
20.0
20.0

own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
dist. water
dist. water
dist. water

4.44
2.22
0.889
3.60
4.86
43.1
21.6
8.62
0.221
0.110
0.0442
0.208
0.104
0.0416
0.161
0.218

dist. water
dist. water
dist. water
cell with blank
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water

1.33
1.80
0.323
2.02
21.5
4.22
2.11
0.844
3.23
4.36
6.25

own blank
own blank
own blank
own blank
own blank
dist. water
dist. water
dist. water
dist. water
dist. water
own blank
dist. water
dist. water
dist. water
dist. water

Pt/Co or HZ

Fluoride Test

Hazen colour
number
Hazen colour
number
Hazen colour
number

Unit

mg/l F

10 mm
20 mm
50 mm
16 mm
10 mm
10 mm
20 mm
50 mm
10 mm
20 mm
50 mm
10 mm
20 mm
50 mm
16 mm
10 mm

605 nm

605 nm
820 nm

605 nm

585 nm

605 nm

16 mm
10 mm
50 mm
10 mm
10 mm
10 mm
20 mm
50 mm
16 mm
10 mm
10 mm

620 nm

340 nm

0+0

10 mm
20 mm
50 mm
50 mm

445 nm

370
185
74
769

1)

0+0

620 nm
565 nm

565 nm
550 nm

0-1000

HZ or Pt/Co

0+0

50 mm

455 nm

725

dist. water

0-1000

HZ or Pt/Co

0+0

50 mm

465 nm

741

dist. water

Handling details: see Appendix


These parameters are not ready-to-use test kits. You will find all detailed information in our application list on
the Internet homepage http://photometry.merck.de.

Date: October 24, 2006

3 of 17

Parameter

Measuring
Unit
range
Hydrazine Test
0.02-2.00
mg/l N2H4
0.01-1.00
0.005-0.400
Hydrazine Test
1.14797.0001 replaced by 1.09711.0001
Hydrogen peroxide 1.14731.0001
2.0-20.0
mg/l H2O2
CT
0.25-5.00
Hydrogen peroxide 1.18789.0001
0.03 6.00
mg/l H2O2
0.015 3.000
Test
Hydrogen Sulfide see Sulfide
Iodine Test
1.00606.0001
0.20-10.00
mg/l I2
0.10-5.00
0.050-2.000
Iodine colour
0.05-3.00
IFZ
number
0.03-1.50
0.010-0.600
Iodine colour
1.0-50.0
IFZ
number
0.5-25.0
0.2-10.0
Iron Test
1.14761.
0.05-5.00
mg/l Fe
0.03-2.50
0.005-1.000
Iron Test
1.00796.0001
0.10-5.00
mg/l Fe
0.05-2.50
0.010-1.000
Iron CT
1.14549.0001
0.05-4.00
mg/l Fe
0.055.00
Iron CT
1.14896.0001
1.0-50.0
mg/l Fe

2)

4)

Catalogue
No.
1.09711.0001

Lead Test

1.09717.0001

Lead CT

1.14833.0001

Mercury
Magnesium CT

1.00815.0001

2)

Reaction
time min
5+0

2+0

10 + 0

3+0

0+0

0+0

3+0

5 + 10

3+0
5+0

0.10-5.00
0.05-2.50
0.010-1.000
0.10-5.00

mg/l Pb

0+0

mg/l Pb

0+0

0.025-1.000
5.0-75.0

mg/l Hg
mg/l Mg

5+0
3+0

mg/l Mn

10 + 0

mg/l Mn

2+2

mg/l Mn

2+5

Manganese
Test

1.01739.0001

Manganese
Test

1.14770.0001

Manganese CT

1.00816.0001

0.05-2.00
0.03-1.00
0.005-0.400
0.50-10.00
0.25-5.00
0.01-2.00
0.10-5.00

Molybdenum CT

1.00860.0001

0.02-1.00

mg/l Mo

2+0

Monochloramine
Test

1.01632.0001

0.25-10.00
0.13-5.00
0.050-2.000
0.18-7.25
0.09-3.63
0.036-1.450
0.05-1.96
0.03-0.98
0.010-0.392
0.10-5.00
0.05-2.50
0.02-1.00
0.10-6.00

mg/l Cl2

5+5

Nickel Test

1.14785.0001

Nickel CT

1.14554.0001

Nickel bath

2)

10-120
5.0-60.0
2.0-24.0

mg/l NH2Cl
mg/l NH2Cl-N

mg/l Ni

1+2

mg/l Ni

1+2

g/l Ni

0+0

Cells

Wavelength
445 nm

Factor

Measuring against

0.870
0.435
0.174

dist. water
dist. water
dist. water

16 mm
10 mm
50 mm
10 mm
20 mm

410 nm

38.5
52.3
10.5
2.67
1.34

cell with blank


dist. water
dist. water
own blank
own blank

10 mm
20 mm
50 mm
10 mm
20 mm
50 mm
10 mm
20 mm
50 mm
10 mm
20 mm
50 mm
10 mm
20 mm
50 mm
16 mm
10 mm
16 mm
10 mm
10 mm
20 mm
50 mm
16 mm
10 mm
50 mm
16 mm
10 mm
10 mm
20 mm
50 mm
10 mm
20 mm
50 mm
16 mm
10 mm
16 mm
10 mm
10 mm
20 mm
50 mm
10 mm
20 mm
50 mm
10 mm
20 mm
50 mm
10 mm
20 mm
50 mm
16 mm
10 mm
10 mm
20 mm
50 mm

550 nm

11.9
5.95
2.38
1.27
0.637
0.255
17.1
8.55
3.42
2.08
1.04
0.416
5.56
2.78
1.11
1.64
2.21
28.3
38.2
6.25
3.13
1.25
4.39
5.93
0.563

dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
cell with blank
dist. water
cell with blank
dist. water
own blank
own blank
own blank
cell with blank
own blank
own blank
dist. water
dist. water
own blank
own blank
own blank
dist. water
dist. water
dist. water
cell with blank
dist. water
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
dist. water
dist. water
dist. water
cell with blank
own blank
dist. water
dist. water
dist. water

10 mm
20 mm
50 mm

445 nm

340 nm

445 nm

565 nm

500 nm

565 nm
525 nm
525 nm

525 nm
565 nm
565 nm
565 nm

445 nm

445 nm
620 nm
690 nm

445 nm

445 nm
690 nm

4)

1.72
0.862
0.345
5.62
2.81
1.12
4.13
5.58
1.10
1.49
5.00
2.50
1.00
3.67
1.83
0.733
0.988
0.494
0.198
4.76
2.38
0.952
3.82
5.16
60.6
30.3
12.1

These parameters are not ready-to-use test kits. You will find all detailed information in our application list on
the Internet homepage http://photometry.merck.de.
Please see programming data under non-linear calibration or absorption-concentration- table.

Date: October 24, 2006

4 of 17

Parameter
Nitrate Test

Nitrate Test

Nitrate CT

Nitrate CT

Nitrate CT

Nitrate CT

Nitrate CT
in seawater

Nitrate Test
in seawater
Nitrite Test

Nitrite CT

Nitrite CT

Catalogue
No.
1.09713.0001

1.14773.0001

1.14542.0001

1.14563.0001

1.14764.0001

1.00614.0001

1.14556.0001

1.14942.0001
1.14776.

1.14547.0001

1.00609.0001

Measuring
range
1.0-25.0
0.5-12.5
0.10-5.00
4.4-110.7
2.2-55.4
0.4-22.1
0.5-20.0
0.2-10.0
2.2-88.5
0.9-44.3
0.5-18.0

Unit

Reaction
time min
10 + 0
mg/l NO3-N
-

mg/l NO3

mg/l NO3-N

10 + 0

mg/l NO3

mg/l NO3-N

10 + 0

2.2-79.7

mg/l NO3

0.5-25.0

mg/l NO3-N

10 + 0

2.2-110.7

mg/l NO

1.0-50.0

mg/l NO3-N

4-221

mg/l NO3

23-225

mg/l NO3-N

102-996

mg/l NO3

0.10-3.00
0.10-2.50
0.4-13.3
0.4-11.1
0.2-17.0
0.9-75.3
0.02-1.00
0.010-0.500
0.002-0.200
0.07-3.28
0.03-1.64
0.007-0.657
0.010-0.700

mg/l NO3-N

mg/l NO2-N

0.03-2.30

mg/l NO2

1.0-90.0

mg/l NO2-N

10 + 0

5+0

30 + 0

mg/l NO3

mg/l NO3-N
mg/l NO3
mg/l NO2-N

15 + 60
10 + 0

mg/l NO2

10 + 0

20 + 0

3.3-295.2

mg/l NO

Nitrogen, total CT

1.00613.0001

0.5-15.0

mg/l N

10 + 0

Nitrogen, total CT

1.14537.0001

0.5-15.0

mg/l N

10 + 0

Nitrogen, total CT

1.14763.0001

10-150

mg/l N

10 + 0

Nitrogen,
Ammonium
Nitrogen, Nitrate
Nitrogen, Nitrite
Organic Acids,
Volatile
Organic Carbon,
Total
Oxygen, dissolved
CT
Oxygen Demand,
Biological
Oxygen Demand,
Chemical

see Ammonium

mg/l O2

0+0

4)

Cells
10 mm
20 mm
50 mm
10 mm
20 mm
50 mm
10 mm
20 mm
10 mm
20 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
10 mm
10 mm
10 mm
20 mm
50 mm
10 mm
20 mm
50 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10mm
16 mm
10mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm

Wavelength
340 nm

Factor

Measuring against

19.6
9.80
3.92
86.8
43.4
17.4
9.62
4.81
42.6
21.3
7.14
9.64
31.6
42.7
14.7
19.9
65.1
87.9
27.9
37.7
124
167
132
180
586
797

500 nm

4)

500 nm

4)

525 nm

0.370
0.185
0.0741
1.22
0.608
0.243
0.274
0.370
0.900
1.22
80.2
109.9
263.4
360.9
15.3
20.6
7.81
10.5
154
208

own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
cell with blank
own blank
cell with blank
own blank
cell with blank
own blank
cell with blank
own blank
cell with blank
own blank
cell with blank
own blank
cell with blank
own blank
cell with blank
own blank
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
cell with blank
dist. water
cell with blank
dist. water
dist. water
dist. water
dist. water
dist. water
cell with blank
own blank
own blank
own blank
cell with blank
own blank

13.5
18.2

dist. water
dist. water

525 nm

525 nm

340 nm

340 nm

340 nm

525 nm

585 nm

340 nm
525 nm
340 nm

see Nitrate
see Nitrite
see Volatile organic acids
see TOC
1.14694.0001

0.5-12.0

16 mm
10 mm

500 nm

see BOD
see COD

Please see programming data under non-linear calibration or absorption-concentration- table.

Date: October 24, 2006

5 of 17

Parameter

Catalogue
No.

Ozone Test

1.00607.

Measuring
range

Unit

Reaction
time min

Cells

Wavelength

Factor

Measuring against

mg/l O3

3+0

10 mm
20 mm
50 mm

550 nm

2.25
1.13
0.450

dist. water
dist. water
dist. water

mg/l Pd

1+0

10 mm

525 nm

0.588

own blank

pH units

0+0

550 nm

4)

0.002-0.100
0.10-5.00
0.013-2.500
0.025-1.000
0.10-2.50

mg/l Phenol

30 + 10
10 + 0

445 nm
495 nm

mg/l Phenol

1+0

0.05-5.00
0.03-2.50
0.010-1.000
0.2-15.3
0.09-7.67
0.03-3.07
0.11-11.46
0.07-5.73
0.02-2.29
0.05-5.00

mg/l PO4-P

5+0

16 mm
10 mm
20 mm
10 mm
20 mm
50 mm
16 mm
10 mm
10 mm
20 mm
50 mm
10 mm
20 mm
50 mm
10 mm
20 mm
50 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
10 mm
20 mm
10 mm
20 mm
10 mm
20 mm
10 mm
10 mm
10 mm
16 mm
10 mm
16 mm
10 mm
16 mm
10 mm
10 mm

0.114
8.33
4.17
1.67
3.39
4.58
2.12
1.06
0.424
6.50
3.25
1.30
4.85
2.43
0.971
1.61
2.18
4.95
6.68
3.70
4.99
8.06
10.9
24.7
33.4
18.5
24.9
13.4
18.2
41.2
55.6
30.8
41.5
18.0
9.00
55.2
27.6
41.3
20.6
35.1
108
80.4
39.2
52.9
120
162
89.9
121
2.38

dist. water
dist. water
own blank
own blank
own blank
own blank
cell with blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
cell with blank
own blank
cell with blank
own blank
cell with blank
own blank
cell with blank
own blank
cell with blank
own blank
cell with blank
own blank
cell with blank
own blank
cell with blank
own blank
cell with blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
own blank
cell with blank
own blank
cell with blank
own blank
cell with blank
own blank
own blank

Ozone Test
Palladium
Peroxide
pH CT

0.05-4.00
0.02-2.00
0.010-0.800
1.14732.0001 replaced by 100607
2)
0.05-1.25
see Hydrogen Peroxide
1.01744.0001
6.4-8.8

Phenol Test

1.00856.0001

Phenol CT

1.14551.0001

Phosphate Test
(PMB)

1.14848.0001

Phosphate CT
(PMB)

1.14543.0001

0.2-15.3

Phosphate CT
(PMB)

Phosphate CT
(VM)

Phosphate Test
(VM)

1.14729.0001

1.14546.0001

1.14842.0001

Phosphate Test
(PMB)

1.00798.0001

Phosphate CT
(PMB)

1.00616.0001

Platinum
Platinium-Cobalt
Standard
2)

3)
4)

2)

3-

mg/l PO4

mg/l P2O5

mg/l PO4-P
mg/l PO

0.11-11.46

mg/l P2O5

0.5-25.0

mg/l PO4-P

5+0

34

1.5-76.7

mg/l PO

1.1-57.3

mg/l P2O5

0.5-25.0
1.0-33.0
1.5-75.0
3.0-90.0
1.1-57.3
1.5-77.4
1.0-30.0
0.5-15.0
3.1-92.0
1.5-46.0
2.3-68.7
1.1-34.4
1.0-100.0
3-307
2-229
3.0-100.0

mg/l PO4-P

0+0

34

mg/l PO

mg/l P2O5
mg/l PO4-P

0+0

34

mg/l PO

mg/l P2O5
mg/l PO4-P
3mg/l PO4
mg/l P2O5
mg/l PO4-P

5+0

5+0

34

9-307

mg/l PO

7-229

mg/l P2O5

0.10-1.25
see Hazen Colour number

5+0

34

mg/l Pt
Pt/Co or HZ

5+1

500 nm
690 nm

690 nm

690 nm

410 nm

410 nm

690 nm

690 nm

690 nm

These parameters are not ready-to-use test kits. You will find all detailed information in our application list on
Internet homepage http://photometry.merck.de analysis.
This methods needs to be instrument-specific calibrated (see appendix).
Please see programming data under non-linear calibration or absorption-concentration- table.

Date: October 24, 2006

6 of 17

Parameter
Potassium CT

Catalogue
No.
1.14562.0001

Measuring
range
5.0-50.0

mg/l K

Reaction
time min
5+0

Potassium CT

1.00615.0001

30-300

mg/l K

5+0

0.50-5.00
1.25-12.50
0.70-7.00
0.070-0.700
0.088-0.875
0.125-1.250
0.50-5.00
1.25-12.50
0.70-7.00
0.070-0.700
0.088-0.875
0.125-1.250
0.10-5.00
0.05-2.50
0.005-0.750
0.21-10.70
0.11-5.35
0.01-1.60
0.5-50
5-500
1.1-107.0
11-1070
0.50-3.00
0.25-1.50
10-300

mg/l Ca
mg/l CaCO3
mg/l CaO
d
e
f
mg/l Ca
mg/l CaCO3
mg/l CaO
d
e
f
mg/l Si

10 + 0

5-250

mg/l SO4

Residual Hardness 1.14683.0001


CT

Silicate Test

Silicate Test

Silver Test

1.14794.0001

1.00857.0001

1.14831.0001

Sodium CT in
1.00885.0001
nutrient solutions for
fertilization
Sulfate CT
1.14548.0001
Sulfate Test
Sulfate CT
Sulfate CT
Sulfide Test

Unit

3 + 10

mg/l SiO2

2+2

mg/l Si
mg/l SiO2
mg/l Ag

5+0

mg/l Na

1+0

2-

690 nm

turbidity

565 nm

4)

665 nm

3.73
1.87
0.286
7.98
3.99
0.611
28.2
279
60.3
598
2.22
1.11
263
355

dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
own blank
own blank
own blank
own blank

820 nm
665 nm
820 nm
410 nm

550 nm
550 nm

3)

3)

10 + 0

1.01764.0001

0.05-1.50

mg/l CTAB

5+0

16 mm

620 nm

1.92

cell with blank

1.01787.0001

0.10-7.50

2+0

16 mm

605 nm

6.06

own blank

2)

25-750

mg/l Triton
X-100
mg/l SuS

0+0

20 mm

820 nm

turbidity

dist. water

0.10-2.50

mg/l Sn

15 + 0

665 nm

4)

mg/l TOC
mg/l TOC

0+0
0+0

16 mm
10 mm
16 mm
16 mm

605 nm
605 nm

-64.5
-645

dist. water
dist. water
own blank
own blank

1.01746.0001

Surfactants
(anionic) CT
Surfactants
(cationic) CT
Surfactants
(nonionic) CT
Suspended Solids
Tensides
Tin CT

see Surfactants
1.14622.0001

25-300
50-500

24
24

5+7
2+0

24

2+0

mg/l SO
mg/l SO

100-1000
0.10-1.50
0.020-0.500
1.0-20.0

mg/l SO
mg/l S

2-

0+0
2-

2+0

2-

2+0

mg/l SO3

1)

4)

turbidity

1.14697.0001

Sulfite Test

3)

Measuring against

mg/l SO3
mg/l SO2
mg/l MBAS

1.14779.0001
1.14394.0001

2)

Factor

0.05-3.00
1.0-60.0
0.8-48.0
0.05-2.00

1.14564.0001

Sulfite CT

TOC CT
TOC CT
Total Alkalinity

16 mm
10 mm
16 mm
10 mm
16 mm
16 mm
16 mm
16 mm
16 mm
16 mm
10 mm
10 mm
10 mm
10 mm
10 mm
10 mm
10 mm
20 mm
50 mm
10 mm
20 mm
50 mm
10 mm
10 mm
10 mm
10 mm
10 mm
20 mm
16 mm
10 mm

Wavelength
690 nm

16 mm
10 mm
10 mm
16 mm
10 mm
16 mm
10 mm
10 mm
50 mm
16 mm
10 mm
50 mm
10 mm
10 mm
16 mm

1.14791.0001
1.00617.0001

2+0

Cells

1.14878.0001
5.0-80.0
1.14879.0001
50-800
see Acid capacity to pH 4.3

525 nm

turbidity

650 nm

0.244
8.77
11.8
1.69
29.4
23.5
1.80

Clear sample without reag.


Clear sample without reag.
own blank
Clear sample without reag.
Clear sample without reag.
Clear sample without reag.
Clear sample without reag.
dist. water
dist. water
cell with blank
own blank
own blank
own blank
own blank
cell with blank

525 nm
525 nm

256
turbidity

820 nm

turbidity

665 nm
410 nm

410 nm

3)

3)

3)
4)

3)

These parameters are not ready-to-use test kits. You will find all detailed information in our application list on
Internet homepage http://photometry.merck.de analysis.
This methods needs to be instrument-specific calibrated (see appendix).
Please see programming data under non-linear calibration or absorption-concentration- table.

Date: October 24, 2006

7 of 17

Parameter
Total Hardness
CT

Catalogue
No.
1.00961.0001

Wavelength
565 nm

Factor

Measuring against

4)

dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water
dist. water

50 mm

550 nm

turbidity

dist. water

3 + 10

16 mm
10 mm

495 nm

1430
1931

own blank
own blank

see Residual hardness or Total hardness


1.00861.0001
0.025-1.000
mg/l Zn

15 + 0

500 nm

1.14832.0001
1.14566.0001

3+2
15 + 0

16 mm
10 mm
10 mm
16 mm
10 mm

1.36
1.84
1.08
4.88
6.59

own blank
own blank
dist. water
cell with blank
own blank

Total Nitrogen CT see Nitrogen, total


2)
Turbidity
Volatile Organic
Acids CT
Water Hardness
Zinc CT
Zinc Test
Zinc CT

2)

3)
4)

1.01763.0001

Measuring
range
5-215
13-538
7-301
0.7-30.1
0.9-37.6
1.3-53.8
5-215
13-538
7-301
0.7-30.1
0.9-37.6
1.3-53.8

mg/l Ca
mg/l CaCO3
mg/l CaO
d
e
f
mg/l Ca
mg/l CaCO3
mg/l CaO
d
e
f

1-100

FAU

0+0

50-3000

mg/l HOAc

0.05-2.50
0.20-5.00

Unit

mg/l Zn
mg/l Zn

Reaction
time min
3+0

Cells
16 mm
16 mm
16 mm
16 mm
16 mm
16 mm
10 mm
10 mm
10 mm
10 mm
10 mm
10 mm

565 nm
500 nm

3)

These parameters are not ready-to-use test kits. You will find all detailed information in our application list on
Internet homepage http://photometry.merck.de analysis.
This methods needs to be instrument-specific calibrated (see appendix).
Please see programming data under non-linear calibration or absorption-concentration- table.

Appendix:
Measuring range with appendix 1)
Each test kit contains a package insert with detailed information regarding the standard procedure of the
measurement. In some cases, however, special points have to be considered which are not mentioned in the
package inserts.
In this appendix you will find specific applications and modified methods for analyses for sensitive measurements
indicated with a 1).
Calcium: with Spectroquant Calcium Test, Cat. No. 1.14815.0001
Measuring range: 1.0
15.0
mg/l Ca
2.5
- 37.5
mg/l CaCO3
1.4
- 21.0
mg/l CaO
Procedure: Add 10 ml of reagent Ca-1 and 8 drops each of reagent Ca-2 and Ca-3 to 1 ml of the sample solution
and mix. Leave to stand for 8 min for colour development. After filling into 10 mm cells measure in the
photometer at 550 nm. Prepare the blank required for the measurement according to the above-mentioned
procedure using 1 ml of distilled water instead of the sample solution.
Fluoride: with Spectroquant Fluoride Cell Test, Cat. No. 1.14557.0001
Measuring range: 0.025 0.500 mg/l FProcedure: Pipette 10 ml of sample solution into the reaction cell, mix and add 1 blue microspoon of reagent F1K. Close the cell tightly and dissolve the solid by shaking. Leave to stand for 5 min for colour development. After
filling into 50 mm cells measure in the photometer at 620 nm. Prepare the blank required for the measurement
according to the above-mentioned procedure using 10 ml of distilled water instead of the sample solution.

Date: October 24, 2006

8 of 17

Sulfite: with Spectroquant Sulfite Cell Test, Cat. No. 1.14394.0001


Measuring range: 0.005 3.00
mg/l SO32Procedure: Place 1 microspoon of reagent SO3-1K into the cell, close tightly and shake until the complete
dissolution of the solid. Then pipette 7 ml of the sample solution into the cell and mix. After the reaction time of 2
min fill into 50 cells and measure in the photometer at 410 nm. Prepare the blank required for the measurement
according to the above-mentioned procedure using 7 ml of distilled water instead of the sample solution.
Alternative methods 2)
There are no test kits available for this parameter. The methods used there are reported in analytical literature.
Applications and instructions how to perform the methods are available on the Internet homepage of Merck KGaA
http://photometry.merck.de.
Turbidity measurement 3)
The parameters
Potassium Cat. No. 1.14562.0001
Potassium Cat. No. 1.00615.0001
Sulfate
Cat. No. 1.14548.0001
Sulfate
Cat. No. 1.00617.0001
Sulfate
Cat. No. 1.14564.0001
Suspended Solids (physical measurement - application)
Turbidity (physical measurement - application)
are methods where the turbidity is measured. As the optical system of every spectrophotometer is different, we
convince you to determine the factor for your spectrophotometer by your own and program it in your photometer.
Non-linear calibration or absorption-concentration- table. 4)
Calibration curves for the methods are non-linear.
1. Use the below mentioned concentration-absorption-table
2. Beside using the concentration-absorption-table you can enter a non-linear curve by using the coefficients of
the following formula.
C = a + bx + cx2 + dx3
Check your instrument and enter the coefficients according the given list. The calibration is always done
against distilled water.
3. We recommend to take a standard and check if the calibration is done correctly because also
spectrophotometers have small differences from instrument to instrument.

Date: October 24, 2006

9 of 17

Absorption-Concentration-Table for Acid capacity Cell Test, Cat. No. 1.01762.0001, calibration against distilled
water.
Absorption 16 mm
round cell
0.544
0.571
0.680
0.816
0.979
1.129
1.292
1.469
1.632
1.782
1.904

mmol/l OH

mg/l CaCO3-

0
0.20
1.00
1.90
2.80
3.70
4.50
5.40
6.30
7.20
8.00

0
10
50
95
140
185
225
270
315
360
400

Absorption 10 mm
cell
0.400
0.420
0.500
0.600
0.720
0.830
0.950
1.080
1.200
1.310
1.400

mmol/l OH

mg/l CaCO3-

0
0.20
1.00
1.90
2.80
3.70
4.50
5.40
6.30
7.20
8.00

0
10
50
95
140
185
225
270
315
360
400

Non-linear curve for Acid capacity Cell Test, Cat. No. 1.01762.0001, calibration against distilled water.
Non-linear
calibration
coefficient a:
coefficient b:
coefficient c:
coefficient d:

16 mm
round cell
0.20 8.00
mmol/l OH
-5.582
13.170
-6.232
1.608

16 mm
round cell
10 400
mg/l CaCO3-279.1
658.5
-311.6
80.4

10 mm
cell
0.20 8.00
mmol/l OH
-5.581
17.899
-11.509
4.038

10 mm
cell
10 400
mg/l CaCO3-279.0
895.0
-575,4
201.9

Absorption-Concentration- Table for Aluminium Cell Test, Cat. No. 1.00594.0001, calibration against distilled
water.
Absorption 16 mm
round cell
0.336
0.397
0.466
0.569
0.671
0.781
0.897
1.032
1.164
1.288
1.411

mg/l Al
0
0.05
0.10
0.15
0.20
0.25
0.30
0.35
0.40
0.45
0.50

Absorption 10 mm
cell
0.245
0.290
0.340
0.415
0.490
0.570
0.655
0.753
0.850
0.940
1.030

mg/l Al
0
0.05
0.10
0.15
0.20
0.25
0.30
0.35
0.40
0.45
0.50

Non-linear curve for Aluminium Cell Test, Cat. No. 1.00594.0001, calibration against distilled water.
Nichtlineare
Kalibrierung
Koeffizient a:
Koeffizient b:
Koeffizient c:
Koeffizient d:

Date: October 24, 2006

16 mm round
cell
0.02 0.50
mg/l Al
-0.308
1.157
-0.748
0.237

10 mm cell
0.02 0.50
mg/l Al
-0.308
1.585
-1.403
0.609

10 of 17

Absorption-Concentration- Table for Aluminium Test, Cat. No. 1.14825.0001, calibration against distilled water.
Absorption 10 mm
cell
0.200
0.250
0.290
0.360
0.430
0.590
0.750
1.165
1.560
1.935
2.285

mg/l Al
0
0.05
0.10
0.15
0.20
0.30
0.40
0.60
0.80
1.00
1.20

Absorption 50 mm
cell
1.050
1.100
1.180
1.300
1.420
1.550
1.670
1.800
1.930
2.060
2.200

mg/l Al
0
0.020
0.040
0.060
0.080
0.100
0.120
0.140
0.160
0.180
0.200

Non-linear curve for Aluminium Test, Cat. No. 1.14825.0001, calibration against distilled water.
Non-linear
calibration
coefficient a:
coefficient b:
coefficient c:
coefficient d:

Date: October 24, 2006

10 mm cell
0.10 1.20
mg/l Al
-0.167
0.981
-0.378
0.092

50 mm cell
0.020 0.240
mg/l Al
-0.493
0.769
-0.348
0.065

11 of 17

Absorption-Concentration-Table for Calcium Cell Test, Cat. No. 1.00858.0001, calibration against distilled water.
Absorption 16 mm
round cell
0.075
0.100
0.170
0.245
0.330
0.450
0.575
0.705
0.835
0.950
1.075

mg/l Ca

mg/l CaCO3

mg/l CaO

0
10
35
60
85
115
145
175
200
225
250

0
25
88
150
213
288
363
438
500
563
625

0
14
49
84
119
161
203
245
280
315
350

Absorption 10 mm
cell
0.056
0.074
0.126
0.181
0.244
0.333
0.426
0.522
0.619
0.704
0.796

mg/l Ca

mg/l CaCO3

mg/l CaO

0
10
35
60
85
115
145
175
200
225
250

0
25
88
150
213
288
363
438
500
563
625

0
14
49
84
119
161
203
245
280
315
350

Non-linear curve for Calcium Cell Test, Cat. No. 1.00858.0001, calibration against distilled water.
Non-linear
calibration
coefficient a:
coefficient b:
coefficient c:
coefficient d:
Non-linear
calibration
coefficient a:
coefficient b:
coefficient c:
coefficient d:

Date: October 24, 2006

16 mm
round cell
10 250
mg/l Ca
-29.293
416.85
-252.27
99.158

16 mm
round cell
25 625
mg/l CaCO3
-73,418
1045
-634.44
249.09

16 mm
round cell
14 350
mg/l CaO
-41.011
583.59
-353.18
138.82

10 mm cell
10 250
mg/l Ca
-29.666
567.59
-473.01
253.87

10 mm cell
25 625
mg/l CaCO3
-74.353
1422.9
-1189.5
637.66

10 mm cell
14 350
mg/l CaO
-41.533
794.63
-662.22
355.42

12 of 17

Absorption-Concentration-Table for Magnesium Cell Test, Cat. No. 1.00815.0001, calibration against distilled
water.
Absorption 16 mm
round cell
0.070
0.085
0.120
0.150
0.190
0.235
0.285
0.335
0.385
0.435
0.490

mg/l Mg
0
5.0
13.0
20.0
28.0
36.0
44.0
52.0
59.0
67.0
75.0

Absorption 10 mm
cell
0.052
0.063
0.089
0.111
0.147
0.174
0.211
0.248
0.285
0.322
0.363

mg/l Mg
0
5.0
13.0
20.0
28.0
36.0
44.0
52.0
59.0
67.0
75.0

Non-linear curve for Magnesium Cell Test, Cat. No. 1.00815.0001, calibration against distilled water.
Non-linear

16 mm
round cell
5.0 75.0
mg/l Mg
-20.79
337.41
-513.33
458.21

calibration
coefficient a:
coefficient b:
coefficient c:
coefficient d:

10 mm
cell
5.0 75.0
mg/l Mg
-19.51
425.65
-778.18
892.38

Absorption-Concentration-Table for Nitrate Cell Test in sea water, Cat. No. 1.14556.0001, calibration against
distilled water.
Absorption 16 mm
round cell
0.000
0.085
0.260
0.480
0.725
1.000
1.275
1.600
1.900
2.200
2.500
2.700

mg/l NO3-N

mg/l NO3-

0
0.10
0.40
0.70
1.00
1.30
1.60
1.90
2.20
2.50
2.80
3.00

0
0.4
1.8
3.1
4.4
5.8
7.1
8.4
9.7
11.1
12.4
13.3

Absorption 10 mm
cell
0.000
0.063
0.193
0.356
0.537
0.741
0.944
1.185
1.407
1.630
1.852
2.000

mg/l NO3-N

mg/l NO3-

0
0.10
0.40
0.70
1.00
1.30
1.60
1.90
2.20
2.50
2.80
3.00

0
0.4
1.8
3.1
4.4
5.8
7.1
8.4
9.7
11.1
12.4
13.3

Non-linear curve for Nitrate Cell Test in seawater, Cat. No. 1.14556.0001, calibration against distilled water.
Non-linear
calibration
coefficient a:
coefficient b:
coefficient c:
coefficient d:
Date: October 24, 2006

16 mm
round cell
0.10 3.00
mg/l NO3-N
-0.01
1.6224
-0.3722
0.0687

16 mm
round cell
0.4 13.3
mg/l NO3-0.0442
7.182
-1.6478
0.3041

10 mm
cell
0.10 3.00
mg/l NO3-N
-0.0102
2.1895
-0.6766
0.1683

10 mm
cell
0.4 13.3
mg/l NO3-0.0454
9.6924
-2.9951
0.7449
13 of 17

Absorption-Concentration-Table for Nitrate Test in sea water, Cat. No. 1.14942.0001, calibration against
distilled water.
Absorption 10 mm
cell
0.000
0.050
0.160
0.300
0.580
0.860
1.140
1.410
1.700
1.980
2.350

mg/l NO3-N

mg/l NO3-

0.0
1.0
2.0
3.0
5.0
7.0
9.0
11.0
13.0
15.0
17.0

0
4.43
8.85
13.28
22.13
30.99
39.84
48.69
57.55
66.40
75.26

Non-linear curve for Nitrate Test in sea water, Cat. No. 1.14942.0001, calibration against distilled water.
Non-linear
calibration
coefficient a:
coefficient b:
coefficient c:
coefficient d:

10 mm cell
0.2 17.0
mg/l NO3-N
0.421
8.251
-0.5679
0.0335

10 mm cell
0.9 75.3
mg/l NO3-1.865
36.524
-2.515
0.149

Absorption-Concentration-Table for pH Cell Test, Cat. No. 1.01744.0001, calibration against dist. water.
Absorption 16 mm
round cell
0.000
0.100
0.175
0.330
0.500
0.600
0.800
1.020
1.325
1.700
1.900

pH
6.2
6.4
6.7
7.0
7.2
7.4
7.6
7.8
8.0
8.4
8.8

Absorption 10 mm
cell
0.000
0.074
0.130
0.244
0.370
0.444
0.593
0.741
0.981
1.259
1.407

pH
6.2
6.4
6.7
7.0
7.2
7.4
7.6
7.8
8.0
8.4
8.8

Non-linear curve for pH Cell Test, Cat. No. 1.01744.0001, calibration against dist. water.
Non-linear
calibration
coefficient a:
coefficient b:
coefficient c:
coefficient d:

Date: October 24, 2006

16 mm
round cell
pH 6.4 8.8
6.144
3.218
-2.318
0.714

10 mm
cell
pH 6.4 8.8
6.141
4.359
-4.231
1.755

14 of 17

Absorption-Concentration-Table for Residual Hardness Cell Test, Cat. No. 1.14683.0001, calibration against
distilled water.
Absorption 16 mm
round cell
0.100
0.220
0.350
0.470
0.600
0.750
0.900
1.200
1.500

mg/l Ca

mg/l CaCO3

mg/l CaO

0
0.50
1.00
1.50
2.00
2.50
3.00
4.00
5.00

0
1.25
2.50
3.75
5.00
6.25
7.50
10.00
12.50

0
0.70
1.40
2.10
2.80
3.50
4.20
5.60
7.00

0
0.070
0.140
0.210
0.280
0.350
0.420
0.560
0.700

0
0.088
0.175
0.263
0.350
0.438
0.525
0.700
0.875

0
0.125
0.250
0.375
0.500
0.625
0.750
1.000
1.250

Absorption 10 mm
cell
0.074
0.163
0.259
0.348
0.444
0.556
0.667
0.889
1.111

mg/l Ca

mg/l CaCO3

mg/l CaO

0
0.50
1.00
1.50
2.00
2.50
3.00
4.00
5.00

0
1.25
2.50
3.75
5.00
6.25
7.50
10.00
12.50

0
0.70
1.40
2.10
2.80
3.50
4.20
5.60
7.00

0
0.070
0.140
0.210
0.280
0.350
0.420
0.560
0.700

0
0.088
0.175
0.263
0.350
0.438
0.525
0.700
0.875

0
0.125
0.250
0.375
0.500
0.625
0.750
1.000
1.250

Non-linear curve for Residual Hardness Cell Test, Cat. No. 1.14683.0001, calibration against distilled water.
Non-linear
calibration
coefficient a:
coefficient b:
coefficient c:
coefficient d:
Non-linear
calibration
coefficient a:
coefficient b:
coefficient c:
coefficient d:

Date: October 24, 2006

16 mm
round cell
0.50 5.00
mg/l Ca
-0.46153
4.62293
-1.14084
0.32358

16 mm
round cell
1.25 12.50
mg/l CaCO3
-1.1538
11.557
-2.8521
0.8089

16 mm
round cell
0.70 7.00
mg/l CaO
-0.64615
6.4721
-1.59717
0.45301

16 mm
round cell
0.070 0.700
d
-0.06461
0.64721
-0.15972
0.0453

16 mm
round cell
0.088 0.875
e
-0.08077
0.80901
-0.19965
0.05663

16 mm
round cell
0.125 1.250
f
-0.11538
1.15573
-0.28521
0.08089

10 mm cell
0.50 5.00
mg/l Ca
-0.46099
6.23776
-2.0739
0.79354

10 mm cell
1.25 12.50
mg/l CaCO3
-1.15246
15.5944
-5.18475
1.98386

10 mm cell
0.70 7.00
mg/l CaO
-0.64538
8.73286
-2.90346
1.11096

10 mm cell
0.070 0.700
d
-0.06454
0.87329
-2.9035
0.1111

10 mm cell
0.088 0.875
e
-0.08067
1.09161
-0.36293
0.13887

10 mm cell
0.125 1.250
f
-0.11525
1.55944
-0.51847
0.19839

15 of 17

Absorption-Concentration-Table for Sulfide Test, Cat. No. 1.14779.0001, calibration against distilled water.
Absorption 10 mm
cell
0.000
0.080
0.220
0.350
0.490
0.600
0.770
0.890
1.080
1.200

mg/l S
0
0.10
0.25
0.40
0.55
0.70
0.90
1.05
1.35
1.50

Non-linear curve for Sulfide Test, Cat. No. 1.14779.0001, calibration against distilled water.
Non-linear
calibration
coefficient a:
coefficient b:
coefficient c:
coefficient d:

10 mm cell
0.10 1.50
mg/l S
0.0052
1.1079
-0.0055
0.1062

Absorption-Concentration-Table for Tin Cell Test, Cat. No. 1.14622.0001, calibration against distilled water.
Absorption 16 mm
round cell
0.000
0.040
0.230
0.500
0.780
0.980
1.190
1.370
1.650
1.900
2.150

mg/l Sn
0
0.10
0.40
0.70
1.00
1.20
1.40
1.60
1.90
2.20
2.50

Absorption 10 mm
cell
0.000
0.030
0.170
0.370
0.578
0.726
0.881
1.015
1.222
1.407
1.593

mg/l Sn
0
0.10
0.40
0.70
1.00
1.20
1.40
1.60
1.90
2.20
2.50

Non-linear curve for Tin Cell Test, Cat. No. 1.14622.0001, calibration against distilled water.
Non-linear
calibration
coefficient a:
coefficient b:
coefficient c:
coefficient d:

Date: October 24, 2006

16 mm
round cell
0.10 2.50
mg/l Sn
0.03
1.5544
-0.5016
0.147

10 mm
cell
0.10 2.50
mg/l Sn
0.03
2.0985
-0.9141
0.3617

16 of 17

Absorption-Concentration-Table for Total Hardness Cell Test, Cat. No. 1.00961.0001, calibration against
distilled water.
Absorption 16 mm
round cell
0.068
0.088
0.150
0.240
0.345
0.465
0.570
0.710
0.855
1.015
1.145

mg/l Ca

mg/l CaCO3

mg/l CaO

0
5
25
50
75
100
120
145
170
195
215

0
13
63
125
188
250
300
363
425
488
538

0
7
35
70
105
140
168
203
238
273
301

0
0.7
3.5
7.0
10.5
14.0
16.8
20.3
23.8
27.3
30.1

0
0.9
4.4
8.8
13.1
17.5
21.0
25.4
29.8
34.1
37.6

0
1.3
6.3
12.5
18.8
25.0
30.0
36.3
42.5
48.8
53.8

Absorption 10 mm
cell
0.050
0.065
0.111
0.178
0.256
0.344
0.422
0.526
0.633
0.752
0.848

mg/l Ca

mg/l CaCO3

mg/l CaO

0
5
25
50
75
100
120
145
170
195
215

0
13
63
125
188
250
300
363
425
488
538

0
7
35
70
105
140
168
203
238
273
301

0
0.7
3.5
7.0
10.5
14.0
16.8
20.3
23.8
27.3
30.1

0
0.9
4.4
8.8
13.1
17.5
21.0
25.4
29.8
34.1
37.6

0
1.3
6.3
12.5
18.8
25.0
30.0
36.3
42.5
48.8
53.8

Non-linear curve for Total Hardness Cell Test, Cat. No. 1.00961.0001, calibration against distilled water.
Non-linear
calibration
coefficient a:
coefficient b:
coefficient c:
coefficient d:
Non-linear
calibration
coefficient a:
coefficient b:
coefficient c:
coefficient d:

16 mm
round cell
5 215
mg/l Ca
-22.354
339.98
-195.26
69.671

16 mm
round cell
13 538
mg/l CaCO3
-55.594
849.94
-489.08
175.17

16 mm
round cell
7 301
mg/l CaO
-31.296
475.97
-273.36
97.54

16 mm
round cell
0.7 30.1
d
-3.1296
47.597
-27.336
9.754

16 mm
round cell
0.9 37.6
e
-3.8748
59.261
-33.641
11.864

16 mm
round cell
1.3 53.8
f
-5.5594
84.994
-48.908
17.517

10 mm cell
5 - 215
mg/l Ca
-22.177
457.29
-351.63
168.46

10 mm cell
13 538
mg/l CaCO3
-55.151
1143.2
-880.8
423.59

10 mm cell
7 - 301
mg/l CaO
-31.048
640.2
-492.29
235.85

10 mm cell
0.7 30.1
d
-3.1048
64.02
-49.229
23.585

10 mm cell
0.9 37.6
e
-3.844
79.71
-60.575
28.674

10 mm cell
1.3 53.8
f
-5.5151
114.32
-88.08
42.359

Please contact our local Merck companies or Merck agents for any questions. Alternatively contact:
environmental.analysis@merck.de

Date: October 24, 2006

17 of 17

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