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Fike offers Single-Time Valving Devices to assist in achieving effective intervention in runaway reactions as well as for effective discharge of reactor contents. Interface with proven early warning detection system (EWDS) capturing the start of the runaway reaction ahead of potentially catastrophic process dynamics is readily available.
Fike Europe B.v.b.a. Toekomstlaan 52 B2200 Herentals Belgium Tel. +32 14 210031 Fax +32 14 210743 email fike-europe@fike.com website http://www.fike.be Fike United Kingdom Maidstone England Tel. (01622)677081 Fax (01622)685737 email sales@fike.co.uk website http://www.fike.co.uk
Prevent
The occurrence of situations that can trigger the existence of exothermic/runaway reactions must be prevented. Following steps are generally considered by process designers and safety experts to assure a suitable safety level to handle reactive chemical hazards:
In order to deal with the hazards related to reactive chemicals one must identify the hazards, and then develop an understanding on possible frequency and effects/consequences. Hazard assessment must take into account all foreseeable process deviations and the consequences of their occurrence. Where the consequences are considered to be severe, risk analysis methodology must be used to identify all possible conditions that can lead to these events. Based on this analysis suitable strategies for accident prevention or protection of installations can be determined.
In some cases it may be possible to avoid or significantly reduce hazards by a change in plant design such as for example use of a lower quantity of hazardous materials in the process at any one time, the use of alternative (safer) materials, the use of less hazardous processing conditions or the use of semi-batch processing instead of batch processing. Such process plants are generally simpler with fewer opportunities for error, less dependant on additional safety systems and respond more slowly to change.
Designers shall anticipate all possible human errors and carefully evaluate scenarios where errors can lead to catastrophic results. The implementation of available protective measures such as temperature control, instrumentation and interlocks to eliminate opportunities for human error must be carefully considered. Evaluation of operating procedures must be included to minimize the likelihood of an undetected human error. Operators must be adequately trained and supervised before they are assigned to critical operations possibly leading to the initiation of uncontrolled reactions.
Fike Europe B.v.b.a. Toekomstlaan 52 B2200 Herentals Belgium Tel. +32 14 210031 Fax +32 14 210743 email fike-europe@fike.com website http://www.fike.be Fike United Kingdom Maidstone England Tel. (01622)677081 Fax (01622)685737 email sales@fike.co.uk website http://www.fike.co.uk
A runaway reaction, if caught early, can often be halted by adding a suitable chemical component to cancel the effect of the reaction catalyst. Early warning detection systems (EWDS) have been developed to assist in the timely detection and are available to the industry user. Common measures include neutralization, quenching with water or another suitable diluent or dumping the reactor content into another vessel which contains a quench media. In many cases the activation of additional or emergency (crash) cooling of the reactor content can be sufficient to remove the excess heat generated by the exothermic reaction.
Proper vent sizing for potential runaway exothermic reactions is complex, requiring data on heat and pressure generation occurring during the runaway. For this reason the application of traditional non-reactive discharge calculation methods can generally not be applied. For most reactive process effluent discharge systems the pressure rise due to the runaway may be extremely fast, making it necessary to assure fast, unobstructed discharge of the reactor content to a suitably designed handling system.
Fike Europe B.v.b.a. Toekomstlaan 52 B2200 Herentals Belgium Tel. +32 14 210031 Fax +32 14 210743 email fike-europe@fike.com website http://www.fike.be Fike United Kingdom Maidstone England Tel. (01622)677081 Fax (01622)685737 email sales@fike.co.uk website http://www.fike.co.uk
Fike Europe B.v.b.a. Toekomstlaan 52 B2200 Herentals Belgium Tel. +32 14 210031 Fax +32 14 210743 email fike-europe@fike.com website http://www.fike.be Fike United Kingdom Maidstone England Tel. (01622)677081 Fax (01622)685737 email sales@fike.co.uk website http://www.fike.co.uk
Fike offers solutions for all chemical process conditions where runaway reactions can not be tolerated and their effects must be controlled.
Fike Europe B.v.b.a. Toekomstlaan 52 B2200 Herentals Belgium Tel. +32 14 210031 Fax +32 14 210743 email fike-europe@fike.com website http://www.fike.be Fike United Kingdom Maidstone England Tel. (01622)677081 Fax (01622)685737 email sales@fike.co.uk website http://www.fike.co.uk
Fike Europe B.v.b.a. Toekomstlaan 52 B2200 Herentals Belgium Tel. +32 14 210031 Fax +32 14 210743 email fike-europe@fike.com website http://www.fike.be Fike United Kingdom Maidstone England Tel. (01622)677081 Fax (01622)685737 email sales@fike.co.uk website http://www.fike.co.uk