WOODLIFE F

Clear Wood Preservative Water Repellent FOR INDUSTRIAL USE ONLY

FOR MORE INFORMATION, CONTACT KOP-COAT:

436 Seventh Avenue Pittsburgh, PA 15219 412/227-2426 412/227-2618 (Fax) Email Address: Ask Our Experts:

5137 Southwest Avenue St. Louis, MO 63110 314/772-2200 314/772-1710 (Fax) ippd@kop-coat.com www.kop-coat.com

Medical Emergencies: 1-800-548-0489

GENERAL: Woodlife F is a unique blend of water repellent and wood preservative ingredients to be used to protect wood products in aboveground exposures. Woodlife F penetrates into wood and controls the growth of decay fungi, staining fungi, surface mold and mildew. It stabilizes wood against the effects of moisture and reduces dimensional changes that can cause swelling, warping and splitting. PRODUCT DESCRIPTION: Woodlife F is a clear penetrating nonswelling, paintable, water repellent wood preservative. The product is ready to use, colorless when dry and will not crack, blister, or peel. PRODUCT USE: PACKAGING: Woodlife F is an excellent treatment for millwork, shingles, siding, plywood, hardboard, flakeboard, structural lumber, fences, and other wood products. Woodlife F is used for the treatment of sash and other millwork components to meet the Hallmark program of the WDMA for a preservative water repellent (WDMA Standard IS-4). PREPARATION: ACTIVE INGREDIENTS: Machine, cut, glue and sand wood as desired before treating. Do not use over previously finished or stained wood without stripping off the old finish. Do not use steel wool. Wood must be clean and dry before treatment. APPLICATION: The temperature of the treating solution, wood and surrounding air must be above 40F (4.4C). Apply by immersion, flood coat, spray or brush. Do not use high pressure spray. Any surface cut after first treatment should be retreated. 3-Iodo-2-Propynyl Butyl Carbamate..........................0.50% INERT INGREDIENTS ..................99.50% TOTAL: .........................................100.00% STORAGE AND DISPOSAL: Storage: Store in a closed, properly labeled container in a cool place. If static generating conditions exist, provide necessary grounding and bonding. Keep containers closed when not in use. Drums Bulk IMMERSION: Millwork or other items to be painted should be treated 15 seconds for single pieces and 3 minutes for bundles. Treatment should be in accordance with WDMA Standard IS-4. FINISHING: The treatment should be completely dry and odor free before glazing, painting or varnishing. Allow 24 to 48 hours under average temperature and humidity conditions for drying. Forced heat drying is a good method to accelerate drying. Some species and types of wood products may take longer to dry. COVERAGE: 8 to 14 gallons per thousand board feet for open tank treatment and 200 square feet per gallon for brush application. Pesticide Disposal: Do not contaminate water, food or feed by storage or disposal. Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal law. If these materials cannot be used according to label instructions, contact your State Pesticide or Environmental Control Agency, or the nearest EPA Regional Office for guidance. Container Disposal: Triple rinse (or equivalent). Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill or by other procedures approved by state and local authorities.
ENVIRONMENTAL HAZARDS: This product is toxic to fish. For terrestrial uses, do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water by disposal of equipment wash-waters.

PHYSICAL PROPERTIES Combustible Liquid Flash Point ............................104F (TCC) Weight per gallon ...........................6.6 lbs. Vapor Density.................................... 5.0% Freezing Point.................................... <0F Vapor Pressure............................. 2mm Hg Evaporation Rate ................................ 0.15 Appearance and Odor ................................ amber liquid; petroleum odor VOC: Total:...................................6.44 lbs./gal. OTHER: For health and safety information, please refer to the Material Safety Data Sheet.
KOP-COAT, INC. Protection Products Division
PDWoodllife F Nov. 2000

REGISTRATIONS: EPA Reg. No. 60061-97 EPA Est. No. 60061-MO-1 Applicable State Registrations.

MATERIAL SAFETY DATA SHEET

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KOP-COAT, INC PROTECTION PRODUCTS 5137 SOUTHWEST AVENUE ST. LOUIS MO 63110

EMERGENCIES HEALTH/SPILLS......: CHEMTREC ASSISTANCE: CHEMTREC OUTSIDE US: CANUTEC............:

800-548-0489 800-424-9300 703-527-3887 613-996-6666

KOP-COAT, INC PRODUCT INFORMATION: 412-227-2700 OUTSIDE USA........: 412-227-2700 -------------------------------------------------------------------------------1 PRODUCT IDENTIFICATION -------------------------------------------------------------------------------PRODUCT NAME: PRODUCT USE.: APPEARANCE..: CAS NUMBER..: SYNONYMS....: Woodlife (R) F Clear Water repellent wood preservative Clear water-like liquid, petroleum distillate odor Mixture None REVISION...: 12 DATE.......: 1/29/04 MSDS NUMBER: 13130

-------------------------------------------------------------------------------2 HAZARDOUS INGREDIENTS -------------------------------------------------------------------------------HAZARDOUS COMPONENT Co-solvent CAS NUMBER:TRADE SECRET-CO PERCENT BY WGT: 5 TO 10 3-iodo-2-propynyl butyl carbamate CAS NUMBER:55406-53-6 PERCENT BY WGT: < 1 Naphtha, Heavy Hydrotreated CAS NUMBER:64742-48-9 PERCENT BY WGT: 85 TO 90 Ketones, Mixture CAS NUMBER:68990-20-5 PERCENT BY WGT: 5 TO 10 ACGIH TLV OSHA PEL REG AGENCY PPM NOTES MG/M3 NOTES

(None established.)

(None established.)

100 500

034 034

ACGIH TLV OSHA PEL

25 25

33 33

NOTES: 33) Exposure limits are for diisobutyl ketone. 034) Exposure limits are for stoddard solvent. -------------------------------------------------------------------------------3 HAZARDS IDENTIFICATION --------------------------------------------------------------------------------

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-------------------------------------------------------------------------------3 HAZARDS IDENTIFICATION -------------------------------------------------------------------------------EYE: Contact with liquid may cause moderate eye irritation if not promptly rinsed from eyes. SKIN: Contact with liquid may cause moderate skin irritation. Repeated or prolonged contact with the skin can result in defatting and drying of the skin which may result in skin irritation and dermatitis. INHALATION: May cause irritation to nose, throat and respiratory tract. Excessive exposure to solvents may cause central nervous system depression, including headache, dizziness, drowsiness or nausea. INGESTION: May cause vomiting, diarrhea and depressed respiration. Aspiration of material into the lungs due to vomiting can cause chemical pneumonitis, which may be fatal. Individuals with pre-existing disease in or a history of ailments involving the skin, eye, respiratory tract, liver, kidney or central nervous system are at a greater than normal risk of developing adverse effects when exposed to this material. -------------------------------------------------------------------------------4 FIRST AID MEASURES -------------------------------------------------------------------------------EYE CONTACT: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first five minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. SKIN CONTACT: Remove contaminated clothing. Wash affected areas immediately with soap and water for 15-20 minutes. Call a poison control center or doctor for treatment advice. INHALATION: Remove to fresh air. If breathing has stopped, call 911, then have a trained person administer artificial respiration, preferably mouth-to-mouth. Call a poison control center or doctor for further treatment advice. INGESTION: Call a poison control center immediately for treatment advice. Do NOT induce vomiting unless told to do so by poison control center or doctor. Do not give ANY liquid to the person. Do not give anything by mouth to an unconscious person. NOTE TO PHYSICIAN: Mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression and convulsions may be required. Although carbamates are known to cause cholinesterase inhibition, 3-iodo-2-propynyl butyl carbamate did not inhibit cholinesterase in animal tests. -------------------------------------------------------------------------------5 FIRE FIGHTING MEASURES --------------------------------------------------------------------------------

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-------------------------------------------------------------------------------5 FIRE FIGHTING MEASURES -------------------------------------------------------------------------------FLASH POINT: 105F/41C AUTOIGNITION TEMPERATURE: Not determined. FLAMMABLE LIMITS (% by volume/air) Lower Limit: Not determined. Upper Limit: Not determined. EXTINGUISHING MEDIA: Use dry chemical, carbon dioxide, or foam. FIRE FIGHTING PROCEDURES: As in any fire, wear complete fire service protective equipment, including full-face MSHA/NIOSH approved or equivalent self-contained breathing apparatus. Use water to cool fire-exposed container/structure/protect personnel. Do not put in contact with oxidizing or caustic materials. FIRE AND EXPLOSION HAZARDS: Solvent vapors are heavier than air and may travel along the ground or be moved by ventilation and ignited by flames and ignition sources. Never use welding or cutting torch on or near drum (even empty), because product residue can ignite explosively. Containers may explode if exposed to extreme heat. Eliminate sources of ignition. -------------------------------------------------------------------------------6 SPILL AND LEAK PROCEDURES -------------------------------------------------------------------------------SMALL SPILL: Absorb spill with an inert material (e.g., sand or earth), then place in a chemical waste container for proper disposal. Take up carefully to avoid heat and sparks. Keep spills out of sewers and open bodies of water. LARGE SPILL: Isolate hazard area and deny entry. Shut-off ignition sources (flares, flames, including pilot lights, electrical sparks). Dike and contain spilled liquid with sand or earth. Do not use combustible products such as sawdust. Pump to storage or salvage vessel. Prevent run-off to sewers, streams or other bodies of water. If run-off occurs, notify proper authorities that a spill has occurred. -------------------------------------------------------------------------------7 HANDLING AND STORAGE -------------------------------------------------------------------------------HANDLING: Avoid prolonged or repeated breathing of vapors or mists and contact with skin or eyes. Observe good personal hygiene practices and recommended procedures. Wash thoroughly after handling. Ground and bond containers when transferring. STORAGE: Store in areas/buildings designed to comply with OSHA 29 CFR 1910.106. Keep in a closed, labeled container within a cool (well-shaded), dry, ventilated area. Protect from physical damage. Keep containers closed when not in use. Store away from caustics and oxidizers. OTHER: Showering and clothing change recommended at the end of each shift. Keep containers from excessive heat and freezing. Intentional misuse by deliberately

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-------------------------------------------------------------------------------7 HANDLING AND STORAGE -------------------------------------------------------------------------------concentrating and inhaling vapors may be harmful or fatal. -------------------------------------------------------------------------------8 EXPOSURE CONTROLS/PERSONAL PROTECTION -------------------------------------------------------------------------------ENGINEERING CONTROLS: Provide sufficient mechanical ventilation (local or general exhaust) to maintain exposures below current exposure limits. Vapors are heavier than air and will collect in low areas. Check all low areas for vapors before entering. RESPIRATORS: If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, an approved respirator must be worn. Respirator selection, use and maintenance should be in accordance with the requirements 29 CFR 1910.134. PERSONAL PROTECTIVE EQUIPMENT: Industrial safety glasses, minimum. As necessary for work area conditions: use side shields, goggles, or faceshield. As required, chemical resistant, flexible type gloves (nitrile, neoprene, or equal). Wear industrial-type work clothing and safety footwear. Depending on working conditions, i.e., contact potential, wear impervious protective garments such as head/neck cover, gloves, aprons, jackets, pants, coveralls, boots, etc. Wash contaminated clothing before reuse. -------------------------------------------------------------------------------9 PHYSICAL AND CHEMICAL PROPERTIES -------------------------------------------------------------------------------Weight Per Gallon (lbs): 6.490 % VOL by Weight.: Vapor Density.: (Air=1)>1 Boiling Point...: Vapor Pressure: Not determined Evaporation Rate: pH............: Not applicable Specific Gravity: Solubility In Water: Negligible Viscosity.......: VOC Content................: Refer to Product Data Sheet Not determined Not determined (Butyl Acet=1)<1 < 1 Not determined

-------------------------------------------------------------------------------10 STABILITY AND REACTIVITY DATA -------------------------------------------------------------------------------STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur. INCOMPATIBILITY: Strong oxidizers and caustics. HAZARDOUS DECOMPOSITION PRODUCT(S): Carbon dioxide, carbon monoxide, and oxides of nitrogen. -------------------------------------------------------------------------------11 TOXICOLOGICAL INFORMATION --------------------------------------------------------------------------------

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-------------------------------------------------------------------------------11 TOXICOLOGICAL INFORMATION -------------------------------------------------------------------------------Contact Kop-Coat for information. -------------------------------------------------------------------------------12 ECOLOGICAL INFORMATION -------------------------------------------------------------------------------Product has not been tested for ecotoxicity. -------------------------------------------------------------------------------13 DISPOSAL CONSIDERATIONS -------------------------------------------------------------------------------Dispose of according to federal, state and local regulations. Discarded material should be incinerated at a permitted facility. Do not reuse empty container. Liquids cannot be discarded in a landfill. -------------------------------------------------------------------------------14 TRANSPORTATION INFORMATION -------------------------------------------------------------------------------DOT information for domestic ground transportation: DOT PROPER SHIPPING NAME: Combustible liquid, n.o.s. (Mineral spirits) DOT HAZARD CLASS: 3 PG III LABEL: Wood Preservatives DOT IDENTIFICATION NUMBER: NA1993 DOT information for domestic air transportation: DOT PROPER SHIPPING NAME: Flammable liquid, n.o.s. (Mineral spirits) DOT HAZARD CLASS: 3 PG III LABEL: Flammable DOT IDENTIFICATION NUMBER: UN1993 -------------------------------------------------------------------------------15 REGULATORY INFORMATION -------------------------------------------------------------------------------SARA TITLE III SECTION 313 CHEMICALS 3-iodo-2-propynyl butyl carbamate Woodlife F RTU EPA REGISTRATION NUMBER: 60061-97 Pest Control Products Act Registration Number: 25696 WHIMIS Classification: B3, D1B -------------------------------------------------------------------------------16 OTHER INFORMATION -------------------------------------------------------------------------------Ketone, Mixture (CAS# 68990-20-5) is comprised primarily of high boiling ketones and methyl n-amyl ketone (CAS# 110-43-0).

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-------------------------------------------------------------------------------16 OTHER INFORMATION -------------------------------------------------------------------------------NOTICE: While the information and recommendations set forth herein are believed to be accurate as of the date hereof, Kop-Coat, Inc. makes no warranty with respect thereto and disclaims all liability from reliance thereon. PREPARED BY: Manager of Health Safety and Environmental Affairs