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CORROSION PREVENTION AND REMOVAL SYSTEM
Best Solution to Paraffin, Scale and Corrosion Problems
Table of Contents
SYSTEM DESCRIPTION ... .................................................................................................................... ...5
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CORROSION PREVENTION AND REMOVAL SYSTEM
Best Solution to Paraffin, Scale and Corrosion Problems
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CORROSION PREVENTION AND REMOVAL SYSTEM
Best Solution to Paraffin, Scale and Corrosion Problems
Scientige Sdn. Bhd, Suite 8-11, 8th Floor, Wisma UOA 2, No.21, Jalan Pinang, 50450 Kuala Lumpur
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CORROSION PREVENTION AND REMOVAL SYSTEM
Best Solution to Paraffin, Scale and Corrosion Problems
SYSTEM DESCRIPTION
Patented Products
The system design, material composition and metallurgical processing have been patented in
USA, Canada, Mexico and some other countries. The USA patents include: 4,789,031US,
D446,797 S, and US 473,925.
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CORROSION PREVENTION AND REMOVAL SYSTEM
Best Solution to Paraffin, Scale and Corrosion Problems
Scientige Sdn. Bhd, Suite 8-11, 8th Floor, Wisma UOA 2, No.21, Jalan Pinang, 50450 Kuala Lumpur
Tel: +603-2161 8696 Fax: +603-2161 5696 www.scientige.com
CORROSION PREVENTION AND REMOVAL SYSTEM
Best Solution to Paraffin, Scale and Corrosion Problems
Scientige Sdn. Bhd, Suite 8-11, 8th Floor, Wisma UOA 2, No.21, Jalan Pinang, 50450 Kuala Lumpur
Tel: +603-2161 8696 Fax: +603-2161 5696 www.scientige.com
CORROSION PREVENTION AND REMOVAL SYSTEM
Best Solution to Paraffin, Scale and Corrosion Problems
Operation Features
• Reduced downtime
Operation Principle
CPRS is comprised of nine dissimilar metals as Copper, Zinc and Nickel, etc., which can form a
special catalyst to enable a change in electrostatic potential, and also polarize the liquid
molecular or minerals, therefore the following performance can be achieved:
• Removal of existing paraffin, scale and rust on the surface of the equipment and
flowlines;
Tool types
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CORROSION PREVENTION AND REMOVAL SYSTEM
Best Solution to Paraffin, Scale and Corrosion Problems
Technical Specification
Downhole Tools
Type Bar Style Downhole Unit Tubing Joint Style Downhole Unit
Cartridges 10.0”(L)X0 .75” (OD) Bar Style Downhole Tool Bar Style Downhole Tool
Flow
90 GPM (20M3/hour) 90 GPM (20M3/hour) 90 GPM (20M3/hour)
Capacity
Installation Nipples, adaptors or threads Standard Tubing Threads, Box Up and Pin Down
Surface Tools
Size 2” 3” 4” 6” 8” 2” 3” 4” 6” 8”
Plate Nos. 4-6 4-6 4-6 4-6 4-6 4-6 4-6 4-6 4-6 4-6
Flow Capacity
Typical Applications
Downhole Application
• Flowing Wells
• Pumping Wells
• Gaslifting Wells
Surface Application
• Boiler/Any heat water facilities
• Cooling Towers
• Heat Water Systems
• Production Facilities
• Water Injection Wells
• Petrochemical Plants
• Oilfield Pipelines
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CORROSION PREVENTION AND REMOVAL SYSTEM
Best Solution to Paraffin, Scale and Corrosion Problems
BEFORE the CPR system was installed, 30 days AFTER the installation of CPR
filters were changed every 6 days and system, filters were changed for the first
chemicals were used everyday time. No chemicals are being used
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CORROSION PREVENTION AND REMOVAL SYSTEM
Best Solution to Paraffin, Scale and Corrosion Problems
The CPRS consists of a special alloy that acts as a catalyst and effects colloidal dispersions
in water. It is used to treat water for service in homes, buildings, air conditioning, and refrigeration
units, boilers, and heat exchangers, to name a few. Since this treatment is catalytic in action, it is
economical for continuous treatment. Nothing is added to the water and, other that a degassing
effect, nothing is removed from the water. The most important commercial application of
CPRS is that problems due to scale formation in various water systems are either eliminated or
dramatically decreased.
A catalyst, by definition, is an agent that allows an action, either chemical or physical, change, to
occur at a high and practical rate and without the agent being consumed in the process. Such
catalyzed reactions thus can be achieved advantageously at reasonable condition (temperature, etc.)
whereas these reactions might not occur to even a detectable extent under non-catalyzed but
otherwise extreme conditions.
A colloid is an aggregate of ions or molecules that is small enough to pass through a filter paper and
is easily kept as a suspension of usually undetectable particles. Colloidal suspensions may be stable
for quite some time and unless they are modified, typically do not form larger aggregates or
precipitates.
Nature of Water
In order to understand how a catalyst affects such a stabilized colloidal suspension in water, one
must understand what ingredients are present in normal water and how those ingredients might be
changed.
Water normally picks up certain salts and gases as it percolates through the earth, the exact
content of which varies with exposure to local and regional soils, rocks, etc. Rain is close to the
makeup of distilled water but has a small amount of impurities, like fine airborne dirt, etc., which
are acquired on passage through the atmosphere and particularly when it contacts some
collection system. Even distilled water or de-ionized water has traces of impurities that arise
from their process, piping, and containers. For research purposes water can be purified through
approximately a five-step process but may also cost up to $50 per gallon. However, water for
consumption has to have some minerals, as these are vital to life processes. Water treatment for
public use may involve chlorination for bacterial control, flocculation and filtration of
objectionable sediments.
Total solids (TS) is a measure of the entire gamut of things in water ranging from suspended dirt to
dissolved salts. To determine TS, the liquid is simple evaporated and the residue weighed.
Turbidity (TURB) is the cloudiness or muddy character of a solution. Turbidity indicates the
true dispersed or suspended solids, including non-filterable colloids, but gives no value for the
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CORROSION PREVENTION AND REMOVAL SYSTEM
Best Solution to Paraffin, Scale and Corrosion Problems
truly dissolved salts. Turbidity tests are made and compared to standard cloudy solutions, usually
stabilized colloids that have an opaque character.
Conductivity (COND) is an electrical measurement of a solution. The greater the dissolved salt
content, the greater the conductivity. In clear water, COND is proportional to TS. High
conductivity water has a salt or saline hazard to soil and crops.
Total Hardness(TM) is the amount of certain cations, Ca++ plus Mg++ and others such as iron.
Hard water has a high scale-forming tendency, requires more soap to just counteract these hard
cations (by forming soap curds), and does not taste good. High iron content not only causes
unsightly staining of surfaces but also acts as a promoter for the formation of other scales.
Alkalinity (ALK) & pH are terms that five information as to the amount of reactible base or
acid. In normal water, these terms relate to the amounts of carbonate and bicarbonate ions.
Bacteria (BACT) typically measured in drinking water as a check on its suitability. However,
industrial concern is usually for an iron bacterium, which feeds upon sulfate ions in water and
converts them to sulfide ions. The sulfide ions attack metallic iron directly where the bacteria are
attached which physically damages the surface and results in more iron ions in the water.
Reverse osmosis water conditioners remove most of the calcium and magnesium from water and
replace them with sodium, which does not have hardness properties. This type of softener
requires periodic recharging with sodium salts as they are consumed in the process. While
chemically softened water is excellent for washing purposes, it is not good for drinking or
irrigation. Softened water requires very little soap to make the initial suds, as in the “green-soap
hardness test”.
The CPRS is not a water softener as described above. It removes absolutely no minerals from the
water, so hard water will still have exactly the same hardness elements as before treatment with
the CPRS. Therefore, CPRS treated water requires exactly the same amount of soap to form the
initial suds as does raw water. However, CPRS treated water is physically different. Its
suspending qualities are modified by catalytic action so that a weak suds solution performs like a
strong suds solution. The increased efficiency of dirt removal lowers the total soap consumption
to the point where chemical softening is often found unnecessary. Furthermore, CPRS treated
water provides superb rinses, and often prevents curds, scales, and scum from sticking to any
other object.
Partially fill two containers with water, one with raw water and one with CPRS treated water
Add a handful of clay dirt to each, stir briefly, and let stand for about 20 minutes. Pour off the
excess water and then literally feel the difference between the two muds with your hand. Note the
dispersed or disintegrated condition of the mud in the CPRS treated water and the smooth slippery
feeling. The clay platelets are easily dispersed into colloidal sizes.
Pitting is by far the most common variety of corrosion in hot water pipes, bailer tubes, condenser
tubes, and other heated surfaces. The major cause of pitting is entrained corrosive gases. For
example: water containing millions of molecules of dissolved oxygen gas will deposit these as
globules at several favored spots on a metal surface when heated. The oxygen naturally oxidizes
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CORROSION PREVENTION AND REMOVAL SYSTEM
Best Solution to Paraffin, Scale and Corrosion Problems
the metal at these selective points until good size craters are formed, eventually resulting in
pinhole leaks. Carbon Dioxide similarly forms at certain points due to the breakdown of the
naturally occurring bicarbonates, which are also present in much higher amounts than oxygen.
Globules of carbon dioxide react locally with water forming carbonic acid, which can quickly eat
through an unprotected metal.
• Prevents corrosion.
Since it is catalytic in action, potentially large savings are possible as most consumed chemical
costs are avoided.
CPRS uses an exclusive metal alloy that acts as a catalyst, which effects colloidal dispersion
thereby enhancing the physical properties of the water. Nothing is added to or extracted from the
water other than a degassing effect to improve its quality. This is extremely helpful since
entrained gasses are the chief cause of pitting on metal surfaces. Because the effect is catalytic in
action, scaling, corrosion, and pitting are prevented without the use of chemicals, electricity or
magnets. CPRS is practically maintenance free. There are no messy filters to clean or replace.
CPRS is completely self-contained and installs directly in your existing line. Many different
models are available to satisfy your specific line size and gallon per minute requirements. Due to our
unique in-line design, convenient installation may be performed virtually anywhere.
CPRS is the non-chemical answer to problems of scale and corrosion in your commercial water
system. It has applications for the following situations:
• Bottling Plants
• Car Washes
• Cooling Towers
• Boilers
• Dairies
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CORROSION PREVENTION AND REMOVAL SYSTEM
Best Solution to Paraffin, Scale and Corrosion Problems
• Factories
• Garden Ponds
• Green Houses
• Hospitals
• Hotels
• Ice Machine/Plants
• Laundries
• Municipalities
• Photo Labs
• Power Plants
• Swimming Pools
• Universities
• Water Heaters
• Water Works
• Calcium carbonate (CaCO3) and magnesium carbonate (MgCO3 ) (with binders). This
forms in oil well rods and tubing and surface equipment.
• Rust (in galvanized pipes) or corrosion (in/on copper, brass, aluminum, or chrome).
In order to understand the process by which CPRS inhibits scale buildup (commonly called
“lime” or “rust”) and the way in which it breaks down and eliminates existing scale, it is
necessary to understand the nature of scale and how it is formed.
Calcium carbonate, CaCO3, exists in nature as limestone and marble; Silica (SiO2), alumni
(Al2O3) and calcium sulfate (CaSO4) are principal impurities in limestone and function as binders
(cementing agents). Large deposits of magnesium carbonate (MgCO3) exist in nature with
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CORROSION PREVENTION AND REMOVAL SYSTEM
Best Solution to Paraffin, Scale and Corrosion Problems
CaCO3 is only very slightly soluble in water, yet large amounts of calcium become dissolved in
most water supplies by the action of rainwater on limestone. Rainwater is somewhat acidic
because as it falls through the atmosphere, it encounter carbon dioxide (CO2) with which it reacts to
form carbonic acid (H2CO3) as follows:
When rainwater contacts limestone in the earth, limestone material is dissolved and goes into
solution as calcium bicarbonate as follow:
H2CO3 H+ + HCO3-
K1= _ÒH+_Ó*_ÒCO32-_Ó
(HCO3-)
The addition of H+ ions from the carbonic acid reduces the concentration of CO32- (ions that go into
solution in the water from the CaCO3 solid) because the H+ ion and the CO32- ion combine to form the
slightly ionized bicarbonate ion, HCO3-. The reduction of the concentration of CO32- ion in the
solution causes more CaCO3 to dissolve in the form of Ca2+ + 2HCO3- in an attempt to saturate
the solution and produce product of the concentrations of Ca2+ and CO32- ions that equals the
solubility product:
Surface waters also dissolve carbon dioxide from soils where it is produced by the slow
oxidization and decay of organic materials. As these waters contact limestone, the limestone
gradually dissolves. Examples of this action are limestone caves and hard water from wells.
The Ca2+ and 2HCO3- that dissolved in water very readily converts into CaCO3 when water is
heated. The amount of Ca2+ and 2HCO3- ions that remain in solution decreases with increases in
temperatures and precipitation as CaCO3 occurs as follows:
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CORROSION PREVENTION AND REMOVAL SYSTEM
Best Solution to Paraffin, Scale and Corrosion Problems
This is the basis reaction that forms the bulk of the “lime” in water heaters and boilers. This
reaction also occurs when water containing Ca(HCO3)2 evaporates and leaves a CaCO3 residue.
The above-mentioned reactions also apply magnesium and its bicarbonates and carbonates.
For example:
Scientists and engineers who have investigated scale formation various industrial systems have
determined that although MgCO3 and CaCO3 form most of the mass in lime type scale, they
require silica (SiO2), alumna (Al2O3), or calcium sulfate (CaSO4) to act as a binder to hold them in
place just as they do in nature.
CaSO4 exists in ionized for when dissolved in water as the ions Ca2+ and SO4 2- The solubility of
CaSO4 increases with temperature up to about 100°F and then decreases with increasing
temperature. Hence precipitation of CaSO4 also occurs in water heaters and boilers.
SiO2 and Al2O3 are not ions but are relatively neutral colloidal residues that are slightly soluble in
water. SiO2 is found in fresh water in a range of 1-100mg/L. At high concentrations (over 50
mg/L), chemical precipitation appears to occur.
. .
Colloids, including SiO2 , Al2O3 and clay(SiO2 Al2O3 12H2O)when suspended in water usually
carry a negative charge. If these negative charges (extra electrons) are neutralized (extra electron
removed), the colloids COAGULATE, PRECIPITATE, AND COMBINE WITH (i.e., become
absorbed by) CaCO3, MgCO3 and CaSO4 to form typical lime scale. The density and hardness of the
scale increases with increase concentration of SiO2, Al2O3, and/or CaSO4.
Approximately 87% of the earth’s solid crust consists of silicon compounds. Silica is one of the
most abundant compounds of silicon. Aluminum is the most abundant metal and the third most
abundant element. The most important one of aluminum is bauxite, a mixture of hydrated
aluminum oxide, Al2O3•3H2O, and iron oxide. Calcium is fifth in abundance of the metals in the
earth’s crust, of which it forms more than 3 %.
CPRS alloy consists of many precious and semiprecious metals that form a special
electrochemical catalyst. In addition, the tool is configured to prevent flow restriction while
providing a high degree of turbulence and increased physical contact between the ions and
molecules in the water and the tool itself, in order to maximize catalytic efficiency.
All metals give up electrons in their outer atomic shells easily. For this reason, metals are
excellent electrical conductors. Of all non-radioactive metals, cesium is the least acquisitive; it
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CORROSION PREVENTION AND REMOVAL SYSTEM
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has an Electro negativity of 0.7 on the Electro negativity Scale of the Elements. Gold is the most
electron acquisitive of the metals and has an Electro negativity of 2.4 on the Electro negativity
Scale. The higher the electro-negativity the more acquisitive the element (atom) is concerning
electron for its outer shell to satisfy its own valance.
The electro negativity of the core alloy is less than the overall electro negativity of the water
solution. Therefore, the core loses (gives up) more electrons than it acquires to elements such as
hydrogen (H+) ions, which have an electro-negativity of 2.1 and to ionic compounds (radicals) such
as SO42- and CO32-, which have higher electro negativities than the core alloy.
The relatively large distances between the nucleus and the electrons of atoms have been
described as follows: If an atom were as large as a house, its nucleus (which is positively charged)
would be smaller than specks of dust that float in the air. When bonded with another atom(s), the outer
orbital shell is pulled out into an egg shape even beyond the boundaries of the walls of the house
because of the attraction of other atom(s).
When water is in the form of ice, the molecules and ions in it are in a relatively rigid pattern. But
in the liquid state, this structure becomes a dynamic, whirling, chaotic dance in which groups of
molecules and ions in the solution take turns whirling around one another, breaking their bonds,
and finding new groups to find partners with. When water rushes through the catalytic alloy
conditioner, the pattern becomes even more frenetic, and electron orbits and associated bonding
undergo increased perturbations and stresses, and additional electrons from the core into the
water solution.
solution
The loss of electrons by CPRS catalytic alloy to the water solution is easily verifiable by: (1)
adapting a catalytic alloy conditioner to a garden hose, (2) turning on the hose faucet, (3)
connecting the positive lead of a multimeter to the conditioner core, (4) inserting the negative
lead probe into the water stream and (5) observing a voltage drop (i.e. the core goes positive with
respect to the water). The fact that the conditioner goes positive with respect to the outer water
stream indicates that electrons are being removed from the catalytic alloy conditioner by the
water solution as it flows through the core.
Electromotive Series
Earlier, the electro negativities of various elements were listed to indicate their relative potentials or
dispositions regarding electron acquisitiveness. Electron acquisitiveness can be regarded as
“reduction potential”. Reduction of an element occurs when its valence becomes more negative (or
less positive); for example in the reaction
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CORROSION PREVENTION AND REMOVAL SYSTEM
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One atom of Cl0 is reduced to Cl- oxidation, which is the opposite of reduction, occurs to an
element when its valence become more positive (or less negative) for example, in the equation
2Cl- is oxidized to Cl20 to provide chlorine gas plus two electrons, which are available (or can be
made available) for reduction of another substance in the solution or circuit
The Electromotive series is a listing of elements and compound rank ordered according to their
oxidation potentials or dispositions regarding electron relinquishment (or their tendency to lose
electrons). The higher (i.e. the more positive) the oxidation potential of an element is, the better the
element is as a reducing agent.
The Electromotive series and Electro negativity listing provide fundamental frames of reference
and some insight into (1) the many ways in which the elements can interact with each other, (2)
why they interact as they do, (3) under what conditions changes or reactions will occur or will
not occur, and (4) the reasons that metals can function as catalytic as catalytic water conditioning
agents.
Electrons are drawn into the water solution the water because the solution contains ions that are
more electronegative than catalytic alloy conditioners core is. Or in terms of the electron series,
catalytic alloy conditioner core contains elements, which have higher oxidation potentials than in
the water solution, As the water flows through the catalytic alloy conditioner, some of the
electrons drawn into the solution displace some already captured ion such as CO32-, HCO3-, SO42-
and OCl- during the turbulent orbiting of the various electrons. This allows the “displaced”
electrons to become “free electrons” in the solution and these “free electrons” can be captured by
ions or colloids with lesser electron negativities such as Ca2+, Mg2+, SiO2, Al2O3 and Fe2O3. This
allows Ca2+ and Mg2+ to free themselves of CO32- , SO42- and HCO3-, and assume their
assume their atomic structures (Ca0 and Mg0)and break away from their ionic bonds while in
solution or from lattice scale bonds in cases where they are in solid precipitated or scales form.
The increased electron count in the water also inhibitors the breakdown of the bicarbonate ion
into H+ and CO32-, when heated water in water heaters and boilers or when alkalinity reaches
levels above pH 8.4.
By acquiring or reacquiring a negative charge, colloidal substances such as silica, alumni, and rust
particles remain in suspension instead of becoming absorbed onto calcium, magnesium and iron
ions; the acquisition of the negative charge also causes these colloidal substances to be repelled
from these ions in the flowing water or they were already onto them. This separation inhibits the
hardness effects of these three ions; hardness in water is always due to the presence of Ca2+, Mg2+
and Fe2+ ions.
The silica and alumna are also able to escape from existing scale lattices to which they have been
absorbed and for which they have been functioning as binders, Thus, the scale lattices are
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CORROSION PREVENTION AND REMOVAL SYSTEM
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gradually broken down and eliminated by the escaping Ca0 and Mg0 elements and negatively
charged SiO2(-) and Al2O3(-) colloids.
The inhibiting effects of the catalytic alloy conditioner on scale formation can be summarized as
follows:
Heat
(6) HCO3- + xe- HCO3- + xe- (inhibition of the CO32- , H2O , CO2)
Heat
(7) Ca + 2HCO3- Ca0 + H2O + 2CO2
0
Heat
(8) 2CO32- 2CO2 + O2 + 4e-
Heat
(9) 2HCO3- + xe 2HCO3- + xe- ( inhibitor of breakdown to CO32- , H2O, CO2)
-
Rust is a type of corrosion involving the special case of iron. Rust formation requires three
electrochemical steps:
Loss of metal occurs in an anodic area (anode) of the surface. In the case of iron, iron (Fe0) is lost to
the water solution and becomes oxidized to Fe2+ ion.
As a result of the formation of Fe2+, two electrons are released from the Fe atom and flow
through to a cathodic area (cathode).
Oxygen (O2) in the water solution moves to the cathode and completes the electric circuit by
using the two electrons that moved to the cathode to form hydroxyl ions (OH-) at the cathode
area. The reaction is as follow:
Or e- + H+ H0
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CORROSION PREVENTION AND REMOVAL SYSTEM
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If oxygen is absent, hydrogen ions (H+) participate in the reaction (equation (3)) at the cathode
instead of oxygen and complete the electrical circuit. The Fe2+ and OH- ions combine to form
ferrous hydroxide as follows:
Corrosion is inhibited if the iron is made more negative compared to its surroundings, forcing the
anode areas to act as cathodes. This is accomplished by the attraction of some of the extra
electron in the water solution (supplied by CPRS) onto the anodic areas, thereby preventing the
ionization of the Fe atoms. The additional electrons also dissolve rust by breaking it into fine
colloidal particles. In a similar manner, corrosion is also inhibited and dissolved for metal other
than iron such as brass and aluminum. It is interesting to note that the addition of electrons to
anodic areas in order to prevent corrosion has been accomplished by other means in the industry;
this method has been called “cathodic protection”. Zinc plating is one example of this method of
cathodic protection since zinc has a higher oxidation potential than iron and forces electron onto
the iron. Cathodic protection has also been obtained by driving stakes of magnesium or zinc into
the ground and connecting them to pipelines or stand pipes to be protected. Water scientists have
found that in addition to rust formed simply by corrosion, rust can be formed and deposited by
iron depositing bacteria in the water such as Sphaerotilus and Gallionella. Iron depositing
bacteria prefer water high in ferrous iron, which then convert to insoluble ferric hydroxide,
Fe(OH)3, which becomes part of the mucilaginous sheath around the cell. These deposits on
galvanized steel pipes and accelerate corrosion rates, which produces additional soluble iron,
further increasing the population of iron, further increasing the population of iron depositing
bacteria in the system. The cycle sometimes continues until the whole system is plugged with
oxidized iron deposits or until a pipe becomes rusted all the way through its walls. The
cathodizing function of the catalytic alloy conditioner also cause the Fe(OH)3 to break up into
fine colloidal particles and go into suspension.
Cleaning Period
For some period of time after a CPRS is installed, especially in older systems, its action of
loosening scale, sediment, and dirt may be limited. During this time the water will be overloaded
with particles loosened from mostly the parts closest to CPRS. This over suspended
concentration of particles may interfere with mechanical action at functional points in the system.
Traps and screens may need to be checked and cleaned very often until the system is cleaned.
After the system is cleaned, CPRS will accomplish the desired results for the entire system.
Be advised that if the condition of the piping system is badly corroded and held together by hard
scale, when CPRS removes scale, leaks may develop, and thus repairs may be anticipated.
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CORROSION PREVENTION AND REMOVAL SYSTEM
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Summary
In accordance with electro-negativities of chemical elements and the oxidation potentials of the
elements listed in the Electro-negativity scale and the electromotive series, respectively. CPRS
catalytic alloy provides electrons to the water solution in a catalytic manner or reduce electron
deficiencies in the water. This enables electrochemical changes to occur that
• Inhibit algae fungus and mildew growth. Because of the bipolar mature of all formed
metals. The conditioner also removes electrons from some negative ions. However the
conditioner provides for a significant net increase of electrons for the ions and colloids
in the water solution, resulting in
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CORROSION PREVENTION AND REMOVAL SYSTEM
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Petroleum crude oil consists of four factions, namely oil constituents, resin, asphaltene and
preasphaltene (i.e. carbene and carboid). The chemical and physical properties of crude oils
depend significantly on the relative amounts of each faction and their properties. The asphaltenes
usually contain more condensed aromatic compounds than do the resin and oil factions. The
resins contain aromatic or naphthenic hydrocarbons and components of oil factions may have
napthenic or paraffin structures. Asphaltenes and preasphaltenes in their natural state exist in
micelle form, peptized with resin molecules.
The center of this micelle can be metal, clay, or water. The essential feature is that the polar
groups (such as S-“negative” and/or N-“negative” and/or O- “negative” containing groups) are
concentrated towards the center. This often is termed oil external-water internal or water-in-oil
emulsion. When crude oils flow into a wellbore, its pressure and temperature decreases. Paraffin and
water then would be released from the water-in-oil emulsion, with the paraffin solidifying at the
reduced temperature condition.
As stated above, crude oils are made up of factions, which contain paraffin and water. When
crude oil flows into a wellbore, pressure and temperature are reduced. As the oil/water solution
cools, the paraffin changes to a solid form. The paraffin deposits obstruct the flow of crude oil and
water particles problems.
CPRS can provides an electrochemical change, which stabilizes the water-in-oil emulsion
structure and prevents paraffin being released from the micelle structure and forming solid states.
This allows the solution to move smoothly and cleanly through the pipe without causing deposit
problems.
Summary
The alloy composition of CPRS provides electrons to the crude in catalytic manner to reduce
electron deficiencies in the crude. This enables electrochemical changes to occur that:
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Best Solution to Paraffin, Scale and Corrosion Problems
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CORROSION PREVENTION AND REMOVAL SYSTEM
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SURFACE UNIT
As shown on the left picture, the surface unit consists of an inlet and
an outlet completed with standard flanges, an outer barrel and an
inner tube, a bevel plate with a center hole, cartridge and a drain
hole with a threaded plug.
Unit Sizes 2” 3” 4” 6” 8”
Plate Nos. 5 5 5 5
Pressure Drop
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Unit Installation
Installation Dimension
The installation dimension of the surface unit is shown in the following table and schematic
drawing.
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CORROSION PREVENTION AND REMOVAL SYSTEM
Best Solution to Paraffin, Scale and Corrosion Problems
+
Q_G_
_
Sizes A H D D1 d d1 n
2” 420 280 ¶110 ¶140 ¶50 ¶18 4
3” 500 350 ¶150 ¶185 ¶80 ¶18 4
4” 550 370 ¶170 ¶210 ¶100 ¶18 4
6” 650 493 ¶225 ¶257 ¶150 ¶18 8
8”
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Cooling Tower
Make Up Condenser
MHD Cooling
Multimedia Tower Chiller Facility
Filter Load
Y Strainer
Pump
Blowdown Surface Tool
Pump Pump
Boilers
Surface Tool
Pump
Condenser
Cooling water
Gases
Load
Makeup
Water
Boiler
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Injection Well
Injection Well
High Pressure
Pump
Water
tank
Surface Unit
Production Lines
When surface units are used on surface flow line applications, how many units need to be
installed and how far it is between every two units will depend on the working condition. Pemex in
Mexico are using a surface unit at each well. A flow line extending five (5) kilometers
Surface Unit
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between wells is standard. This is working very nicely for Pemex with a two (2) inch flow line.
For large size flowlines like six (6) and eight (8) inch lines, the distance between the units should be
much shorter. It is recommended the distance
between units can vary from five (5) kilometers to
ten (10) kilometers depending on the size of the
flow line and the viscosity of the fluid.
Pipelines with a large pressure flow may need to be
closer because the principle of the tool
depends on contact time with the fluids.
Oil Storage
Surface unit tank
Transfer Pump
Water Oil
Tank Tank
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Production Battery
If there is problem with high bottoms in oil production tanks, a surface unit may be installed
downstream from the oil dump of the production separator.
Oil Water
tank tank
Surface Unit
Gas
Oil dump line
Oil
Water dump line
Water
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CORROSION PREVENTION AND REMOVAL SYSTEM
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DOWNHOLE UNIT
Description
CPRS downhole unit is an innovative tool specially designed and developed for solution to the
paraffin, scale and corrosion problems in oil wells. It can be used during the oil and natural gas
production to prevent the buildup of paraffin, scale, rust and asphaltene deposits, and also to
remove the existing deposits on the surface of the equipment or flowlines. When installed in a
producing oil or gas well, current treatment methods such as wireline scraping, chemical and hot oil
circulation, will be eliminated, resulting in reduced operating costs and stabilized production.
254mm
Ø6.35mm +
508 mm
If the tool will be attached to the downhole pump directly, the connection threads can be
machined to meet the pump specification.
Technical Data
• Size:1.66”
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Operation Benefits
How it works
The crude oil and its entrained minerals treated in the units as
described above pass through the string of tubing to the surface.
The treated crude oil not only has the paraffin’s and other waxes
which tend to clog the tubing in suspension but the unit breaks up the
long chain hydrocarbon molecules making the oil “slicker”. On
high paraffin low gravity crude’s, the treatment increases the
American Petroleum Institute (API) specific gravity of the
resulting crude by at least two or three points thus Increasing the
marketability of the treated crude. These same results occur with
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the surface units with the crude being pumped through the cartridge inserts.
CPRS works in virtually any well that experiences deposition, including dual completions,
directional, horizontal, water source and water injection wells. CPRS downhole unit works with any
pumping system, including Electrical Submersible Pumps. Each application is designed for the
specific well depending upon tubing size and fluid volume. Typically, CPRS will be run either
below the pump intake or above the pump discharge, or as a tail joint at the end of the tubing
string. Simple to install, CPRS requires no external power source, maintenance or servicing
and has no internal restrictions.
CPRS downhole unit can also be installed in a flowing well without pulling the tubing. It can be set
in a tubing string in a nipple using the appropriate setting tool using wireline.
Most heavy oil wells have problems with production because of low viscosity of the oil in the
tubing. With CPRS, you get increased flow rates, less torque pressures and less stress on pumps
due to changes in viscosity. Once again, cleaner, smoother running well is more efficient and
easier on your equipment.
Scientige
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Pumping Well
Downhole
Pump
CPRS
Downhole
Flowing Well
CPRS
Downhole
Packer
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Gaslifting Well
Gas lifting
Mandrel CPRS
Downhole
CPRS
Downhole
Gas lifting
Mandrel
Packer Packer
ESP Well
ESP
CPRS
Packer
Sand
Screen
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Surface Units
• Unscrew the bolt of top blind flange and take off the flange.
• Take out the plate insert out of the inner tube, flush the plates with clean water or clean
them with other materials.
• Unscrew the bottom plug from the drain hole, flush inside of the unit with clean water.
• Put back the inserts and the drain hole plug. Bolt the top flange on.
The interval between maintenances will depend on the working condition of unit. It is
recommended to check it on monthly bases.
• Vent the pressure before open the top flange when the pressure is trapped.
Downhole Units
Downhole units are almost maintenance free. Flush it with clean water when the tool is pulled out
of the hole while downhole pumps is pulled out for inspection or maintenance.
Notice
Once installed, CPRS my cause old scale and corrosion particles to separate from inside of the pipe
and equipment, which can cause leaks and accumulation of old scale particles, especially in older
systems. Cautions should be taken by the users.
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The CPRS can last for a very long time. It acts only as a catalyst during the whole function process
to change the property of the fluids and the minerals entrained in the fluids through
electrochemical ways and polarization. The process is a non-sacrificing process, and it will not
change the characteristics of the unit itself.
CPRS, including surface units and downhole units, has no moving parts, and has no wearing
problems. However, how long the units can last still depend on the working conditions. During the
working process, the abrasive solids in the fluids may cause wearing or damage to the units
because the solids will pass through the unit at high speed and certain pressure.
Depending on the working conditions and the property of the fluids, it can be estimated that from our
tool history that CPRS can run for 5 to 10 years without any problem. The first few tools are still in
good condition after being used for more than six years.
A leach test was run at the same test facility in Roswell of New Mexico from July 20, 1988 to
January 13, 1989. Well water was used for the test having a TDS (Total Dissolved Solids) of
about 111.000 ppm (parts per million). A flow meter was installed after the surface unit plate to
measure the amount of water through the plate. The plate was removed, cleaned with a 2% citric
acid, dried and weighed. Then the plate was reinstalled in line. This was performed once a week for
the first month, then once again after two months and the last time three months later. The initial
weight of the plate (after 75,143 gallons had flowed through the stabilizer) was 76.3834 grams. The
final weight of the plate was 71.5665 grams. The plate lost 4.8169 grams. This is an average of
0.0009 ppm total plate material added to the water. (One part per million corresponds to one minute
in two years or a single penny in $10.000)
The abrasive solids in high-speed flow may cause premature wear or damage to the units, as
shown in the following pictures. However the damage will not influence the working
performance of the unit.
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CASE STUDIES
Changqing Oilfield/PetroChina
• Well H16-7, Wangnan Operation Base
• September 15, 2002: No hot oil treatment was done and no pump repair job. The
maximum rod load and maximum current of the motor were obviously dropped than
before the installation
• July 2004: One-year downhole operation without any problems, no hot oil treatment, no
chemicals and no pump repair.
The following is the date sheet, which shows there are no workover jobs, no pump repair and no hot
oil treatment after the installation.
Date Well Daily Daily Oil Water Dynamic Horsepower Max Min Up Down Notes
Production Fluid Rate (t) ratio Fluid schematic Rod Rod stroke stroke
Days Rate (%) Level analysis Load load Max Max
3
(m ) (m) (KN) (KN) Amps Amps
(A) (A)
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CORROSION PREVENTION AND REMOVAL SYSTEM
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2003.4.17 29.7 11.43 2.02 79.0 389/575 OK _ _ _ _ H/O
Paraffin Severity Average Pumps Repairing interval: 237 days; Average Hot oil treatment Interval: 30 days_
Date Well Daily Fluid Daily Water Dynamic Horsepower Max Min Up Down Notes
3
Production Rate (m ) Oil ratio Fluid schematic Rod Rod stroke stroke
Days Rate (%) Level analysis Load load Max Max
(t) (m) (KN) (KN) Amps Amps
(A) (A)
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CORROSION PREVENTION AND REMOVAL SYSTEM
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2003.12.4 _ 10.67 1.67 81.4 462/501 OK 28.96 9.57 _ _ _
2004.2.4 _ _ _ _ 394/578 OK _ _ _ _ _
Prior to installing the downhole tool, the Hooks-State Well #1 was producing at 5000 psig
flowing tubing pressure at a rate of approximately 200 barrels of condensate per day with a
paraffin content of 13.5%. Due to paraffin buildup in the 2-3/8" tubing string, it was requested to cut
paraffin each month at a cost of approximately $1500. In addition, downtime for cutting the
paraffin was causing loss of production revenue amounting to approximately $2000 per month.
After installing the tool, no more paraffin cutting was needed for the next year, which has
resulted in a savings to Touchstone Resources of approximately $42,000.00.
In addition, the well recently began producing a large quantity of sand, which resulted in the
tubing plugging with sand and the necessity of performing a coiled tubing cleanout of the well.
After cleaning out the tubing string, the downhole unit was easily removed with a slickline and
showed no effects from either erosion or corrosion.
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CORROSION PREVENTION AND REMOVAL SYSTEM
Best Solution to Paraffin, Scale and Corrosion Problems
• Before installation, the wells were being hot oiled (tubing and flowline) in the winter
months on a weekly basis.
• Two years after installation, the wells have not required hot oiling since
• Serious paraffin problems and the production rate was less than1000BOPD
• The well has not produced for more than 2 months at single stretch
LA
Prior to installation:
• Cut paraffin every 30 days at a cost of US$10,500 for each well.
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After installation:
• No need to cut paraffin.
• Within two years, approximately US$120,000 was saved for each well
• Two of the leases with the worst scale and paraffin problems
• Before CPRS units was installed, hot oiling on flow lines and downhole every thirty
• days.
• Running heater treaters at 135 degrees, rolling tanks just before the hauls and selling
oil at a BS &W count of 2. That is the maximum number allowed for Scurlock to pick
up the oil. Paraffin and scale existed throughout the entire system.
• May 1, 2000: installed surface units on two different leases south of Kilgore. These
wells produce from the Travis Peak and Pettit formations, 7300 to 7500 feet.
• June 1,2000: Surface equipment had cleaned up. The separators could be put back
into service. Prior to this time the separators had to be bypassed because of paraffin.
Flow lines were clean. The BS&W fell to 0.50 and sometimes to as low of 0.10. No hot
oil treatments. No rolling the tanks to sell the oil.
• By June 15: all shakeouts were showing no paraffin, only corrosion. The corrosion was
from the inside of the walls of the lank battery …… further proof that the unit was
removing old scale.
• July 7,2000: Company man came to location to see for himself. The flow lines were
cleaned up. All surface equipment was clean. Noted that the site glass on the separators
was clean… had never been able to read it before.
• July 28,2000- Had to hot oil one lease to pull the pump. A downhole unit was installed
• on both leases.
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Prior to installation:
• Have to pull this well every 3 months for corrosion and paraffin problems
• No hot oil treatment had been done because the rods were paraffin free.
• No pump change out because there was no pump corrosion and the only thing did was
to change the ball and seat.
• Savings from replacing pumps and rods, hot oil treatment, workover time totaled at
approximately US$29,540.20
This test involves using a surface unit, in place of an antiscalant being pumped into the feed
water, to prevent scaling up of the reverse osmosis membrane. This test is running on water with
total dissolved solids of 10,400 mg/L at 50% recovery. This can be compared to the water from the
City of Roswell that has total dissolved solids of 840 mg/L. This means there are more than ten
times the dissolved solids in the test water than the water from the City of Roswell. The water used
for this test has a total hardness of 166 grains/ gallon.
The test membrane with the surface unit in the feed line was run for 2,193 hours with an only
slight decrease on the percentage rejection and percentage recovery during this period of time. It is
not unusual for an untreated feed on the same membranes to plug the membrane in 100 hours or
less. The membrane did not show any signs of scaling up. The only pre-treatment of the water used
in the test was to run it through and A.G. and Magnesium green sand filters to remove iron.
When the product flow dropped to this unit it was flushed for 30 minutes with City water. This was
done 3 times and it brought the product flow back up.
It can be inferred from the data that the surface unit is keeping the reverse osmosis membrane
from scaling up.
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CORROSION PREVENTION AND REMOVAL SYSTEM
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• 71 days after installation on May 15, 2001 (no chemicals had been used), the system
inspection indicated that:
• Pressure at injection well has maintained at 400psi, down from 425-430 psi prior to
installation
• Suction cap on Gardner Denver injection pump had no additional scale buildup
Cooling Towers and Ice Machine / Reddy Ice Plant, Houston, Texas
Location: Reddy Ice Plant, Houston, Texas
Prior to installation:
• Repaint equipment twice each year due to chemical leakage from towers
• Enormous expenses to dispose of chemical laden water into city sewer system
After installation:
• Permission was obtained from the city to dispose water at no extra expense
• After the cooling tower application, a stainless steel 4” unit was installed on the ice
machines. Within 2 weeks, the lines had to be shut down because the old scale had
broken loose and clogged up the lines. After going back on lines, all salt was eliminated,
the efficiency increased 2%, producing 6 to 9 more tons of ice a day.
• Four weeks after installation, all of the towers had to be cleaned manually because of
swarm of ants, it was noticed that the old scale on the tower with the surface unit
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CORROSION PREVENTION AND REMOVAL SYSTEM
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literally fell off whereas the scale on the other towers has to be forcibly removed by
hand.
The Stratford #1 is located in the Texas Panhandle (Hugoton Field) and produces from the
Brown Dolomite Formation at approximately 3200’. The. Majority of these Dolomite wells have
extremely low bottomhole pressures and have to rod pumped in order to produce the gas. Very
small amounts of formation water (1/4 - 1 BBL) will load these wells up. There is a serious
Iron-Sulfide problem that exists with the production of the Dolomite gas. The Iron-Sulfide
precipitates out of solution as the gas and small amounts of water are produced. The Iron-Sulfide
can and will over time plug the perforations and corrode the downhole pumps. As previously
mentioned these wells pump about _ -1BBL/water/day and produce from 10 - 100 MCF/Day.
These wells normally pump using a time clock due to the small amounts of water production.
With Iron-Sulfide problems, as time goes on the downhole pump efficiency decreases due the
sulfide problems therefore it is necessary to lengthen pump time. To increase pump time the
more wear and tear is encountered on the pump thus reducing the length between pulling the well
and doing the necessary repairs. It is known that the longer run times without costly workovers
the more profitable the well.
Since installing the CPRS tool on the bottom of the downhole pump in November 2000, not any
problems have happened with pump efficiency and the amount of on time has not been increased.
This accounts for less wear and tear and obviously without having to increase the on time. Pump
efficiency was excellent, which saved the on time by at least 50% in comparison to the time
before the installation of CPRS. The well pumps 15 minutes out of every 3 hours and produces 46
MCF/Day and 0.5 BBL Water. Without the CPRS tool the pumping time will approximately be
1HR on and 2HR off.
In conclusion, CPRS tool has eliminated the majority of the Iron-Sulfide problems experienced in
the Hugoton Field.
• CPRS was installed in a waterflood unit with a total daily injection of 2,900 barrels
made up of 75% produced water and 25% purchased potable water. A surface unit was
installed to reduce precipitations of sulfate reducing bacteria. The surface unit was
located between parallel booster pumps and sock-type filter canisters prior to injection
pumps. Typical filter changes were occurring on ten-day intervals. Normal operating
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booster pump pressure is 88 psig. Filters were being changed when pressure
downstream of the filters reached approximately 10 psig due to filter plugging.
• After installing the stabilizer, two failures occurred in the PVC basket due to
the seal-support ring breaking. This problem has been resolved. Run times,
disregarding failure periods when flow could bypass the stabilizer plates and oil
upsets allowing oil carryover into the injection system, have ranged from 17 to 30
days. Recent filter changes have been made prior to the downstream pressure
reaching 20 psig.
• Considering all data, including basket failures and oil in the system, CPRS surface
unit resulted in extending filter changes by a factor of two or better.
Other Applications
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CUSTOMER LIST
International Customers
• Ecopetrol / Equador
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CORROSION PREVENTION AND REMOVAL SYSTEM
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• KOR / Kazakhstan
• Mark Carpenter Plumbing / Clovis, New Mexico __North Tower Systems / California
• PDVSA / Venezuela
• Shell / Nigeria
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China Customers
• Changqing Oilfield, CNPC
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